Institute of Physics eBooks
Symmetry in quantum mechanics
Abstract
Symmetry in quantum mechanicsRoughly speaking, a symmetry of some mathematical object is an invertible transformation that leaves all relevant structure as it is.Thus a symmetry of a set is just a bijection (as sets have no further structure, whence invertibility is the only demand on a symmetry), a symmetry of a topological space is a homeomorphism, a symmetry of a Banach space is a linear isometric isomorphism, and, crucially important for this chapter, a symmetry of a Hilbert space H is a unitary operator, i.e., a linear map u : H → H satisfying one and hence all of the following equivalent conditions:• u is invertible and preserves the inner product, i.e., uϕ, uψ = ϕ, ψ (ϕ, ψ ∈ H).The discussion of symmetries in quantum physics is based on the above idea, but the mathematically obvious choices need not be the physically relevant ones.Even in elementary quantum mechanics, where A = B(H), i.e., the C*-algebra of all bounded operators on some Hilbert space H, the concept of a symmetry is already diverse.The main structures whose symmetries we shall study in this chapter are:1.The normal pure state space P 1 (H), i.e., the set of one-dimensional projections on H, with transition probability τ : P 1 (H) × P 1 (H) → [0, 1] defined by (2.44).2. The normal state space D(H), i.e. the convex set of density operators ρ on H. The self-adjoint operators B(H)sa on H, seen as a Jordan algebra (see below).4. The effects E (H) = [0, 1] B(H) , seen as a convex partially ordered set (poset). 5.The projections P(H) on H, seen as an orthocomplemented lattice.6.The unital commutative C*-subalgebras C (B(H)) of B(H), seen as a poset.Each of these structures comes with its own notion of a symmetry, but the main point of this chapter will be to show these notions are equivalent, corresponding in all cases to either unitary or-surprisingly-anti-unitary operators, both merely defined up to a phase.The latter subtlety will open the world of projective unitary group representation to quantum mechanics (without which the existence of spin-1 2 particles such as electrons, and therewith also of ourselves, would be impossible).