Topological order, as a generic phenomenon, not only appears in FQH systems, it can also appear in quantum spin systems. Quantum spin systems even allow the more general quantum order. This chapter develops a mean-field theory for the topological/quantum order in strongly interacting quantum spin systems. The mean-field theory is based on the projective construction (or the slave-particle construction). The chapter introduces the notion of projective symmetry group (PSG) to describe distinct phases that have exactly the same symmetry. PSG allows for the introduction of the notion of quantum order, which is more general then the notion of topological order. Using the mean-field theory, it calculates the phase diagram and phase transitions for quantum spin systems that do not involve change of symmetry. In fact, many phases that are studied do not break any symmetry and correspond to quantum spin liquids. The mean-field theory shows that those spin liquids can have some very exotic properties such as fractionalization, spin-charge separation, emergent gauge bosons and fermions, interacting gapless exactions, etc. The chapter finds that in addition to the symmetry breaking mechanism, PSG and quantum order is another way to produce and protect gapless excitations.
Topological order, as a generic phenomenon, not only appears in FQH systems, it can also appear in quantum spin systems. Quantum spin systems even allow the more general quantum order. This chapter develops a mean-field theory for the topological/quantum order in strongly interacting quantum spin systems. The mean-field theory is based on the projective construction (or the slave-particle construction). The chapter introduces the notion of projective symmetry group (PSG) to describe distinct phases that have exactly the same symmetry. PSG allows for the introduction of the notion of quantum order, which is more general then the notion of topological order. Using the mean-field theory, it calculates the phase diagram and phase transitions for quantum spin systems that do not involve change of symmetry. In fact, many phases that are studied do not break any symmetry and correspond to quantum spin liquids. The mean-field theory shows that those spin liquids can have some very exotic properties such as fractionalization, spin-charge separation, emergent gauge bosons and fermions, interacting gapless exactions, etc. The chapter finds that in addition to the symmetry breaking mechanism, PSG and quantum order is another way to produce and protect gapless excitations.
Quantum spin liquids are novel phases of matter whose physical properties cannot be captured within the conventional framework of phase transitions. These quantum states are characterized by excitations, called spinons, carrying a fractional value of the integer spin. A description based on a mean-field approximation leads to effective gauge theory. Due to this gauge freedom symmetry group operations act via projective symmetry group (PSG) representations, which can be used to classify quantum states beyond the conventional method. This introducing discussion is found in Chapters 2-6. A preceding PSG classification on the square lattice, which took spin rotational symmetry breaking terms into account, showed that the resulting mean-field states could exhibit topologically non-trivial spinon bands. In Chapter 7, only those el- ements of this Classification are studied, which lead to short-ranged mean-field models. The mutual effect of spinons and visons is scrutinized by adding static configurations of a background gauge field. Spinons and visons form composite ob- jects, which in the case of topological spinon bands, are described by Majorana zero modes. An exact mapping corroborates the relation to topological supercon- ductors and vortices. The effect of multiple visons is investigated, and a possible experimental signature is exposed. Chapter 8 explains how spinon mean-field theory can be used to derive a phe- nomenological effective model for the compound Ca 10 Cr 7 O 28 . A material that was recently proposed as a quantum spin liquid. This low-energy theory consists of spinon hopping processes. The underlying bilayer kagome structure can be simpli- fied to an effective honeycomb lattice. The dynamical spin structure factor is calcu- lated and compared to neutron scattering data. It is discussed how f -wave pairing of spinons can explain small deviations from a linear temperature dependency observed in heat capacity measurements at the low temperatures. This pairing mechanism breaks the U (1) invariance group of the pure hopping model and renders a coherent picture of Ca 10 Cr 7 O 28 being a Z 2 quantum spin liquid. Chapter 9 carries out a PSG classification for the simple-, body centered-, and face centered cubic lattices. Despite a large number of possible PSG representations, only very few describe short-ranged mean-field states. These mean-field models are constructed up to third neighbor couplings and calculated in a self-consistent manner. It is found that the energy is lower for non-trivial sign patterns induced by non-trivial representations of the symmetry generators. Higher neighbor extensions, including pairing terms, yield lower mean-field ground state energies compared to extensions with only hopping terms. For the fcc lattice, a first neighbor state could be identified, which exhibits symmetry protected zero-energy modes.
