The partition function for interacting bosons is derived as the coherent state path integral and then generalized to magnetic transitions. Phase transitions in the Ginzburg–Landau–Wilson theory for a fluctuating order parameter are discussed in Hartree's and Landau's approximations, and the fundamental limitation of perturbation theory near the critical point is exposed. The concept of upper critical dimension is introduced. Partition function for interacting bosons As a prototypical system with a continuous phase transition we will consider the system of interacting bosons. A well studied physical realization is provided by helium ( 4 He) with the pressure–temperature phase diagram as depicted in Fig. 2.1. Since the atoms of helium are light and interact via weak dipole–dipole interactions, due to quantum zero-point motion helium stays liquid down to the lowest temperatures, at not too high pressures. Instead of solidifying it suffers a continuous normal liquid–superfluid liquid transition at T c ≈ 2K, also called the λ-transition due to the characteristic form of the specific heat in Fig. 1.6. The λ-transition represents the best quantitatively understood critical point in nature. We have already quoted the specific heat exponent α = -0.0127 ± 0.0003, with the power-law behavior being observed over six decades of the reduced temperature! To achieve this accuracy the experiment had to be performed in the space shuttle so that the small variations in Tc along the height of the sample due to Earth's gravity would be minimized. At higher pressures He eventually solidifies, with the superfluid–solid and the normal liquid–solid phase transitions being discontinuous, the former being so rather weakly.
The partition function for interacting bosons is derived as the coherent state path integral and then generalized to magnetic transitions. Phase transitions in the Ginzburg–Landau–Wilson theory for a fluctuating order parameter are discussed in Hartree's and Landau's approximations, and the fundamental limitation of perturbation theory near the critical point is exposed. The concept of upper critical dimension is introduced. Partition function for interacting bosons As a prototypical system with a continuous phase transition we will consider the system of interacting bosons. A well studied physical realization is provided by helium ( 4 He) with the pressure–temperature phase diagram as depicted in Fig. 2.1. Since the atoms of helium are light and interact via weak dipole–dipole interactions, due to quantum zero-point motion helium stays liquid down to the lowest temperatures, at not too high pressures. Instead of solidifying it suffers a continuous normal liquid–superfluid liquid transition at T c ≈ 2K, also called the λ-transition due to the characteristic form of the specific heat in Fig. 1.6. The λ-transition represents the best quantitatively understood critical point in nature. We have already quoted the specific heat exponent α = -0.0127 ± 0.0003, with the power-law behavior being observed over six decades of the reduced temperature! To achieve this accuracy the experiment had to be performed in the space shuttle so that the small variations in Tc along the height of the sample due to Earth's gravity would be minimized. At higher pressures He eventually solidifies, with the superfluid–solid and the normal liquid–solid phase transitions being discontinuous, the former being so rather weakly.
Using the functional-integral method applied to the BCS Hamiltonian we have calculated the partition function, off-diagonal correlation function, specific heat, and conductivity of a super-conductor in the transition region. The partition function is obtained in the form $\ensuremath{\int}D\ensuremath{\psi}{e}^{\ensuremath{-}\ensuremath{\beta}F[\ensuremath{\psi}]}$, where F is of the Ginzburg-Landau form but with a time-dependent order parameter. An examination of the coefficient b of the fourth-order term in F, however, shows that b is sharply peaked at zero frequency, thus justifying the use of a time-independent order parameter. We then apply a self-consistent mean-field approximation similar to that of Mar\ifmmode \check{c}\else \v{c}\fi{}elja to the fourth-order term. The self-consistency condition determines the mean-square fluctuation in the order parameter and a renormalized temperature shift in terms of which the nature of the phase transition (or lack of it) can be understood. We find that only in three dimensions does a phase transition strictly occur, at a slightly lowered transition temperature with critical indices $\ensuremath{\gamma}=2$, $\ensuremath{\nu}=1$. In two, one, and zero dimensions the mean-square fluctuation in the order parameter is bounded for T>0 and the mean value of the order parameter vanishes, indicating that the transition is completely suppressed in samples of reduced dimensionality. This behavior is reflected in the off-diagonal correlation function which manifests off-diagonal long-range order only in three dimensions. The specific heat in three dimensions is found to be finite at Tc, with critical index $\ensuremath{\alpha}=\ensuremath{-}1$. In two, one, and zero dimensions the specific-heat transition is rounded relative to the BCS result. We find an anomalous factor of 2 in the specific-heat calculation deriving from our treatment of the fourth-order term in F. As a result we conjecture that the Hartree approximation of Mar\ifmmode \check{c}\else \v{c}\fi{}elja may be better than the Hartree-Fock approximation of Tucker and Halperin. The equations for the conductivity are identical to those of Mar\ifmmode \check{c}\else \v{c}\fi{}elja.
