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Wiley eBooks

Electronic Correlation Mapping

Jamal Berakdar

Published Jan 1, 2006• 3 citations
Publisher

Abstract

An up-to-date selection of applications of correlation spectroscopy, in particular as far as the mapping of properties of correlated many-body systems is concerned. The book starts with a qualitative analysis of the outcome of the two-particle correlation spectroscopy of localized and delocalized electronic systems as they occur in atoms and solids. The second chapter addresses how spin-dependent interactions can be imaged by means of correlation spectroscopy, both in spin-polarized and extended systems. A further chapter discusses possible pathways for the production of interacting two-particle continuum states. After presenting some established ways of quantifying electronic correlations and pointing out the relationship to correlation spectroscopy, the author addresses in a separate chapter the electron-electron interaction in extended systems, and illustrates the ideas by some applications to fullerenes and metal clusters. The last two chapters are devoted to the investigation of the potential of two-particle spectroscopy in studying ordered surfaces and disordered samples. Throughout the book the material is analyzed using rather qualitative arguments, and the results of more sophisticated theories serve the purpose of endorsing the suggested physical scenarios. The foundations of some of these theories have been presented in a corresponding volume entitled "Concepts of Highly Excited Electronic Systems" (3-527-40335-3).

DOI
10.1002/9783527618521

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An up-to-date selection of applications of correlation spectroscopy, in particular as far as the mapping of properties of correlated many-body systems is concerned. The book starts with a qualitative analysis of the outcome of the two-particle correlation spectroscopy of localized and delocalized electronic systems as they occur in atoms and solids. The second chapter addresses how spin-dependent interactions can be imaged by means of correlation spectroscopy, both in spin-polarized and extended systems. A further chapter discusses possible pathways for the production of interacting two-partic

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X. Zotos

This book and the accompanying software (PC Diskette) is a toolbox for performing a set of numerical simulations on simple quantum mechanical problems. It is one in a series of similar books (CUPS) covering different fields in physics from classical mechanics to nuclear and particle physics. Each chapter of the book is written by a different author and deals with a different physical problem. The choice of problems is standard, e.g. bound state and scattering problems in one and three dimensions, quantum mechanical time development; the exceptions are, a study of identical particles and electron states in a one dimensional lattice, an example from solid state physics. Although the chapters are self-contained and can be studied independently (at the expense of some minor duplication of material), care was taken with a uniform style of presentation and similar format in numerical simulations. As a result, it is easy to proceed in the study of the different problems having understood the technical possibilities of one simulation. Each chapter starts with a section presenting the basic theoretical concepts to be studied using the numerical simulation. It is followed by a section with a short description of the numerical technique used and an extensive series of suggestions for problems and quantities to experiment with, using the computer codes provided. A final section describes in detail how to run the computer programs. This book is not, and is not intended to be, a textbook for learning quantum mechanics nor a textbook of numerical analysis. Nevertheless, I find the theoretical presentation clear and straightforward enough for its purpose. The extensive and up to date list of references to books and research articles at the end of each chapter is also very helpful. Technically, I found the software easy to install and, after some initial testing, easy to run. The produced plots are clear and the use of units of atomic dimension gives a touch of reality to the simulations. In contrast to other similar books, this is not a `picture' book of quantum mechanics where results of numerical simulations are illustrated; here the reader is given the necessary means to play and discover for himself the properties of quantum mechanical systems. I believe that this book, used by teachers for demonstrations and students for independent study, provides a versatile tool for numerical experimentation in quantum mechanics.

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Modern Physics for Engineers

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After a short review of some essential concepts of classical physics (with a discussion of the so-called `scientific method', which is rarely found in textbooks of this kind), including the classical description of particles and waves, together with a sketch of statistical thermodynamics, the basics of quantum mechanics are introduced. The third chapter then treats systems of identical particles and their statistics, as well as the statistics of discrete energy levels. This is followed by an extensive presentation of the behaviour of quantum particles in periodic potentials with obvious applications to crystalline materials, including metals, insulators, semiconductors and superconductors. The band structure of some special materials, intrinsic carrier concentrations and electrons in metals are further topics of this main chapter. In most quantum mechanics textbooks the subjects of the fifth chapter, quantum wells, harmonic oscillators and the hydrogen atom, are usually introduced before a discussion of periodic potentials, but the author's exposition makes it quite plausible to place them afterwards. The concept of tunnelling through potential barriers and important application examples, ranging from ohmic contacts to scanning tunnelling microscopy and even radioactivity, make up the next chapter. Some approximation methods, i.e. stationary perturbation theory with applications to coupled wells, and the variational method, are treated in the next chapter. The final chapter dealing with quantum mechanics then is concerned with scattering and collision problems, again, of course, with examples from solid state physics. This last chapter, however, looks somehow merely added on, since it introduces only quite briefly the theory of special relativity -almost certainly in order not to leave out this important revolution of modern physics. Three appendices, on Fermi's Golden Rule, Boltzmann's transport theory and quantum interference devices, round off the contents. The book abounds with links to modern technologies that have evolved out of quantum mechanics (with, of course, the exception of the last chapter on special relativity). To the reviewer this constitutes its outstanding value as a textbook on quantum mechanics for engineering students. In addition, about 100 solved numerical examples in the text illustrate very lucidly some of the more abstract concepts, and at the end of the chapters altogether 200 further problems are posed. Although some of the concepts and results of quantum mechanics are introduced in a seemingly ad hoc manner, nevertheless the book as a whole certainly represents a valuable teaching tool at engineering schools; even physics majors may profit from the wealth of technical applications not usually found in their textbooks on quantum mechanics.

