Abstract At higher electric fields, the drifting ions are not in thermal equilibrium with the gas of the elementary excitations of the superfluid, and the mobility depends on the field. This chapter presents the experimental results of the ion mobility in the superfluid at higher fields and larger temperatures. The field dependence of the mobility is explained in terms of roton scattering in presence of an enhanced roton density around the charge. Emphasis is given on the discovery of the giant mobility discontinuity at which the excess energy is dissipated by ions creating quantized vortex rings. Ions are captured by them and drift together as a new, single unit called a charged vortex ring. The puzzling issue of the drift velocity discontinuities is also addressed.