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Cambridge University Press eBooks

Exact solution to the s–d problem

Jun Kondo

Published Aug 23, 2012• 0 citations
Publisher

Abstract

Andrei and Wiegmann derived the exact solution to the s-d problem independently. If the s-d interaction is localized, only the radial degree of freedom needs to be considered, and the problem may be reduced to the Schrödinger equation in one-dimensional real space. When the solution is assumed to be in accord with Bethe's ansatz, the problem can be treated in exactly the same manner as in the one-dimensional Hubbard model, and the exact solution method used therein can be adapted as it is to the s–d problem. In this way, each of the various physical quantities can be represented by a single function all the way from high to low temperatures. This is a function of T/TK , and its functional form is found to be consistent with the result of Wilson, insofar as they can be compared. This approach is mathematically powerful, and we may apply it to the case with a magnetic field, the case with S > 1/2, and the Anderson model. However, the focus of our attention in this chapter will be to discuss the initial analysis of Andrei (Andrei, 1980; Andrei and Lowenstein, 1981; Andrei et al. , 1983) and Wiegmann (Weigmann, 1981; Filyov et al. , 1981). A one-dimensional model At first, let us consider the movement of conduction electrons on a onedimensional line. Even in the three-dimensional case, if the interaction is δ function-like, only s -wave scattering arises.