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Many-Body Quantum Theory in Condensed Matter Physics—An Introduction

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This is undoubtedly an ambitious book. It aims to provide a wide ranging, yet self-contained and pedagogical introduction to techniques of quantum many-body theory in condensed matter physics, without losing mathematical `rigor' (which I hope means rigour), and with an eye on physical insight, motivation and application. The authors certainly bring plenty of experience to the task, the book having grown out of their graduate lectures at the Niels Bohr Institute in Copenhagen over a five year period, with the feedback and refinement this presumably brings. The book is also of course ambitious in another sense, for it competes in the tight market of general graduate/advanced undergraduate texts on many-particle physics. Prospective punters will thus want reasons to prefer it to, or at least give it space beside, well established texts in the field. Subject-wise, the book is a good mix of the ancient and modern, the standard and less so. Obligatory chapters deal with the formal cornerstones of many-body theory, from second quantization, time-dependence in quantum mechanics and linear response theory, to Green's function and Feynman diagrams. Traditional topics are well covered, including two chapters on the electron gas, chapters on phonons and electron–phonon coupling, and a concise account of superconductivity (confined, no doubt judiciously, to the conventional BCS case). Less mandatory, albeit conceptually vital, subjects are also aired. These include a chapter on Fermi liquid theory, from both semi-classical and microscopic perspectives, and a freestanding account of one-dimensional electron gases and Luttinger liquids which, given the enormity of the topic, is about as concise as it could be without sacrificing clarity. Quite naturally, the authors' own interests also influence the choice of material covered. A persistent theme, which brings a healthy topicality to the book, is the area of transport in mesoscopic systems or nanostructures. Two chapters, some fifty pages of the book, are devoted to electron transport in mesoscopic systems; the one on interacting systems is preceded by a brief account of equation of motion techniques–a relative rarity in a general text, used here to provide background to subsequent discussion of the Coulomb blockade in quantum dots. So does it work, and will it find a niche beside other established, wide ranging texts? On the whole I think the answer has to be yes. To begin with, the book is well organised and user-friendly, which must surely appeal to students (and their mentors). The chapters are typically bite-sized and digestible. Each is accompanied by a summary/outlook, which in doing just that attempts to place the specific topic in a wider context, together with a set of problems that illustrate, and in many cases expand substantially on, the basic subject matter. A particularly healthy feature of the book is the extent to which the authors have sought where possible to include physical and/or material applications of basic theory, thereby enlivening old material and enhancing appreciation of the new. The first chapter on the electron gas, for example, introduces the reader to a range of material examples, including 2D heterostructures, carbon nanotubes and quantum dots. A chapter on the formalism of Green's functions takes time out to explain how the single-particle spectral function can be measured by tunnelling spectroscopy, while discussion of impurity scattering and conductivity is refreshed by consideration of weak localization in bulk and mesoscopic systems, and the phenomenon of universal conductance fluctuations. And so on: in a text that could readily descend to the purely formal, the authors have clearly taken seriously the task of incorporating relevant, topical applications of the underlying theory. In a book as wide ranging as this any reviewer is of course bound to perceive the occasional deficiency. I felt for example that some aspects of the discussion of conductance in quantum dots, notably the Coulomb blockade and the Kondo effect, were not quite up to scratch—a touch unbalanced in coverage perhaps (no serious mention of renormalization or scaling, even perturbative), with the odd conceptual error creeping in, and the Kondo effect appearing more mysterious than it really is, possibly in part because consideration of it appears before the chapter on Fermi liquid theory, in which the effect is firmly rooted. But let me not miss the bigger picture: I don't doubt this is a pretty impressive book overall, likely to have broad appeal to budding theorists and adventurous experimentalists, either as a course textbook or—for the slave to garret or lab—as a serious source for self-study. So make a space on your bookshelves.

