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Cambridge University Press eBooks

The Theory of Turns Adapted from Hamilton

Lawrence C. Biedenharn, James D. Louck, Peter A. Carruthers

Published Dec 28, 1984• 1 citation
Publisher

Abstract

An Alternative Approach to Rotations In the preceding chapters, we have discussed the standard view of the quantum theory of angular momentum. The present chapter is concerned with developing a new view of the subject starting from the beginning with a fresh look at rotations based on a viewpoint adapted primarily from Hamilton [1], but also partly from Klein and Sommerfeld [2] and from Wigner [3] (see Note 1). This new survey will be rewarded by the concept of a novel geometric entity – the turn – which in its quantal version (Chapter 5) will be realized by an elementary operator structure. In discussing this alternative viewpoint, we are primarily interested in motivation and in suggesting concepts. Accordingly, we shall proceed, at first, intuitively. When reduced to fundamentals, the concept of an elementary (point) particle in physics (as discussed in Chapter 1) becomes synonymous with the fundamental symmetries assumed to characterize physical space. We have seen that, from the homogeneity and isotropy assumed for space, one induces the symmetries of spatial displacements (translations) and rotations; that is, one assumes that space is Euclidean and three-dimensional, having the isometry group, E (3), of rotations and translations. It is quite easy to characterize translations, since three-dimensional translations necessarily (Artin [4]) form an abelian (commutative) group. For physics, the translation generator is the (Hermitian) momentum operator p , and the associated operator generating finite displacements is realized by U ( a ) = exp(– i a · p / ħ ). This operator displaces the system by the (numerical) vector a .

DOI
10.1017/cbo9780511759888.007

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Some Applications to Physical Problems

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Introductory Remarks The concepts and techniques of angular momentum theory are by now all but ubiquitous in present-day quantum physics; there is scarcely a single issue of a physics journal that does not in some article directly use angular momentum constructs. It would accordingly be rather fatuous, if not indeed quite impossible, to attempt any definitive (or even very detailed) survey of applications. The purpose of this chapter is therefore rather more modest; we shall focus attention on several typical applications of the theory, in widely different contexts, with an emphasis toward illustrating the basic principles. In discussing any particular field of application, however, we have attempted not to be extensive, but instead have chosen to present a novel, or, at least, unfamiliar, aspect of the subject in some detail. (The discussion in Section 6g – of a result due to Casimir – provides a good example of our intentions.) Basic Principles Underlying the Applications Before turning to specific examples, it will be useful to review briefly the principles underlying the applications. We have seen that a symmetry in quantum physics is a transformation on state vectors (active view – vectors in Hilbert space are transformed and operators are kept fixed) and on observables (passive view – vectors in Hilbert space are kept fixed and operators are transformed) such that all probabilities are preserved (Chapter 3, Section 14). Using the Wigner theorem, we found that this led to either a unitary, or an antiunitary, realization of the symmetry by operators.

Cambridge University Press eBooks•Dec 28, 1984•4 citations

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For pedagogical purposes it is demonstrated that with little effort the customary discussion of rotations in introductory courses can be extended to naturally produce a number of angular momentum operator properties, if coordinate-free rotation operators are used in their exponential form. This form gives rise to a particularly useful coordinate-free representation of the generators of rotations in three-space, from which the student can derive the usual angular momentum formalism for the case j=1 by elementary vector algebra alone. Since in this approach the j=1 formalism appears as a set of relations among simple geometric objects in ordinary space, it admits of a geometric interpretation and will leave the student better prepared for a more profound appreciation of the abstract concepts of the full theory.

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The Boson Calculus Applied to the Theory of Turns

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Introduction The space of turns was shown in the preceding chapter to be the carrier space of the defining (fundamental) representation of the group SU (2) * SU (2) – the group of the symmetric top. We shall show in the present chapter how the complete representation theory of this structure can be obtained from a mapping (the generalized Jordan map) that maps the generic turn into an operator (the matrix boson operator) acting in a Hilbert space. By means of this construction we shall obtain a unified presentation of the angular momentum states, the rotation matrices, and the Wigner coefficients as well. An interesting aspect of this technique is that it leads automatically to a view of the Wigner coefficients as a form of discretized rotation matrix (Section 8 below), which in turn implies a relationship between the Wigner coefficients and Jacobi polynomials (Gel'fand et al . [1, Supplement III]). The key idea behind this unified presentation – the Jordan mapping of the turn into a matrix boson – is of more general validity than the application made here. To put this structure in a larger context we first develop, in some detail, the techniques of the boson calculus . It is hoped that this digression does not break the thread of the development too badly. Excursus on the Boson Calculus The harmonic oscillator . The boson calculus originated in the treatment of a basic physical problem, the quantum mechanics of the linear harmonic oscillator.

