Sudip Chakravarty Department of Physics and Astronomy, University of California Los Angeles, Los Angeles, CA 90095-1547, U.S.A. This chapter reflects my subjective choice of topics. My interest falls into three distinct categories. The intense interest in the problem of dissipation in quantum systems began at the time when macroscopic quantum tunneling and coherence in superconducting quantum interference devices (SQUIDs) were proposed. This subject has seen considerable developments over the past three decades both in theory and in experiments [1]. An important problem in this subject is a particle in a double well potential coupled to a bath consisting of an infinite number of harmonic oscillators providing a linear dissipation to the particle, in other words coupled to an Ohmic heat bath in the language of electrical engineering [2]. Yet, it is hardly recognized that this problem constitutes one of the simplest models of quantum criticality [3]. Thus, unsurprisingly, little attention has been paid over the years to experimentally explore this critical phenomenon. It remains equally unrecognized that the same model holds a germ of the quantum-to-classical transition much discussed in measurement theory.1 Here I have attempted to draw a parallel with an even more elementary model of Coleman and Hepp [4], which actually contains no dissipation. Nonetheless the two problems are united by the dictum that for infinitely many degrees of freedom two distinct states of matter cannot be unitarily related. A particle in a double well coupled to a dissipative environment is indeed a system with an infinite number of degrees of freedom. Of course, the Coleman-Hepp model can be supplemented by dissipation to bring the two models closer, but the basic issue with respect to measurement is clearer in its original form.
Sudip Chakravarty Department of Physics and Astronomy, University of California Los Angeles, Los Angeles, CA 90095-1547, U.S.A. This chapter reflects my subjective choice of topics. My interest falls into three distinct categories. The intense interest in the problem of dissipation in quantum systems began at the time when macroscopic quantum tunneling and coherence in superconducting quantum interference devices (SQUIDs) were proposed. This subject has seen considerable developments over the past three decades both in theory and in experiments [1]. An important problem in this subject is a particle in a double well potential coupled to a bath consisting of an infinite number of harmonic oscillators providing a linear dissipation to the particle, in other words coupled to an Ohmic heat bath in the language of electrical engineering [2]. Yet, it is hardly recognized that this problem constitutes one of the simplest models of quantum criticality [3]. Thus, unsurprisingly, little attention has been paid over the years to experimentally explore this critical phenomenon. It remains equally unrecognized that the same model holds a germ of the quantum-to-classical transition much discussed in measurement theory.1 Here I have attempted to draw a parallel with an even more elementary model of Coleman and Hepp [4], which actually contains no dissipation. Nonetheless the two problems are united by the dictum that for infinitely many degrees of freedom two distinct states of matter cannot be unitarily related. A particle in a double well coupled to a dissipative environment is indeed a system with an infinite number of degrees of freedom. Of course, the Coleman-Hepp model can be supplemented by dissipation to bring the two models closer, but the basic issue with respect to measurement is clearer in its original form.
