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Mean‐field theories

Hidetoshi Nishimori, Gerardo Ortíz

Published Dec 2, 2010• 0 citations
Publisher

Abstract

Abstract The present chapter explains the mean-field approximation, the Landau theory, the infinite-range model, and the Bethe approximation, and shows that all these (mean-field) theories are essentially equivalent to each other. The Landau theory is a phenomenological approach that uses the concept of symmetry and the order parameter, a measure of the breaking of that symmetry, as fundamental collective degrees of freedom. Also described are the Landau theory of tricritical behaviour, correlation functions, the limit of applicability of the mean-field theory, known as the Ginzburg criterion, and dynamic critical phenomena. Mean-field theories yield the exact critical exponents for dimensions larger than the upper critical dimension, and their solutions provide a reasonable starting point for more advanced methods including the renormalization group.

DOI
10.1093/acprof:oso/9780199577224.003.0002

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Abstract The present chapter explains the mean-field approximation, the Landau theory, the infinite-range model, and the Bethe approximation, and shows that all these (mean-field) theories are essentially equivalent to each other. The Landau theory is a phenomenological approach that uses the concept of symmetry and the order parameter, a measure of the breaking of that symmetry, as fundamental collective degrees of freedom. Also described are the Landau theory of tricritical behaviour, correlation functions, the limit of applicability of the mean-field theory, known as the Ginzburg criterion, and dynamic critical phenomena. Mean-field theories yield the exact critical exponents for dimensions larger than the upper critical dimension, and their solutions provide a reasonable starting point for more advanced methods including the renormalization group.
Mean field theory works well when R/a is large or the co-ordination number is large. In both cases, each degree of freedom is coupled to many neighbors. Mean field theory is exact when each spin is coupled to all other spins. In some complex situations, a systematic and relatively easy way to generate mean field theory is by extending the Hamiltonian to be infinite range. Another way of generating mean field theory is to allow the order parameter to have n components and to consider the case n → ∞. The chapter examines the limitations of the phenomenological theory. It provides the analysis which has been for the Landau theory of the Ising universality class. The chapter discusses the Gaussian approximation to the functional integral, and shows how the critical exponents are calculated the lowest order systematic correction to mean field theory.
Abstract Statistical-mechanical systems often involve discrete elementary degrees of freedom such as spins in the Ising model. Field theories, on the other hand, have continuous fields, defined over the whole space-time or part of it, as fundamental degrees of freedom. These two seemingly different descriptions of physical phenomena can be related close to the critical point. The present chapter summarizes how the description by continuous fields emerges from discrete degrees of freedom in a more systematic manner than in previous chapters. The phenomenological Landau-Ginzburg approach, based on the concept of order parameter, is expanded to generate effective field theories. The important roles of symmetry and topology are also elucidated in some detail. Also shown are some of the important consequences of having a broken-symmetry phase, such as long-range order, the emergence of Nambu-Goldstone modes when the symmetry involved is continuous, and topological defects.
To set the stage for our subsequent thorough discussion of dynamic critical phenomena, we first review the theoretical description of second-order equilibrium phase transitions. (Readers already well acquainted with this material may readily move on to Chapter 2.) To this end, we compare the critical exponents following from the van-der-Waals equation of state for weakly interacting gases with the results from the Curie–Weiss mean-field approximation for the ferromagnetic Ising model. We then provide a unifying description in terms of Landau–Ginzburg theory, i.e., a long-wavelength expansion of the effective free energy with respect to the order parameter. The Gaussian model is analyzed, and a quantitative criterion is established that defines the circumstances when non-linear fluctuations need to be taken into account properly. Thereby we identify d c = 4 as the upper critical dimension for generic continuous phase transitions in thermal equilibrium. The most characteristic feature of a critical point turns out to be the divergence of the correlation length that renders microscopic details oblivious. As a consequence, not only the correlation functions, but remarkably the thermodynamics as well of a critical system are governed by an emergent unusual symmetry: scale invariance. A simple scaling ansatz is capable of linking different critical exponents; as an application, we introduce the basic elements of finite-size scaling. Finally, a brief sketch of Wilson's momentum shell renormalization group method is presented, intended as a pedagogical preview of the fundamental RG ideas. Exploiting the scale invariance properties at the critical point, the scaling forms of the free energy and the order parameter correlation function are derived.
Abstract The successful calculation of critical exponents for continuous phase transitions is one of the main achievements of theoretical physics over the last quarter-century. This was achieved through the use of scaling and field-theoretic techniques which have since become standard equipment in many areas of physics, especially quantum field theory. This book provides a thorough introduction to these techniques. Continuous phase transitions are introduced, then the necessary statistical mechanics is summarized, followed by standard models, some exact solutions and techniques for numerical simulations. The real-space renormalization group and mean-field theory are then explained and illustrated. The final chapters cover the Landau-Ginzburg model, from physical motivation, through diagrammatic perturbation theory and renormalization to the renormalization group and the calculation of critical exponents above and below the critical temperature.
In this chapter, the author shows the theory of phase transition using some systems of interacting spins. Note that various systems of different nature can be mapped into spin systems and solved using the spin language. However, the mean-field theory gives some artifacts at low dimensions and cannot determine with precision the critical exponents which characterize the nature of a phase transition. A transition from one phase to another may take place when an external parameter varies. Such a parameter can be the temperature or an external applied magnetic field. Renormalization group analysis shows that the universality class depends only on a few very general parameters such as the space dimension, the symmetry of the order parameter and the nature of the interaction. The Landau–Ginzburg theory is an extension of the mean-field theory which includes a great part of fluctuations so far neglected near the transition.
The sophistication of modern tools used in the study of statistical mechanics and field theory is often an obstacle to the easy understanding of new important current results reported in journals. The main purpose of this book is to introduce the reader to the methods of the fluctuation (field) theory of phase transitions and critical phenomena so as to provide a good source for research. The introductory contents are concerned with ideas of description, thermodynamic stability theory related to phase transitions, major experimental facts, basic models and their relationships. Special attention is paid to the mean field approximation and to the Landau expansion for simple and complex models of critical and multicritical phenomena. An instructive representation of the modern perturbation theory and the method of the renormalization group is developed for field models of phase transitions. The essential influence of the fluctuations on the critical behaviour is established together with the theory of correlation functions, Gaussian approximation, the Ginzburg criterion, [symbol]- and 1/n- expansions as practical realizations of the renormalization group ideas. Applications of the theory to concrete aspects of condensed matter physics are considered: quantum effects, Bose condensation, crystal anisotropy, superconductors and liquid crystals, effects of disorder of type randomly distributed quenched impurities and random fields. This volume can be used as an advanced University course book for students with a basic knowledge of statistical physics and quantum mechanics. It could be considered as a complementary text to a standard University course on statistical physics