The goal of this chapter will be to briefly describe the remarkable properties of helium at low temperatures. After stating some of these properties we will see how they can be understood in terms of the phenomenon of Bose–Einstein condensation described in Chapter 7. We will give the main argument in two different formulations, once using the quasi-particle method of Bogoliubov, and then using a Green function approach. We start with some experimental facts. Helium is a remarkable element. It was predicted to exist from observations of the Sun before it was found on Earth. It is the only element which remains a liquid at zero temperature and atmospheric pressure. Experimentally the phase diagram of 4 He is shown in Figure 10.1. Helium I is a normal fluid and has a normal gas-liquid critical point. Helium II is a mixture of a normal fluid and a superfluid. The superfluid is characterized by the vanishing of its viscosity. Helium I and helium II are separated by a line known as the λ -transition line. At T λ = 2.18 K, P λ = 2.29 Pa, helium I, helium II, and helium gas coexist. The specific heat of liquid helium along the vapor transition line forms a logarithmic discontinuity shown in Figure 10.2. The form of this diagram resembles the Greek letter λ and is the reason for calling the transition a λ -transition. The lack of viscosity of helium II leads to some remarkable experimental consequences, one of which we briefly describe. Let two containers A and B be linked by a thin capillary through which only a fluid with zero (or very low) viscosity can pass freely.
The Landau-Ginzburg-Wilson (LGW) paradigm is the backbone of the modern understanding of critical phenoma. It rests on the assumption that a continuous phase transition can be described solely in terms of a fluctuating order parameter. In this sandwich thesis, we analyze several quantum phase transitions in two-dimensional systems where this basic assumption is violated. Our analysis is structured in three parts: In the first part, two ordering transitions in metals are studied, where the presence of gapless fermionic modes invalidates the pure order parameter description. Instead, we apply a renormalization group approach which retains both fermionic and bosonic (order paramater) degrees of freedom, using the deviation from an upper critical dimension of d = 5/2 as a control parameter. We first apply this technique to describe the quantum phase transition between a normal metal and an inhomogeneous (FFLO) superconductor. Our analysis rigorously confirms the mean field expectation that this transition is continuous, and shows that interesting non-Fermi liquid physics can arise at the critical point, manifesting itself in unusual scaling of various observables. The second case study is the onset of incommensurate 2kF charge density wave order. While non-Fermi liquid features are less pronounced at this transition, we find a strong dynamical nesting of the Fermi surface, which stabilizes the density wave formation and results in a continuous transition, opposed to early theoretical claims. In the second part, we present a novel case study of “deconfined criticality” for a quantum magnet: Here, symmetries are broken on both sides of the phase transition, which would be first order within a conventional two-order-parameter LGW description. By contrast, the scenario of deconfined criticality predicts a continuous transition, driven by condensation of topological defects which carry quantum numbers of the opposite phase. Its paradigmatic application is the transition from a SU (2)-Neél state to a valence-bond solid (a singlet covering configuration that breaks spatial symmetries) on the square lattice. Here, we propose a novel extension and study a SU (3) antiferromagnet on a triangular lattice, which supports a transition between a magnetic, three-sublattice color-ordered phase and a trimerized SU (3) singlet phase. We provide a critical theory in terms of fractional bosonic degrees of freedom (and with a topological defect interpretation), and study its fixed point properties with functional renormalization group. This yields a critical fixed point in a suitable large-N -limit, implying a continuous transition in accordance with the deconfined criticality framework. In the third and final part, we study the “polaron”-problem of a single impurity coupled to a majority Fermi sea, which is particularly interesting when formation of a bound state (“molecule”) between impurity and majority is allowed for. Starting from the exactly solvable limit of infinite impurity mass, we present a controlled computation of impurity spectra (both single- and two-particle) for heavy impurities based on Feynman diagram techniques, with an eye for experiments on doped semiconductors and ultracold gases. Furthermore, we discuss various aspects of the “molecule-to-polaron” transition that occurs in these systems, which also defies a simple LGW description in the single-impurity limit.