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General remarks As already mentioned in the Introduction, the exact solution of the main equation of quantum mechanics – the Schrödinger equation – lies beyond the potentialities of modern mathematics and computer technology. But a number of important inferences about the behaviour, structure and properties of a given quantum-mechanical many-particle system can be drawn without solving this equation, just by examining its symmetry properties. Symmetry concepts come about in physics in two ways. First, since any physical process occurs in a real space, we have to make use of one or another coordinate system. The isotropy and homogeneity of space make physically meaningful only those mathematical relationships that remain unchanged under rotations of the axes of the coordinate system, and that impose fairly rigorous constraints on the possible physical laws. Second, every physical object and process features a symmetry which should be taken into account by the physical theory. A common idea underlying particular forms of symmetry is the invariance of a system under a certain set (group) of transformations. The normally considered forms of symmetry are rotational symmetry, which is based on the equivalence of all directions in space, and permutation symmetry, which is caused by identical particles. The operations of the geometrical symmetry group are responsible for appropriate conservation laws. So, the rotational symmetry of a closed system gives rise to the law of conservation of angular momentum. The group of rotations of a three-dimensional space stands apart in atomic spectroscopy. This is mostly due to the high accuracy of the central field approximation, on which the entire modern theory of complex atoms and ions is based.

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Introduction

L. C. Biedenharn, J. D. Louck

It has been the purpose of the monograph Angular Momentum in Quantum Physics (AMQP) to develop comprehensively those aspects of angular momentum theory that are required in carrying out research in modern physics and chemistry. The emphasis there was principally on physical concepts and the symmetry principles that underlie the general applicability of angular momentum theory to a broad area of physical phenomena. Mathematical techniques were introduced within the context of the physical concepts themselves. Physical applications of angular momentum theory are to a large extent applications of specific properties of Wigner or Racah functions (more generally of 3 n-j coefficients) or of the representation functions themselves. Such applications tend to emphasize the “numerical” aspects of these functions and thus obscure the relationships to other areas of mathematics. The purpose of the present monograph is to show by specific examples the many interrelations that exist between concepts originating in angular momentum theory and various areas of mathematics. It turns out that this is a substantial task—the diversity of the interrelations is far greater than might be thought. Even a brief acquaintance with the contents of AMQP will show that the concept that recurs again and again in physical applications is that of an irreducible tensor operator with respect to a group [in our case, SU (2), the quantal rotation group]. Indeed, it is this concept that carries the mathematical apparatus of the physical theory beyond the related but much simpler results of the Lie algebraic theory of the angular momentum itself and the implied representation theory of the group SU (2).

