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Cambridge University Press eBooks

Quantum statistical mechanics

Michel Le Bellac

Published Aug 1, 1996• 3 citations
Publisher

Abstract

We now start what will be the subject of this book: quantum field theory at non-zero temperature and/or non-zero chemical potential. Two competing formalisms have been used at zero temperature in order to study field theory: the operator formalism, which is the older one, and the path integral formalism, which represents the more modern approach. Actually, it may often be illuminating to look at a given problem from both points of view, although in some cases one of the formalisms may prove to be definitely superior to the other: for example, path integrals are much simpler when quantizing gauge theories. At finite temperature, both formalisms are useful, and it is instructive to be able to switch from one approach to the other. Since the simplest case of field theory is field theory with zero space dimension, or, in other words, quantum mechanics, we shall begin with a short description of quantum mechanics at finite temperature, or, equivalently, quantum statistical mechanics. We first deal with the path integral approach, and later on revert to the more conventional operator formalism. We shall be particularly interested in time-ordered products of position operators, which will generalize to time-ordered products of field operators in field theory.

DOI
10.1017/cbo9780511721700.003

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We now start what will be the subject of this book: quantum field theory at non-zero temperature and/or non-zero chemical potential. Two competing formalisms have been used at zero temperature in order to study field theory: the operator formalism, which is the older one, and the path integral formalism, which represents the more modern approach. Actually, it may often be illuminating to look at a given problem from both points of view, although in some cases one of the formalisms may prove to be definitely superior to the other: for example, path integrals are much simpler when quantizing gauge theories. At finite temperature, both formalisms are useful, and it is instructive to be able to switch from one approach to the other. Since the simplest case of field theory is field theory with zero space dimension, or, in other words, quantum mechanics, we shall begin with a short description of quantum mechanics at finite temperature, or, equivalently, quantum statistical mechanics. We first deal with the path integral approach, and later on revert to the more conventional operator formalism. We shall be particularly interested in time-ordered products of position operators, which will generalize to time-ordered products of field operators in field theory.
The aim of this chapter is to introduce the concept of the Feynman path integral. As well as developing the general construction scheme, particular emphasis is placed on establishing the interconnections between the quantum mechanical path integral, classical Hamiltonian mechanics, and classical statistical mechanics. The practice of path integration is discussed in the context of several pedagogical applications. As well as the canonical examples of a quantum particle in a single and a double potential well, we discuss the generalization of the path integral scheme to tunneling of extended objects (quantum fields), dissipative and thermally assisted quantum tunneling, and the quantum mechanical spin. In this chapter we temporarily leave the arena of many-body physics and second quantization and, at least superficially, return to single-particle quantum mechanics. By establishing the path integral approach for ordinary quantum mechanics, we will set the stage for the introduction of field integral methods for many-body theories explored in the next chapter. We will see that the path integral not only represents a gateway to higher-dimensional functional integral methods but, when viewed from an appropriate perspective, already represents a field theoretical approach in its own right. Exploiting this connection, various concepts of field theory, namely stationary phase analysis, the Euclidean formulation of field theory, instanton techniques, and the role of topology in field theory, are introduced in this chapter. The path integral: general formalism Broadly speaking, there are two approaches to the formulation of quantum mechanics: the “operator approach” based on the canonical quantization of physical observables and the associated operator algebra, and the Feynman path integral.
In this chapter, the concept of path integration is generalized to integration over quantum fields. Specifically we will develop an approach to quantum field theory that takes as its starting point an integration over all configurations of a given field, weighted by an appropriate action. To emphasize the importance of the formulation that, methodologically, represents the backbone of the remainder of the text, we have pruned the discussion to focus only on the essential elements. This being so, conceptual aspects stand in the foreground and the discussion of applications is postponed to the following chapters. In this chapter, the concept of path integration will be extended from quantum mechanics to quantum field theory. Our starting point will be from a situation very much analogous to that outlined at the beginning of the previous chapter. Just as there are two different approaches to quantum mechanics, quantum field theory can also be formulated in two different ways: the formalism of canonically quantized field operators, and functional integration. As to the former, although much of the technology needed to efficiently implement this framework – essentially Feynman diagrams – originated in high-energy physics, it was with the development of condensed matter physics through the 1950s, 1960s, and 1970s that this approach was driven to unprecedented sophistication. The reason is that, almost as a rule, problems in condensed matter investigated at that time necessitated perturbative summations to infinite order in the non-trivial content of the theory (typically interactions).