Journal of Physics A Mathematical and General•Feb 10, 2005•314 citations

Beyond the single-site approximation in DMFT

Richard M. Martin, Lucia Reining, David M. Ceperley

The previous chapter is devoted to the formulation of DMFT and applications that are exact in the limit of infinite dimensions; however, in finite dimensions this is only a single-site approximation. The present chapter is devoted to clusters and other methods to treat correlation between sites. The equations are derived in a unified way, applicable to a single site or a cluster. For a cluster with more than one site there are various ways to choose the boundary conditions and the embedding procedure, and special care must be taken to satisfy causality and translation invariance. A few selected applications illustrate different techniques and results for Hubbard-type models. The essential features of DMFT are brought out in the previous chapter in the simplest form: the single-site approximation in which correlation between sites can be neglected. In this case the self-energy due to interactions can be calculated using an auxiliary system of a single site embedded in an effective medium that represents the surrounding crystal. The resulting many-body problem is equivalent to an Anderson impurity model that must be solved self-consistently. The results are exact for infinite dimensions d → ∞; however, in any finite dimension, i.e., real systems, this is just a mean-field approximation analogous to the Weiss mean field in magnetic systems or the CPA for disordered alloys. There are, however, many important properties and phenomena that require us to go beyond mean-field approximations. For example, basic questions concerning the nature of a metal–insulator transition can be established only by quantitative assessment of the correlations between different sites. Is a single site sufficient (the central idea in the arguments by Mott discussed in Sec. 3.2) or is correlation between sites (for example, an ordered antiferromagnetic state) essential for interactions to lead to an insulating state? A complete theory must establish the range of correlation needed to understand the mechanisms and to make quantitative calculations. A striking example that requires a k -dependent self-energy is the opening of a “pseudogap” in only part of the Brillouin zone in a high-temperature superconductor, as illustrated in Fig. 2.16. This chapter is devoted to methods that go beyond the single-site approximation to take into account interactions and correlations between electrons on sites.