A concept---quantum order---is introduced to describe a new kind of orders that generally appear in quantum states at zero temperature. Quantum orders that characterize the universality classes of quantum states (described by complex ground-state wave functions) are much richer than classical orders that characterize the universality classes of finite-temperature classical states (described by positive probability distribution functions). Landau's theory for orders and phase transitions does not apply to quantum orders since they cannot be described by broken symmetries and the associated order parameters. We introduced a mathematical object---projective symmetry group---to characterize quantum orders. With the help of quantum orders and projective symmetry groups, we construct hundreds of symmetric spin liquids, which have SU(2), U(1), or Z2 gauge structures at low energies. We found that various spin liquids can be divided into four classes: (a) Rigid spin liquid---spinons (and all other excitations) are fully gapped and may have bosonic, fermionic, or fractional statistics. (b) Fermi spin liquid---spinons are gapless and are described by a Fermi liquid theory. (c) Algebraic spin liquid---spinons are gapless, but they are not described by free fermionic-bosonic quasiparticles. (d) Bose spin liquid---low-lying gapless excitations are described by a free-boson theory. The stability of those spin liquids is discussed in detail. We find that stable two-dimensional spin liquids exist in the first three classes (a)--(c). Those stable spin liquids occupy a finite region in phase space and represent quantum phases. Remarkably, some of the stable quantum phases support gapless excitations even without any spontaneous symmetry breaking. In particular, the gapless excitations in algebraic spin liquids interact down to zero energy and the interaction does not open any energy gap. We propose that it is the quantum orders (instead of symmetries) that protect the gapless excitations and make algebraic spin liquids and Fermi spin liquids stable. Since high-Tc superconductors are likely to be described by a gapless spin liquid, the quantum orders and their projective symmetry group descriptions lay the foundation for a spin liquid approach to high-Tc superconductors.
In this thesis, we study the topological phases of quantum spin systems. One project is to investigate a class of anti-ferromagnetic SU(N) Heisenberg models, describing Mott insulators of fermionic ultra-cold alkaline earth atoms on the three-dimensional simple cubic lattice. Our large-N analysis maps a rich phase diagram. One particularly striking state we found spontaneously breaks lattice rotation symmetry, where the cubic lattice breaks up into bilayers, each of which forms a two-dimensional chiral spin liquid state. In the other projects, we study the phenomenon of symmetry fractionalization on anyons as a tool to characterize two-dimensional symmetry enriched topological phases. In particular, we focus on how crystalline symmetries may fractionalize in gapped Z2 spin liquids. If the system has the symmetry of the square lattice, then there are 2080 symmetry fractionalization patterns possible. With exactly solvable models, we realize 487 of these in strictly two-dimensional systems. In addition, we succeed to understand why the remaining patterns cannot be found in the family of models we construct. Some can only appear on the surface of three-dimensional systems with non-trivial point group symmetry protected topological (pgSPT) order, whose boundary degrees of freedom transform non-locally under the symmetries. We construct a simple toy model to show this anomalous crystalline symmetry fractionalization phenomenon associated with a reflection. Moreover, our approach establishes the connection between the pgSPT phases and the topological phases with on-site symmetries in lower dimensions. This insight is very useful for classification of pgSPT orders in general.
In this paper we systematically study a simple class of translation-symmetry protected topological orders in quantum spin systems using slave-particle approach. The lattice spin systems are translation invariant, but may break any other symmetries. We consider topologically ordered ground states that do not spontaneously break any symmetry. Those states can be described by Z2A or Z2B projective symmetry group. We find that the Z2A translation symmetric topological orders can still be divided into 16 subclasses corresponding to 16 translation-symmetry protected topological orders. We introduced four Z2 topological indices ${\ensuremath{\zeta}}_{\mathbf{k}}=0,1$ at k=(0,0), $(0,\ensuremath{\pi})$, $(\ensuremath{\pi},0)$, and $(\ensuremath{\pi},\ensuremath{\pi})$ to characterize those 16 topological orders on square lattice. We calculated the topological degeneracies and crystal momenta for those 16 topological phases on even-by-even, even-by-odd, odd-by-even, and odd-by-odd lattices, which allows us to physically measure such topological orders. We predict the appearance of gapless fermionic excitations at the quantum phase transitions between those symmetry protected topological orders. Our result can be generalized to any dimensions. We find 256 translation-symmetry protected Z2A topological orders for a system on three-dimensional cubic lattice.
