Abstract This chapter analyzes issues that deal with the general properties of angular momentum; angular momentum, l = 1; the addition of angular momenta; and tensor formalism in angular momentum theory.
Chapter 11 is devoted to the quantum theory of angular momentum. As in classical mechanics, working with angular momentum requires leaving the one-dimensional space, with all the complications that this entails. The importance of angular momentum resides in at least three facts: i) central problems are of particular interest; (ii) many particles have an intrinsic angular momentum (the spin); and iii) the physics of angular momentum involves features such as the so-called space quantization. The first part of the chapter deals with the orbital angular momentum and its eigenfunctions, the spherical harmonics. Its algebraic properties, embodied in the matrix representation, allow for an extension of the theory to half-integer angular momentum in terms of Pauli matrices, as well as the addition of angular momenta.
This chapter covers various aspects of orbital, total, and spin angular momenta and the Clebsch-Gordon coefficients. An approach that is not found in many books, is used to derive eigenvalues of orbital angular momentum. The Pauli theory of spin half systems, addition of angular momenta, eigenfunctions of orbital angular momentum, computation of Clebsch-Gordon coefficients, solved examples, and unsolved exercises are included in the chapter. The basic purpose of the chapter has been to bring out the quantum mechanical importance of the theory of angular momenta with the use of essential mathematical derivations, which are self-consistent, and to adopt an elegant modern approach. Special mention on why orbital angular momentum cannot have non-integer values is made. The concept of spin angular momentum, which is purely a quantum mechanical quantity, is introduced in a simple and most convincing manner.
Synopsis: General operator properties of angular momenta are recalled, and a physical motivation for adding them is given. The product and total angular momentum bases are defined. It is shown how to express one basis in terms of the other, and an explicit example of adding two spin 1/2 angular momenta is given. A further example consists of adding a general orbital angular momentum value to spin 1/2. These considerations are applied to perturbations in the hydrogen atom energy spectrum, where the correct choice for calculations is the total angular momentum basis.
Angular momentum is one of the more abstract topics in quantum mechanics. This chapter begins with a review of classical angular momentum. Quantum-mechanical angular momentum is then introduced by obtaining operators from their classical counterparts. The commutation relations amongst those operators and the corresponding uncertainty relations then follow. Eigenstates and eigenvalues of the angular momentum operators are then introduced (but not derived). From these follow the raising and lowering operators. Physical meaning is imparted to quantum angular momentum by considering predictions for sequential measurements, and by comparing the conceptual pictures of angular momentum in classical and quantum mechanics. Finally, quantum spin and orbital angular momenta, and the deep differences between them, are discussed.
Synopsis: General operator properties of angular momenta are recalled, and a physical motivation for adding them is given. e product and total angular momentum bases are defined. It is shown how to express one basis in terms of the other, and an explicit example of adding two spin 1/2 angular momenta is given. A further example consists of adding a general orbital angular momentum value to spin 1/2. ese considerations are applied to perturbations in the hydrogen atom energy spectrum, where the correct choice for calculations is the total angular momentum basis.