Cambridge University Press eBooks•May 31, 2016•0 citations
An up-to-date selection of applications of correlation spectroscopy, in particular as far as the mapping of properties of correlated many-body systems is concerned. The book starts with a qualitative analysis of the outcome of the two-particle correlation spectroscopy of localized and delocalized electronic systems as they occur in atoms and solids. The second chapter addresses how spin-dependent interactions can be imaged by means of correlation spectroscopy, both in spin-polarized and extended systems. A further chapter discusses possible pathways for the production of interacting two-particle continuum states. After presenting some established ways of quantifying electronic correlations and pointing out the relationship to correlation spectroscopy, the author addresses in a separate chapter the electron-electron interaction in extended systems, and illustrates the ideas by some applications to fullerenes and metal clusters. The last two chapters are devoted to the investigation of the potential of two-particle spectroscopy in studying ordered surfaces and disordered samples. Throughout the book the material is analyzed using rather qualitative arguments, and the results of more sophisticated theories serve the purpose of endorsing the suggested physical scenarios. The foundations of some of these theories have been presented in a corresponding volume entitled "Concepts of Highly Excited Electronic Systems" (3-527-40335-3).
An up-to-date selection of applications of correlation spectroscopy, in particular as far as the mapping of properties of correlated many-body systems is concerned. The book starts with a qualitative analysis of the outcome of the two-particle correlation spectroscopy of localized and delocalized electronic systems as they occur in atoms and solids. The second chapter addresses how spin-dependent interactions can be imaged by means of correlation spectroscopy, both in spin-polarized and extended systems. A further chapter discusses possible pathways for the production of interacting two-partic
The main aim of this book is to give a self-contained and representative cross section through present-day research in solid-state physics. This covers metallic and mesoscopic transport, localization by disorder and superconductivity, including questions related to high-temperature superconductors and to heavy fermion systems. An important part of the book is devoted to itinerant-electron magnetism, discussing paramagnons, strong correlation, magnetization fluctuations and spin density waves. All the formal tools used in these chapters are developed in the first part of the book which contains a thorough discussion of second quantization, and of perturbation theory for an arbitrary complex time path, and also describes the functional approach to Feynman diagrams, including general ward identities. Each chapter contains an extensive list of the relevant literature and a series of problems with detailed solutions which complement the main text. The book is meant as both a course and a research tool.
This book and the accompanying software (PC Diskette) is a toolbox for performing a set of numerical simulations on simple quantum mechanical problems. It is one in a series of similar books (CUPS) covering different fields in physics from classical mechanics to nuclear and particle physics. Each chapter of the book is written by a different author and deals with a different physical problem. The choice of problems is standard, e.g. bound state and scattering problems in one and three dimensions, quantum mechanical time development; the exceptions are, a study of identical particles and electron states in a one dimensional lattice, an example from solid state physics. Although the chapters are self-contained and can be studied independently (at the expense of some minor duplication of material), care was taken with a uniform style of presentation and similar format in numerical simulations. As a result, it is easy to proceed in the study of the different problems having understood the technical possibilities of one simulation. Each chapter starts with a section presenting the basic theoretical concepts to be studied using the numerical simulation. It is followed by a section with a short description of the numerical technique used and an extensive series of suggestions for problems and quantities to experiment with, using the computer codes provided. A final section describes in detail how to run the computer programs. This book is not, and is not intended to be, a textbook for learning quantum mechanics nor a textbook of numerical analysis. Nevertheless, I find the theoretical presentation clear and straightforward enough for its purpose. The extensive and up to date list of references to books and research articles at the end of each chapter is also very helpful. Technically, I found the software easy to install and, after some initial testing, easy to run. The produced plots are clear and the use of units of atomic dimension gives a touch of reality to the simulations. In contrast to other similar books, this is not a `picture' book of quantum mechanics where results of numerical simulations are illustrated; here the reader is given the necessary means to play and discover for himself the properties of quantum mechanical systems. I believe that this book, used by teachers for demonstrations and students for independent study, provides a versatile tool for numerical experimentation in quantum mechanics.
After a short review of some essential concepts of classical physics (with a discussion of the so-called `scientific method', which is rarely found in textbooks of this kind), including the classical description of particles and waves, together with a sketch of statistical thermodynamics, the basics of quantum mechanics are introduced. The third chapter then treats systems of identical particles and their statistics, as well as the statistics of discrete energy levels. This is followed by an extensive presentation of the behaviour of quantum particles in periodic potentials with obvious applications to crystalline materials, including metals, insulators, semiconductors and superconductors. The band structure of some special materials, intrinsic carrier concentrations and electrons in metals are further topics of this main chapter. In most quantum mechanics textbooks the subjects of the fifth chapter, quantum wells, harmonic oscillators and the hydrogen atom, are usually introduced before a discussion of periodic potentials, but the author's exposition makes it quite plausible to place them afterwards. The concept of tunnelling through potential barriers and important application examples, ranging from ohmic contacts to scanning tunnelling microscopy and even radioactivity, make up the next chapter. Some approximation methods, i.e. stationary perturbation theory with applications to coupled wells, and the variational method, are treated in the next chapter. The final chapter dealing with quantum mechanics then is concerned with scattering and collision problems, again, of course, with examples from solid state physics. This last chapter, however, looks somehow merely added on, since it introduces only quite briefly the theory of special relativity -almost certainly in order not to leave out this important revolution of modern physics. Three appendices, on Fermi's Golden Rule, Boltzmann's transport theory and quantum interference devices, round off the contents. The book abounds with links to modern technologies that have evolved out of quantum mechanics (with, of course, the exception of the last chapter on special relativity). To the reviewer this constitutes its outstanding value as a textbook on quantum mechanics for engineering students. In addition, about 100 solved numerical examples in the text illustrate very lucidly some of the more abstract concepts, and at the end of the chapters altogether 200 further problems are posed. Although some of the concepts and results of quantum mechanics are introduced in a seemingly ad hoc manner, nevertheless the book as a whole certainly represents a valuable teaching tool at engineering schools; even physics majors may profit from the wealth of technical applications not usually found in their textbooks on quantum mechanics.