To set the stage for our subsequent thorough discussion of dynamic critical phenomena, we first review the theoretical description of second-order equilibrium phase transitions. (Readers already well acquainted with this material may readily move on to Chapter 2.) To this end, we compare the critical exponents following from the van-der-Waals equation of state for weakly interacting gases with the results from the Curie–Weiss mean-field approximation for the ferromagnetic Ising model. We then provide a unifying description in terms of Landau–Ginzburg theory, i.e., a long-wavelength expansion of the effective free energy with respect to the order parameter. The Gaussian model is analyzed, and a quantitative criterion is established that defines the circumstances when non-linear fluctuations need to be taken into account properly. Thereby we identify d c = 4 as the upper critical dimension for generic continuous phase transitions in thermal equilibrium. The most characteristic feature of a critical point turns out to be the divergence of the correlation length that renders microscopic details oblivious. As a consequence, not only the correlation functions, but remarkably the thermodynamics as well of a critical system are governed by an emergent unusual symmetry: scale invariance. A simple scaling ansatz is capable of linking different critical exponents; as an application, we introduce the basic elements of finite-size scaling. Finally, a brief sketch of Wilson's momentum shell renormalization group method is presented, intended as a pedagogical preview of the fundamental RG ideas. Exploiting the scale invariance properties at the critical point, the scaling forms of the free energy and the order parameter correlation function are derived.
Phase transitions are defined, and the concepts of order parameter and spontaneously broken symmetry are discussed. Simple models for magnetic phase transitions are introduced, together with some experimental examples. Critical exponents and the notion of universality are defined, and the consequences of the scaling assumptions are derived. Phase transitions and order parameters It is a fact of everyday experience that matter in thermodynamic equilibrium exists in different macroscopic phases. Indeed, it is difficult to imagine life on Earth without all three phases of water. A typical sample of matter, for example, has the temperature–pressure phase diagram presented in Fig. 1.1: by changing either of the two parameters the system may be brought into a solid, liquid, or gas phase. The change of phase may be gradual or abrupt. In the latter case, the phase transition takes place at well defined values of the parameters that determine the phase boundary. Phase transitions are defined as points in the parameter space where the thermodynamic potential becomes non-analytic. Such a non-analyticity can arise only in the thermodynamic limit, when the size of the system is assumed to be infinite. In a finite system the partition function of any system is a finite sum of analytic functions of its parameters, and is therefore always analytic. A sharp phase transition is thus a mathematical idealization, albeit one that describes the reality extremely well. Macroscopic systems typically contain ∼ 10 23 degrees of freedom, and as such are very close to being in the thermodynamic limit. The phase boundaries in Fig. 1.1, for example, for this reason represent reproducible physical quantities.
Introduction The quantum phase transitions considered so far in this book are mostly continuous, second order. They are associated with the divergence of a correlation length and of a characteristic time that renders the quantum critical point scale invariant. However, there are many important phase transitions at which the order parameter goes abruptly to zero and, more important, at which the characteristics of length and critical time do not diverge. In general there is also a latent heat , or work required, to transform one phase into another. In this and the next chapter we study these discontinuous quantum phase transitions. We proceed by considering initially some important cases of what is known as fluctuation induced quantum phase transitions to next treat a more general case of a first-order quantum phase transition. We will show through the study of these problems that the concepts of critical exponents and scaling remain useful, even though these systems do not exhibit scale invariance at their critical point. In Chapter 15 we present the scaling theory of first-order quantum phase transitions and use its results to treat some general problems. One of the most interesting cases of fluctuation-induced transitions occurs in superconductors due to the coupling of the charged carriers to the electromagnetic field. We consider initially a wider class of systems with macroscopic wave functions, the superfluids, of which superconductors are the charged version. We adopt a macroscopic approach to this problem and describe the superfluid by a complex order parameter φ , such that | φ | 2 is proportional to the density of condensed particles. The zero temperature phase diagram is expressed in terms of a control parameter, m 2 , such that, at m 2 = 0, the system presents a quantum phase transition from a superfluid state, for m 2 < 0, φ ≠ 0, to a normal state for m 2 > 0 where φ = 0. In the case of the superconductor with particles of charge q = 2 e , we will include the coupling of these particles to the electromagnetic field and study its effect in the phase diagram of these systems. We show that in the neutral superfluid, the zero temperature transition to the normal state is continuous and occurs at a quantum critical point.