In this chapter, the concept of path integration is generalized to integration over quantum fields. Specifically we will develop an approach to quantum field theory that takes as its starting point an integration over all configurations of a given field, weighted by an appropriate action. To emphasize the importance of the formulation that, methodologically, represents the backbone of the remainder of the text, we have pruned the discussion to focus only on the essential elements. This being so, conceptual aspects stand in the foreground and the discussion of applications is postponed to the following chapters. In this chapter, the concept of path integration is extended from quantum mechanics to quantum field theory. Our starting point is a situation very much analogous to that outlined at the beginning of the previous chapter. Just as there are two different approaches to quantum mechanics, quantum field theory can also be formulated in two different ways: the formalism of canonically quantized field operators, and functional integration. As to the former, although much of the technology needed to efficiently implement this framework – essentially Feynman diagrams – originated in high-energy physics, it was with the development of condensed matter physics through the 1950s, 1960s, and 1970s that this approach was driven to unprecedented sophistication. The reason is that, almost as a rule, problems in condensed matter investigated at that time necessitated perturbative summations to infinite order in the non-trivial content of the theory (typically interactions).
Quantum field theories are quantum mechanical systems with an infinite number of degrees of freedom. We start this book with a review of quantum mechanics in a form that is particularly suited for the field theory generalization. This form utilizes the Heisenberg picture and the functional integral representation of probability amplitudes — the transformation functions of Dirac. Some time will be spent developing and discussing the functional or path integral representation of quantum mechanics since this will enable us to learn a new formalism in a simple and familiar physical context — we won't have to learn too many new things all at once. The functional formulation will be illustrated by applying it at some length to the harmonic oscillator which is not only the simplest (and exactly soluble) non-trivial quantum system but which is also the dynamics of a single mode of a free field theory. The purpose of this review of quantum mechanics is to introduce in the simplest form much of the notation and methods used later in the book. Throughout this chapter we will explicitly work only with systems that have a single degree of freedom (one coordinate variable). The extension to systems with several degrees of freedom is straightforward.
Quantum field theory (QFT) provides us with one and almost only suitable language (or mathematical tool) for describing not only the motion and interaction of particles but also their “annihilation” and “creation” out of a field considered a priori in a sophisticated way, whose view seems to be suited for describing dislocations, as a particle or a string embedded within a crystalline ordered field. This chapter concisely overviews the method of QFT, emphasizing distinction from the quantum mechanics, conventionally used for a single and/or many particle problems, and its equivalence to the statistical mechanics. The alternative formalism based on Feynman path integral and its imaginary time representation are reviewed, as the foundation for our use in Chapter 10.
These lectures are intended as an introduction to the technique of path integrals and their applications in physics. The audience is mainly first-year graduate students, and it is assumed that the reader has a good foundation in quantum mechanics. No prior exposure to path integrals is assumed, however. The path integral is a formulation of quantum mechanics equivalent to the standard formulations, offering a new way of looking at the subject which is, arguably, more intuitive than the usual approaches. Applications of path integrals are as vast as those of quantum mechanics itself, including the quantum mechanics of a single particle, statistical mechanics, condensed matter physics and quantum field theory. After an introduction including a very brief historical overview of the subject, we derive a path integral expression for the propagator in quantum mechanics, including the free particle and harmonic oscillator as examples. We then discuss a variety of applications, including path integrals in multiply-connected spaces, Euclidean path integrals and statistical mechanics, perturbation theory in quantum mechanics and in quantum field theory, and instantons via path integrals. For the most part, the emphasis is on explicit calculations in the familiar setting of quantum mechanics, with some discussion (often brief and schematic) of how these ideas can be applied to more complicated situations such as field theory.