Topological phases of matter are purely quantum mechanical and have no classical analogue. Most phases in nature can be classified and studied classically through the concept of symmetry breaking and its theoretical description, Landau-Ginzburg field theory. In contrast to the general wisdom of Landau-Ginzburg field theory, the topological phases share the same symmetry as a trivial insulator and still are different phases. Having gapped spectrum in bulk, they support a metallic edge excition robust against symmetry-respecting perturbation or an emergent fractional excitation in bulk. Following after fractional quantum Hall fluids, many topologically orderd phases, such as spin liquids and topological insulators, have been found and studied. Spin liquids are disordered phases of frustrated antiferromagnets and do not freeze and order even at the lowest temperature. They support an electrically neutral spin-1/2 excitation, which does not exist in a microscopic scale, with emergent dynamical gauge field in bulk and do not have an adiabatic path to a trivial paramagnet phase. The topological insulators are time-reversal symmetric band insulators which cannot evolve smoothly into a trivial insulator with the symmetry, and they have been intensely studied theoretically and experimetally for the last decade. Though the topological insulators are inherently non-interacting systems, they have exotic gapless edge and surface states which demonstrate many interesting quantum phenomena such as fractionalization, axionic electromagnetism, and half quantum Hall effect. In this thesis, we study various quantum phenomena of the topological phases, mainly of the topological insulator and its close relatives in which the physics of spin liquids has been merged into. As they are intrinsically quantum many-body states, the quantum field theory is an invaluable tool to explore the venue of the phases and will be used thorougly in this work. First, we present a topological field theoretic description of the topological insulators and translational symmetric Z2 spin liquid. We demostrate that abelian BF theory is an effective field theory for the two and three dimensional topological insulators. We show that the phenomenologies of BF theory are consistent with those of the topological insulators such as gapless edge and surface excitations and response functions to external gauge field. The same form of the BF theory is also applicable to study the certain classes of Z2 spin liquids with the gapless edge states. We closely examine the possible gapless edge theory of the BF theory and the translational symmetric spin liquids, and we show that the effective BF theories capture the bulk properties as well as the gapless edge spectrum of the spin liquid. Also we discuss the zero-temperature phase diagram of a thin film three dimensional topological insulators with two competing mass terms: time-reversal symmetric exciton condensation and time-reversal symmetry breaking Zeeman effect. There are two phases, quantum spin Hall phase and quantum anomalous Hall phase, and both phases support fractional excitations. We derive an effective topological field theory for the fractional excitations and examine the origin of the fractional excitations. Next we consider the relatives of the topological insulators. First we discuss the proximate symmetry broken phases of topological Mott insulator, a U(1) spin liquid with fermionic spinons in the topological insulator state. The topologically non-trivial band structure of the spinon generates the axion term for the gauge field, and we show that the axion term changes the nature of the confined phase of the spin liquid. Contrast to the conventional confined phase which has only a bond order, the confined phase of the spin liquid is in general a coexisting phase of the two different orders : a current order and a bond order. We then consider another relative of the topological insulator: a bosonic symmetry protected topological phase in two dimensional space, with both PSU(N) and time reversal symmetry. We develop an effective field theory for the phase, which is a SU(N) principal chiral model with a theta-term, and reveal the physics of the topological phase in detail.Finally we consider a topological semimetal, namely a Weyl semimetal. We first demonstrate that the Weyl semimetal can be realized in the magnetically doped topological band insulators. We explicitly derive the low energy theory of Weyl points from the general continuum Hamiltonian and tight-binding model of the topological insulators. Then we study superconducting instabilities of doped Weyl semimetals. We consider a minimal model for a Weyl semimetal and study the superconducting instabilities induced by a short-ranged attractive interaction. With the interaction, we find two competing states: a fully gapped finite-momentum pairing state and a nodal even-parity pairing state. We show that, in a mean field approximateion, the finite-momentum pairing state wins energetically against the usual even-parity paired state. We also show that exotic modes are localized at the full and half quantum vortices of the finite-momentum pairing state.
The ruby lattice has been the subject of much interest recently due its realization in Rydberg atom arrays, where its rich variety of frustrated interactions gives rise to topologically ordered quantum spin liquids. Similarly, numerical studies of ruby-lattice spin models, with both isotropic and anisotropic interactions, have provided evidence of gapped and gapless spin-liquid ground states with different low-energy gauge structures. Motivated by these findings, we perform a projective symmetry group (PSG) classification of U(1) and Z2 fermionic spinon mean-field theories$\unicode{x2014}$respecting space-group and time-reversal symmetries$\unicode{x2014}$for S=1/2 spins. We obtain a total of 50 U(1) and 64 Z2 PSGs, and upon restricting their realization via mean-field Ansa¨tze with up to second-nearest-neighbor singlet amplitudes (relevant to the models studied here), only 8 U(1) and 18 Z2 distinct states are obtained. We present the singlet fields for all Ansa¨tze up to third-nearest-neighboring bonds and discuss their spinon dispersions as well as their dynamical spin structure factors. Building on this information, we also obtain the phase diagram of the Heisenberg model in the presence of first (J1), second (J1′), and third (J2) neighbor antiferromagnetic couplings within a self-consistent mean-field approximation.