Quantum dissipation has been the object of study within the physics and chemistry communities for many years. Despite this, the field is in constant evolution, largely due to the fact that novel systems where the understanding of dissipation and dephasing processes is of crucial importance have become experimentally accessible in recent years. Among the ongoing research themes, we mention the defeat of decoherence in solid state-based quantum bits (qubits) (e.g. superconducting qubits or quantum dot based qubits), or dissipation due to non-equilibrium Fermi reservoirs, as is the case for quantum transport through meso- and nanoscale structures. A close inspection of dissipation in such systems reveals that one has to deal with 'unconventional' environments, where common assumptions of, for example, linearity of the bath and/or equilibrium reservoir have to be abandoned. Even for linear baths at equilibrium it might occur that the bath presents some internal structure, due, for example, to the presence of localized bath modes. A large part of this focus issue is devoted to topics related to the rapidly developing fields of quantum computation and information with solid state nanodevices. In these implementations, single and two-qubit gates as well as quantum information transmission takes place in the presence of broadband noise that is typically non-Markovian and nonlinear. On both the experimental and theory side, understanding and defeating such noise sources has become a crucial step towards the implementation of efficient nanodevices. On a more fundamental level, electron and spin transport through quantum dot nanostructures may suffer from 'unconventional' dissipation mechanisms such as the simultaneous presence of spin relaxation and fermionic dissipation, or may represent themselves out of equilibrium baths for nearby mesoscopic systems. Finally, although not expected from the outset, the present collection of articles has revealed that different 'unconventional' questions were still open on the standard harmonic oscillator and spin baths. This includes both fundamental issues, such as the possibility of estimating the specific heat for a free particle in the presence of dissipation, and the development of methods suitable to dealing with long range correlations at zero temperature and with quantum chaotic environments. We believe that the present focus issue on Quantum Dissipation in Unconventional Environments , although certainly not exhaustive, provides an important open-access resource that presents the latest state of the art of research in this field along its different lines. Focus on Quantum Dissipation in Unconventional Environments Contents Coherent control of an effective two-level system in a non-Markovian biomolecular environment J Eckel, J H Reina and M Thorwart Charge transfer dynamics in driven molecular ratchets: quantum Monte Carlo results and rate models L Mühlbacher and J Ankerhold Decoherence in qubits due to low-frequency noise J Bergli, Y M Galperin and B L Altshuler Dephasing by electron–electron interactions in a ballistic Mach–Zehnder interferometer Clemens Neuenhahn and Florian Marquardt Quantum frustration of dissipation by a spin bath D D Bhaktavatsala Rao, Heiner Kohler and Fernando Sols A random matrix theory of decoherence T Gorin, C Pineda, H Kohler and T H Seligman Dissipative dynamics of a biased qubit coupled to a harmonic oscillator: analytical results beyond the rotating wave approximation Johannes Hausinger and Milena Grifoni Dissipative dynamics of a two-level system resonantly coupled to a harmonic mode Frederico Brito and Amir O Caldeira Spin correlations in spin blockade Rafael Sánchez, Sigmund Kohler and Gloria Platero Landau–Zener tunnelling in dissipative circuit QED David Zueco, Peter Hänggi and Sigmund Kohler Quantum oscillations in the spin-boson model: reduced visibility from non-Markovian effects and initial entanglement F K Wilhelm Dynamics of dissipative coupled spins: decoherence, relaxation and effects of a spin-boson bath P Nägele, G Campagnano and U Weiss Spin chain model for correlated quantum channels Davide Rossini, Vittorio Giovannetti and Simone Montangero Finite quantum dissipation: the challenge of obtaining specific heat Peter Hänggi, Gert-Ludwig Ingold and Peter Talkner Dynamics of large anisotropic spin in a sub-ohmic dissipative environment close to a quantum-phase transition Frithjof B Anders Effects of low-frequency noise cross-correlations in coupled superconducting qubits A D'Arrigo, A Mastellone, E Paladino and G Falci From coherent motion to localization: dynamics of the spin-boson model at zero temperature Haobin Wang and Michael Thoss Phonon distributions of a single-bath mode coupled to a quantum dot F Cavaliere, G Piovano, E Paladino and M Sassetti
Dissipation and decoherence in quantum systems have important practical implications, from stabilizing superconductivity in granular materials, to the loss of information stored in qubits. In the models we consider in this chapter, energy dissipation is introduced by coupling a quantum mechanical degree of freedom to a bath of suitably chosen harmonic oscillators. The degrees of freedom of this bath can be integrated out analytically, which leads to an effective action with long-range interactions in imaginary time. We will review and present a number of recently developed efficient cluster Monte Carlo algorithms for various dissipative quantum systems. This chapter is based in large part on Refs. [1, 2] but has been updated with more recent developments, especially in the applications section.