Cambridge University Press eBooks•Dec 28, 1984•0 citations
An Alternative Approach to Rotations In the preceding chapters, we have discussed the standard view of the quantum theory of angular momentum. The present chapter is concerned with developing a new view of the subject starting from the beginning with a fresh look at rotations based on a viewpoint adapted primarily from Hamilton [1], but also partly from Klein and Sommerfeld [2] and from Wigner [3] (see Note 1). This new survey will be rewarded by the concept of a novel geometric entity – the turn – which in its quantal version (Chapter 5) will be realized by an elementary operator structure. In discussing this alternative viewpoint, we are primarily interested in motivation and in suggesting concepts. Accordingly, we shall proceed, at first, intuitively. When reduced to fundamentals, the concept of an elementary (point) particle in physics (as discussed in Chapter 1) becomes synonymous with the fundamental symmetries assumed to characterize physical space. We have seen that, from the homogeneity and isotropy assumed for space, one induces the symmetries of spatial displacements (translations) and rotations; that is, one assumes that space is Euclidean and three-dimensional, having the isometry group, E (3), of rotations and translations. It is quite easy to characterize translations, since three-dimensional translations necessarily (Artin [4]) form an abelian (commutative) group. For physics, the translation generator is the (Hermitian) momentum operator p , and the associated operator generating finite displacements is realized by U ( a ) = exp(– i a · p / ħ ). This operator displaces the system by the (numerical) vector a .
Introductory Remarks The concepts and techniques of angular momentum theory are by now all but ubiquitous in present-day quantum physics; there is scarcely a single issue of a physics journal that does not in some article directly use angular momentum constructs. It would accordingly be rather fatuous, if not indeed quite impossible, to attempt any definitive (or even very detailed) survey of applications. The purpose of this chapter is therefore rather more modest; we shall focus attention on several typical applications of the theory, in widely different contexts, with an emphasis toward illustrating the basic principles. In discussing any particular field of application, however, we have attempted not to be extensive, but instead have chosen to present a novel, or, at least, unfamiliar, aspect of the subject in some detail. (The discussion in Section 6g – of a result due to Casimir – provides a good example of our intentions.) Basic Principles Underlying the Applications Before turning to specific examples, it will be useful to review briefly the principles underlying the applications. We have seen that a symmetry in quantum physics is a transformation on state vectors (active view – vectors in Hilbert space are transformed and operators are kept fixed) and on observables (passive view – vectors in Hilbert space are kept fixed and operators are transformed) such that all probabilities are preserved (Chapter 3, Section 14). Using the Wigner theorem, we found that this led to either a unitary, or an antiunitary, realization of the symmetry by operators.
For pedagogical purposes it is demonstrated that with little effort the customary discussion of rotations in introductory courses can be extended to naturally produce a number of angular momentum operator properties, if coordinate-free rotation operators are used in their exponential form. This form gives rise to a particularly useful coordinate-free representation of the generators of rotations in three-space, from which the student can derive the usual angular momentum formalism for the case j=1 by elementary vector algebra alone. Since in this approach the j=1 formalism appears as a set of relations among simple geometric objects in ordinary space, it admits of a geometric interpretation and will leave the student better prepared for a more profound appreciation of the abstract concepts of the full theory.
Abstract In this chapter we introduce the concept of orbital angular momentum into the mathematical language of quantum mechanics. We discuss the commutation relations of the corresponding operators and their roles as generators of rotations in the context of the theory of Lie groups and Lie algebras, focusing on the three-dimensional rotation group SO(3). We further examine how scalar and vector-valued operators transform under spatial rotations. We then turn to the derivation of the eigenfunctions and eigenvalues of the angular-momentum operators, for which we follow a dual approach in analogy to that employed for the harmonic oscillator in Chapter 5. Using both the algebraic ladder-operator method and an analytical method using spherical polar coordinates we discover the relevant azimuthal and magnetic quantum numbers and their relation to the spherical harmonics and the Legendre polynomials
Introduction The space of turns was shown in the preceding chapter to be the carrier space of the defining (fundamental) representation of the group SU (2) * SU (2) – the group of the symmetric top. We shall show in the present chapter how the complete representation theory of this structure can be obtained from a mapping (the generalized Jordan map) that maps the generic turn into an operator (the matrix boson operator) acting in a Hilbert space. By means of this construction we shall obtain a unified presentation of the angular momentum states, the rotation matrices, and the Wigner coefficients as well. An interesting aspect of this technique is that it leads automatically to a view of the Wigner coefficients as a form of discretized rotation matrix (Section 8 below), which in turn implies a relationship between the Wigner coefficients and Jacobi polynomials (Gel'fand et al . [1, Supplement III]). The key idea behind this unified presentation – the Jordan mapping of the turn into a matrix boson – is of more general validity than the application made here. To put this structure in a larger context we first develop, in some detail, the techniques of the boson calculus . It is hoped that this digression does not break the thread of the development too badly. Excursus on the Boson Calculus The harmonic oscillator . The boson calculus originated in the treatment of a basic physical problem, the quantum mechanics of the linear harmonic oscillator.
General remarks As already mentioned in the Introduction, the exact solution of the main equation of quantum mechanics – the Schrödinger equation – lies beyond the potentialities of modern mathematics and computer technology. But a number of important inferences about the behaviour, structure and properties of a given quantum-mechanical many-particle system can be drawn without solving this equation, just by examining its symmetry properties. Symmetry concepts come about in physics in two ways. First, since any physical process occurs in a real space, we have to make use of one or another coordinate system. The isotropy and homogeneity of space make physically meaningful only those mathematical relationships that remain unchanged under rotations of the axes of the coordinate system, and that impose fairly rigorous constraints on the possible physical laws. Second, every physical object and process features a symmetry which should be taken into account by the physical theory. A common idea underlying particular forms of symmetry is the invariance of a system under a certain set (group) of transformations. The normally considered forms of symmetry are rotational symmetry, which is based on the equivalence of all directions in space, and permutation symmetry, which is caused by identical particles. The operations of the geometrical symmetry group are responsible for appropriate conservation laws. So, the rotational symmetry of a closed system gives rise to the law of conservation of angular momentum. The group of rotations of a three-dimensional space stands apart in atomic spectroscopy. This is mostly due to the high accuracy of the central field approximation, on which the entire modern theory of complex atoms and ions is based.
It has been the purpose of the monograph Angular Momentum in Quantum Physics (AMQP) to develop comprehensively those aspects of angular momentum theory that are required in carrying out research in modern physics and chemistry. The emphasis there was principally on physical concepts and the symmetry principles that underlie the general applicability of angular momentum theory to a broad area of physical phenomena. Mathematical techniques were introduced within the context of the physical concepts themselves. Physical applications of angular momentum theory are to a large extent applications of specific properties of Wigner or Racah functions (more generally of 3 n-j coefficients) or of the representation functions themselves. Such applications tend to emphasize the “numerical” aspects of these functions and thus obscure the relationships to other areas of mathematics. The purpose of the present monograph is to show by specific examples the many interrelations that exist between concepts originating in angular momentum theory and various areas of mathematics. It turns out that this is a substantial task—the diversity of the interrelations is far greater than might be thought. Even a brief acquaintance with the contents of AMQP will show that the concept that recurs again and again in physical applications is that of an irreducible tensor operator with respect to a group [in our case, SU (2), the quantal rotation group]. Indeed, it is this concept that carries the mathematical apparatus of the physical theory beyond the related but much simpler results of the Lie algebraic theory of the angular momentum itself and the implied representation theory of the group SU (2).