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IMPERIAL COLLEGE PRESS eBooks

The Schrödinger Equation, Waves and Wave Packets

Published Mar 1, 2010• 1 citation
Publisher
DOI
10.1142/9781848163027_0001

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The Schrödinger Wave Equation

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Time-independent wave-packet forms of the Schr\"odinger equation (TIWSE) and Lippmann-Schwinger equation (TIWLSB) have been derived by a partial time-to-energy Fourier transform of L2{\mathit{L}}^{2}L2 wave-packet solutions to the time-dependent Schr\"odinger equation. The new equations retain the initial wave packet \ensuremath{\chi}(t0{\mathit{t}}_{0}t0​) as a ``universal source'' of scattered waves, which applies for all collision energies E contained in the initial wave packet. The relationship between the solution ${\mathrm{\ensuremath{\Psi}}}_{\mathit{t}0}$(E) of the TIWSE or TIWLSE and the scattering solution ${\mathrm{\ensuremath{\Psi}}}^{(+)}$(E) of the standard time-independent Lippmann-Schwinger or Schr\"odinger equation is given and the method illustrated by a computational application.
We discuss nonspreading wave packets in one dimensional Schrödinger equation. We derive general rules for constructing nonspreading wave packets from a general potential V(x,t)\textmd{V}(x,t)V(x,t). The essential ingredients of a nonspreading wave packet, the shape function f(x)f(x)f(x), the motion d(t)d(t)d(t), the phase function ϕ(x,t)ϕ(x,t)ϕ(x,t) are derived. Since the form of the shape of a nonspreading wave packet does not change in time, the shape equation should be time independent. We show that the shape function f(x)f(x)f(x) is the eigenfunction of the time independent Schrödinger equation with an effective potential VeffV_{\textmd{eff}}Veff​ and an energy EeffE_{\textmd{eff}}Eeff​. We derive nonspreading wave packets found by Schrödinger, Senitzky, and Berry and Balazs as examples. We show that most stationary potentials can only support stationary nonspreading wave packets. We show how to construct moving nonspreading wave packets from time dependent potentials, which drive nonspreading wave packets into an arbitrary motion.