The study of dissipative systems holds significant interest in physics.This thesis aims to explore these phenomena in both classical and quantum regimes.In the first part, we utilize the system-reservoir approach to investigate the dynamics of two Brownian particles immersed in the same bath.Two methods are employed to address this problem: one with bilinear coupling and the other with nonlinear coupling between the particles and the bath.The extension of the system to include two particles with bilinear coupling yields unphysical results, such as free-particle motion for the relative coordinate and a lack of interaction between closely spaced particles.To address this issue, authors have been introduced an exponential coupling.In this work, we propose a method to reconcile both linear and nonlinear couplings.We demonstrate how to derive the same nonlinear dissipation rates starting from the bilinear Lagrangian, achieved through a modified spectral function that explicitly depends on the distance between the particles.Additionally, we implement a modified spectral function to mitigate anomalous diffusion observed in the standard nonlinear model, along with a phenomenological model describing hydrodynamic interaction between a pair of Brownian particles in a viscous fluid.In the quantum regime, we adopt the same system-reservoir approach to investigate the dissipative adaptation hypothesis proposed by Jeremy England.This hypothesis proposes a general thermodynamic mechanism that explains the self-organization of systems through the dissipation of work absorbed from an external drive.In the second part of this thesis, we explore the quantum dynamics of systems subjected to an external drive, evaluating the thermodynamic quantities of a self-organization process.To do so, we utilize a time-dependent spin-boson Hamiltonian that characterizes a particle subject to a metastable double potential with time-dependent parameters controlling the asymmetry of the wells.Our objective is to demonstrate that the asymmetric potential can localize the particle in the unstable side of the well and verify that this transition results in the highest energy absorption.In conclusion, we propose further investigations into the driven spin-boson model to establish a comprehensive theory of the system's evolution and its thermodynamic implications.
The thesis comprises two major themes of quantum statistical dynamics. One is the development of quantum dissipation theory (QDT). It covers the establishment of some basic relations of quantum statistical dynamics, the construction of several nonequivalent complete second-order formulations, and the development of exact QDT. Another is related to the applications of quantum statistical dynamics to a variety of research fields. In particular, unconventional but novel theories of the electron transfer in Debye solvents, quantum transport, and quantum measurement are developed on the basis of QDT formulations. The thesis is organized as follows. In Chapter 1, we present some background knowledge in relation to the afore-mentioned two themes of this thesis. The key quantity in QDT is the reduced density operator ρ(t) ≡ trBρT(t); i.e., the partial trace of the total system and bath composite ρT(t) over the bath degrees of freedom. QDT governs the evolu-tion of reduced density operator, where the effects of bath are treated in a quantum statistical manner. In principle, the reduced density operator contains all dynam-ics information of interest. However, the conventional quantum transport theory is formulated in terms of nonequilibrium Green's function. The newly emerging field of quantum measurement in relation to quantum information and quantum computing does exploit a sort of QDT formalism. Besides the background of the relevant theoretical development, some representative experiments on molecular nanojunctions are also briefly discussed. In Chapter 2, we outline some basic (including new) relations that highlight several important issues on QDT. The content includes the background of nonequi-librium quantum statistical mechanics, the general description of the total compos-ite Hamiltonian with stochastic system-bath interaction, a novel parameterization scheme for bath correlation functions, a newly developed exact theory of driven Brownian oscillator (DBO) systems, and its closely related solvation mode trans-formation of system-bath coupling Hamiltonian in general. The exact QDT of DBO systems is also used to clarify the validity of conventional QDT formulations that involve Markovian approximation. In Chapter 3, we develop three nonequivalent but all complete second-order QDT (CS-QDT) formulations. Two of them are of the conventional prescriptions in terms of time-local dissipation and memory kernel, respectively. The third one is called the correlated driving-dissipation equations of motion (CODDE). This novel CS-QDT combines the merits of the former two for its advantages in both the