This is undoubtedly an ambitious book. It aims to provide a wide ranging, yet self-contained and pedagogical introduction to techniques of quantum many-body theory in condensed matter physics, without losing mathematical `rigor' (which I hope means rigour), and with an eye on physical insight, motivation and application. The authors certainly bring plenty of experience to the task, the book having grown out of their graduate lectures at the Niels Bohr Institute in Copenhagen over a five year period, with the feedback and refinement this presumably brings. The book is also of course ambitious in another sense, for it competes in the tight market of general graduate/advanced undergraduate texts on many-particle physics. Prospective punters will thus want reasons to prefer it to, or at least give it space beside, well established texts in the field. Subject-wise, the book is a good mix of the ancient and modern, the standard and less so. Obligatory chapters deal with the formal cornerstones of many-body theory, from second quantization, time-dependence in quantum mechanics and linear response theory, to Green's function and Feynman diagrams. Traditional topics are well covered, including two chapters on the electron gas, chapters on phonons and electron–phonon coupling, and a concise account of superconductivity (confined, no doubt judiciously, to the conventional BCS case). Less mandatory, albeit conceptually vital, subjects are also aired. These include a chapter on Fermi liquid theory, from both semi-classical and microscopic perspectives, and a freestanding account of one-dimensional electron gases and Luttinger liquids which, given the enormity of the topic, is about as concise as it could be without sacrificing clarity. Quite naturally, the authors' own interests also influence the choice of material covered. A persistent theme, which brings a healthy topicality to the book, is the area of transport in mesoscopic systems or nanostructures. Two chapters, some fifty pages of the book, are devoted to electron transport in mesoscopic systems; the one on interacting systems is preceded by a brief account of equation of motion techniques–a relative rarity in a general text, used here to provide background to subsequent discussion of the Coulomb blockade in quantum dots. So does it work, and will it find a niche beside other established, wide ranging texts? On the whole I think the answer has to be yes. To begin with, the book is well organised and user-friendly, which must surely appeal to students (and their mentors). The chapters are typically bite-sized and digestible. Each is accompanied by a summary/outlook, which in doing just that attempts to place the specific topic in a wider context, together with a set of problems that illustrate, and in many cases expand substantially on, the basic subject matter. A particularly healthy feature of the book is the extent to which the authors have sought where possible to include physical and/or material applications of basic theory, thereby enlivening old material and enhancing appreciation of the new. The first chapter on the electron gas, for example, introduces the reader to a range of material examples, including 2D heterostructures, carbon nanotubes and quantum dots. A chapter on the formalism of Green's functions takes time out to explain how the single-particle spectral function can be measured by tunnelling spectroscopy, while discussion of impurity scattering and conductivity is refreshed by consideration of weak localization in bulk and mesoscopic systems, and the phenomenon of universal conductance fluctuations. And so on: in a text that could readily descend to the purely formal, the authors have clearly taken seriously the task of incorporating relevant, topical applications of the underlying theory. In a book as wide ranging as this any reviewer is of course bound to perceive the occasional deficiency. I felt for example that some aspects of the discussion of conductance in quantum dots, notably the Coulomb blockade and the Kondo effect, were not quite up to scratch—a touch unbalanced in coverage perhaps (no serious mention of renormalization or scaling, even perturbative), with the odd conceptual error creeping in, and the Kondo effect appearing more mysterious than it really is, possibly in part because consideration of it appears before the chapter on Fermi liquid theory, in which the effect is firmly rooted. But let me not miss the bigger picture: I don't doubt this is a pretty impressive book overall, likely to have broad appeal to budding theorists and adventurous experimentalists, either as a course textbook or—for the slave to garret or lab—as a serious source for self-study. So make a space on your bookshelves.
The previous chapter is devoted to the formulation of DMFT and applications that are exact in the limit of infinite dimensions; however, in finite dimensions this is only a single-site approximation. The present chapter is devoted to clusters and other methods to treat correlation between sites. The equations are derived in a unified way, applicable to a single site or a cluster. For a cluster with more than one site there are various ways to choose the boundary conditions and the embedding procedure, and special care must be taken to satisfy causality and translation invariance. A few selected applications illustrate different techniques and results for Hubbard-type models. The essential features of DMFT are brought out in the previous chapter in the simplest form: the single-site approximation in which correlation between sites can be neglected. In this case the self-energy due to interactions can be calculated using an auxiliary system of a single site embedded in an effective medium that represents the surrounding crystal. The resulting many-body problem is equivalent to an Anderson impurity model that must be solved self-consistently. The results are exact for infinite dimensions d → ∞; however, in any finite dimension, i.e., real systems, this is just a mean-field approximation analogous to the Weiss mean field in magnetic systems or the CPA for disordered alloys. There are, however, many important properties and phenomena that require us to go beyond mean-field approximations. For example, basic questions concerning the nature of a metal–insulator transition can be established only by quantitative assessment of the correlations between different sites. Is a single site sufficient (the central idea in the arguments by Mott discussed in Sec. 3.2) or is correlation between sites (for example, an ordered antiferromagnetic state) essential for interactions to lead to an insulating state? A complete theory must establish the range of correlation needed to understand the mechanisms and to make quantitative calculations. A striking example that requires a k -dependent self-energy is the opening of a “pseudogap” in only part of the Brillouin zone in a high-temperature superconductor, as illustrated in Fig. 2.16. This chapter is devoted to methods that go beyond the single-site approximation to take into account interactions and correlations between electrons on sites.