Solution of time-dependent problems in quantum mechanics

Rafael Almeida, Daniel A. Morales

Exact analytical solutions are found for the quantum mechanical problem of a particle subject to a time-dependent potential with time-dependent boundary conditions. The method of solution employs time-dependent invariants, rescaling of space and time variables along with an unitary transformation. Several applications are discussed. © 1997 John Wiley & Sons, Inc. Int J Quant Chem 63: 827–833, 1997

Martin Formánek

Paul H. E. Meijer, Tomoyasu Tanaka

Although the weakly coupled double pendulum seems to be a standard illustration in classical mechanics, it is seldom mentioned in quantum mechanics. It shares this fate with the damped harmonic oscillator, but while there is a good reason for avoiding the last one in quantum mechanics, the first can be treated with the same procedure as in classical mechanics. The exact solution is then compared with the solutions obtained by time-independent and time-dependent perturbation methods. It turns out that there are some additional steps to be taken, compared to the usual textbook treatment of the time-independent perturbation theory, due to the fact that all the levels of the unperturbed problem are degenerate. It is shown that the diagonalization of the secular matrix in the time-independent problem is equivalent to a problem of rotation of angular momentum operators in function space. The time-dependent problem needs, again, additional steps due to the degeneracy, and it yields the well-known beat-behavior.

Junhao, Z.

Quantum mechanics take the sum of first finite order approximate solutions of time-dependent perturbation to substitute the exact solution. From the point of mathematics, it may be correct only in the convergent region of the time-dependent perturbation series. Where is the convergent region of this series? Quantum mechanics did not answer this problem. However it is relative to the question, can we use the Schrodinger equation to describe the transition processes? So it is the most important unsettling problem of physical theory. We find out the time-dependent approximate solution for arbitrary and the exact solution. Then we can prove that: (1) In the neighborhood of the conservation of energy, the series is divergent. The basic error of quantum mechanics is using the sum of the first finite orders approximate solutions to substitute the exact solution in this divergent region. It leads to an infinite error. So the Fermi golden rule is not a mathematically reasonable inference of the. Schrodinger equation (2) The transiton probability per unit time deduced from the exact solution of Schrodinger equation cannot describe the transition processes. This paper is only a prime discussion.