application and numerical implementation aspects. Also highlighted is the importance of correlated driving-dissipation effects on the dynamics of the reduced system. In Chapter 4, we construct an exact QDT formalism via the calculus on path integrals. The new theory aims at the efficient evaluation of non-Markovian dis-sipation beyond the weak system-bath interaction regime in the presence of time-dependent external field. By adopting exponential-like expansions for bath corre-lation function, hierarchical equations of motion formalism and continued fraction Liouville-space Green's function formalism are established. The latter will soon be used together with the Dyson equation technique for an efficient evaluation of non-perturbative reduced density matrix dynamics. The interplay between system-bath interaction strength, non-Markovian property, and the required level of hierarchy is also studied with the aid of simple spin-boson systems, together with the three proposed schemes to truncate the infinite hierarchy. In Chapter 5, we develop a nonperturbative theory of electron transfer (ET) in Debye solvents. The resulting exact and analytical rate expression is constructed on the basis of the aforementioned continued fraction Liouville-space Green's func-tion formalism, together with the Dyson equation technique. Not only does it re-cover the celebrated Marcus' inversion and Kramers' turnover behaviors, the new theory also shows some distinct quantum solvation effects that can alter the ET mechanism. Moreover, the present theory predicts further for the ET reaction ther-modynamics, such as equilibrium Gibbs free-energy and entropy, some interesting solvent-dependent features that are calling for experimental verification. In Chapter 6, we discuss the constructed QDTs, in terms of their unified math-ematical structure that supports a linear dynamics space, and thus facilitates their applications to various physical problems. The involving details are exemplified with the CODDE form of QDT. As the linear space is concerned, we identify the Schrödinger versus Heisenberg picture and the forward versus backward propaga-tion of the reduced, dissipative Liouville dynamics. For applications we discuss the reduced linear response theory and the optimal control problems, in which the correlated effects of non-Markovian dissipation and field driving are shown to be important. In Chapter 7, we turn to quantum transport, i.e. electric current through molecular or mesoscopic systems under finite applied voltage. By viewing the nonequilibrium transport setup as a quantum open system, we develop a reduced-density-matrix approach to quantum transport. The resulting current is explicitly expressed in terms of the molecular reduced density matrix by tracing out the degrees of freedom of the electrodes at finite bias and temperature. We propose a conditional quantum master equation theory, which is an extension of the conven-tional (or unconditional) QDT by tracing out the well-defined bath subsets indi-vidually, instead of the entire bath degrees of freedom. Both the current and the noise spectrum can be conveniently analyzed in terms of the conditional reduced density matrix dynamics. By far, the QDT (including the conditional one) has only been exploited in a second-order form. A self-consistent Born approximation for the system-electrode coupling is further proposed to recover all existing nonlinear current-voltage behaviors including the nonequilibrium Kondo effect. Transport theory based on the exact QDT formalism will be developed in future. In Chapter 8, we study the quantum measurement of a qubit with a quantum-point-contact detector. On the basis of a unified quantum master equation (a form of QDT), we study the measurement-induced relaxation and dephasing of the qubit . Our treatment pays particular attention on the detailed-balance relation, which is a consequence of properly accounting for the energy exchange between the qubit and detector during the measurement process. We also derive a conditional quantum master equation for quantum measurement in general, and study the readout characteristics of the qubit measurement. Our theory is applicable to the quantum measurement at arbitrary voltage and temperature. A number of remarkable new features are found and highlighted in concern with their possible relevance to future experiments. In Chapter 9, we discuss the further development of QDT, aiming at an effi-cient evaluation of many-electron systems. This will be carried out by reducing the many-particle (Fermion or Boson) QDT to a single-particle one by exploring, e.g. the Wick's contraction theorem. It also results in a time-dependent density func-tional theory (TDDFT) for transport through complex large-scale (e.g. molecules) systems. Primary results of the TDDFT-QDT are reported. In Chapter 10, we summary the thesis, and comment and remark on the future work on both the theoretical and application aspects of QDT.
The past decade has seen a substantial rejuvenation of interest in the study of quantum phase transitions, driven by experiments on cuprate superconductors, heavy fermion materials, organic conductors, and related compounds. Although quantum phase transitions in simple spin systems, like the Ising model in a transverse field, were studied in the early 1970s, much of the subsequent theoretical work examined a particular example: the metal–insulator transition. While this is a subject of considerable experimental importance, the greatest theoretical progress was made for the case of the Anderson transition of non-interacting electrons, which is driven by localization of the electronic states in the presence of a random potential. The critical properties of this transition of noninteracting electrons constituted the primary basis upon which most condensed matter physicists have formed their intuition on the behavior of the systems near a quantum phase transition. However, it is clear that strong electronic interactions play a crucial role in the systems of current interest noted earlier, and simple paradigms for the behavior of such systems near quantum critical points are not widely known. It is the purpose of this book to move interactions to center stage by describing and classifying the physical properties of the simplest interacting systems undergoing a quantum phase transition. The effects of disorder will be neglected for the most part but will be considered in the concluding chapters. Our focus will be on the dynamical properties of such systems at nonzero temperature, and it will become apparent that these differ substantially from the noninteracting case.
For the realistic theoretical descriptions of quantum devices, we have to take the unavoidable coupling to their surrounding environment into account. A lot of effort in theoretical physics has been made to describe decoherence effects and the corresponding quantum to classical transition in the past. In these studies, baths are coupled to certain observables making their behavior more classical. In the most general case, a quantum device is affected by environments coupled to different observables. In this thesis, we study the differences emerging from coupling the bath to different observables. In particular, we investigate the situation, where two baths are coupled simultaneously to two conjugate variables (e.g. xˆ and pˆ, denoted dissipative frustration). We study how the interplay of these two baths can lead to interesting effects. After an introduction of the topic, we discuss the results of this thesis in Part II and Part III. In Part II, we study the effect of quantum tunneling in presence of a dissipative interaction with two Ohmic environments to the position xˆ and/or to the momentum pˆ of a particle. In chapter 2, we consider a symmetric double well potential which is important in the context of coherent state preparation, as its ground state is a superposition of being in the left and in the right well. Using the semiclassical approximation to calculate instanton paths within the path integral method, we find that momentum dissipation enhances the coherent tunnel splitting. In presence of dissipative couplings to xˆ and pˆ, the momentum dissipation acts in favor of the delocalization of the particle shifting the critical coupling strength of the dissipative phase transition induced by the position dissipation. Chapter 3 contains a study of the escape rate out of a metastable well in presence of dissipation. Here we find that the incoherent tunneling rate is exponentially enhanced in presence of momentum dissipation. We further show that the influence of momentum dissipation depends on the slope of the part of barrier the particle escaping through. In presence of both dissipative couplings, we find a non-monotonic behavior of the escape rate as a function of the dissipative couplings strengths. In Part III, we show that it is possible to realize the situation of "dissipative frustration" in Josephson junction chains. In particular, we introduce charge dissipation as a physical realization of the afore introduced momentum coupling. After presenting the circuit elements needed for charge dissipation, we study a chain of Josephson junctions affected by Ohmic baths coupled to the charge and/or the phase. Using a self-consistent harmonic approximation, we determine the phase diagram at zero temperature which exhibits a quantum phase transition between an ordered phase, corresponding to the superconducting state, and a disordered phase, corresponding to the insulating state with localized superconducting charge. Interestingly, we find that the critical line separating the two phases has a non-monotonic behavior as a function of the dissipative coupling strength. Moreover, within the self-consistent harmonic approximation, we analyze the dissipation induced crossover between a first and second order phase transition, showing that dissipative frustration increases the range in which the phase transition is second order. The non-monotonic behavior is also reflected in the purity of the system that quantifies the degree of correlation between the system and the environment, and in the logarithmic negativity as an entanglement measure that encodes the internal quantum correlations in the chain.