DOI
10.1017/cbo9781139162173.010

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Andrei and Wiegmann derived the exact solution to the s-d problem independently. If the s-d interaction is localized, only the radial degree of freedom needs to be considered, and the problem may be reduced to the Schrödinger equation in one-dimensional real space. When the solution is assumed to be in accord with Bethe's ansatz, the problem can be treated in exactly the same manner as in the one-dimensional Hubbard model, and the exact solution method used therein can be adapted as it is to the s–d problem. In this way, each of the various physical quantities can be represented by a single function all the way from high to low temperatures. This is a function of T/TK , and its functional form is found to be consistent with the result of Wilson, insofar as they can be compared. This approach is mathematically powerful, and we may apply it to the case with a magnetic field, the case with S > 1/2, and the Anderson model. However, the focus of our attention in this chapter will be to discuss the initial analysis of Andrei (Andrei, 1980; Andrei and Lowenstein, 1981; Andrei et al. , 1983) and Wiegmann (Weigmann, 1981; Filyov et al. , 1981). A one-dimensional model At first, let us consider the movement of conduction electrons on a onedimensional line. Even in the three-dimensional case, if the interaction is δ function-like, only s -wave scattering arises.
The bare existence of this book is due to the amazing fact that the solution of the stationary Schrödinger equation for the one-dimensional Hubbard model can be reduced to a set of algebraic equations, which is tractable in the thermodynamic limit. These equations will be derived in this chapter. We will call them the Lieb-Wu equations to honour E. H. Lieb and F. Y. Wu, who first obtained them [298]. The derivation is based on a method, called the nested (coordinate) Bethe ansatz, which goes back to the seminal articles of C. N. Yang [493] and M. Gaudin [154], who generalized earlier work [60, 296] on exactly solvable models to models with internal degrees of freedom. The roots of the Lieb-Wu equations parameterize the eigenvalues and the eigenstates of the Hamiltonian of the one-dimensional Hubbard model. They encode the complete information about the model. These roots are not explicitly known in the general N -particle case. In the thermodynamic limit ( N →∞), however, only the distributions of the roots in the complex plane matter, and many physical quantities can be calculated as solutions of linear or non-linear Fredholm type integral equations. Moreover, it is sometimes possible to use the Lieb-Wu equations in an implicit way even for finite N , e.g., in the proof of the SO(4) highest weight properties of the eigenstates in Sections 3.D and 3.F of the appendix or in the calculation of their norm in Section 3.5.
Introduction to Integrable Many-Body systems III This is the third part of a three-volume introductory course about integrable systems of interacting bodies. The emphasis is put onto the method of Thermodynamic Bethe ansatz. Two kinds of integrable models are studied. Systems of itinerant electrons, forming a part of Condensed Matter Physics, involve the Hubbard lattice model of electrons with short-ranged one-site interactions (Sect. 20) and the s-d exchange Kondo model (Sect. 21), describing the scattering of conduction electrons on a spin-s impurity. Methods and basic concepts used in Quantum Field Theory are explained on the integrable (1 + 1)-dimensional sine-Gordon model. We start with the classical description of the model in Sect. 22, analyze its finite energy field configurations (soliton, anti-soliton and breathers) and show its classical integrability. The model is quantized by using two schemes: the conformal (Sect. 23) and Lagrangian (Sect. 24) quantizations. The scattering matrix of the sine-Gordon theory is derived at the full quantum level in the bootstrap scheme and is compared to its classical limit in Sect. 25. The parameters of the scattering matrix are related to those of the Lagrangian by calculating the ground-state energy in an applied magnetic field in two ways: Conformal perturbation theory and Thermodynamic Bethe ansatz (Sect. 26). The relation of the sine-Gordon theory to the XXZ Heisenberg model, which provides a complete solution of the sine-Gordon model in a finite volume, is pointed out in Sect. 27. The obtained results are applied in Sect. 28. to the derivation of the exact thermodynamics for the (symmetric) two-component Coulomb gas; this is the first classical two-dimensional fluid with exactly solvable thermodynamics.
We propose a novel characterization of the exact solution of the one-dimensional Hubbard model with unparallel boundary magnetic fields. The non-diagonal boundary terms break the U(1) symmetry of the system and the number of electrons with fixed spin is not conserved. Thus it is difficult to study the physical quantities in the thermodynamic limit based on the previously obtained inhomogeneous T−Q relation and Bethe ansatz equations. In order to solve this problem, we propose the t−W scheme. The basic idea is that the eigenvalues of the transfer matrix can be expressed by its zero-roots instead of the usual Bethe roots. This method allows us to study thermodynamic properties of the system such as the ground state, surface energy, charge and spin excitations. The t−W scheme is universal and can be applied to the systems either with or without U(1) symmetry.
Introduction The one-dimensional Bose gas with point-like interaction of the particles (the quantum variant of the nonlinear Schrödinger equation) is one of the main and most important models which can be Solved by means of the Bethe Ansatz. This model has been thoroughly investigated (and. We shall start with the construction of eigenfunctions of the Hamiltonian in a finite volume. Quantities interesting from the physical point of view (in the thermodynamic limit at zero temperature) are considered; the thermodynamics at finite temperatures is investigated in detail as well. A number of essential ideas which will be applied to other models are introduced. The construction of eigenfunctions of the Hamiltonian is explained in section 1. Their explicit form and, in particular, the two-particle reducibility, are common features of the models solvable by means of the Bethe Ansatz method. Periodic boundary conditions are imposed on the wave function in section 2; the Bethe equations for the particle' momenta are introduced and analyzed. Taken in the logarithmic form, these equations realize the extremum condition of a certain functional, the corresponding action being called the Yang-Yang action. The transition to the thermodynamic limit is considered in section 3. In that same section the ground state of the gas is constructed. The density of the particle distribution in momentum space and the energy of the ground state are calculated. The method of the transition to the thermodynamic limit described in this section is rather general and may be applied to any model solvable by means of the Bethe Ansatz. In section 4, excitations above the ground state are constructed and their main characteristics (energy, momentum and scattering matrix) are determined by means of the dressing equations. The ground state of the model is the Dirac sea (also called the Fermi sphere).
An essential role for the description of correlated quantum many-particle systems is played by impurity problems. These consist of a small number of localized orbitals, where the electrons are subject to a Coulomb-interaction, coupled to noninteracting bath degrees of freedom. Impurity models are used for the description of magnetic impurities in metals, of quantum points in nanostructures, and in the context of the dynamical mean field theory (DMFT). For their solution a large number of numerical methods exists. We mention here quantum Monte Carlo methods, the numerical renormalization group, or the exact diagonalization method. In this thesis we introduce a new approach to impurity problems, which is based on the functional renormalization group (fRG). In contrast to the methods mentioned above this approach is approximative, but it can be applied with comparatively lower numerical effort. The aim of this thesis is to examine the advantages and limits of this method. An important role in this connection is played by the single impurity Anderson model (SIAM), which is already understood very well with other methods and is seen as a prototype for models with strong local correlations. The spin fluctuations of this model are governed by the so-called Kondo energy scale and a central question of this thesis is whether this scale can be reproduced with our approach. We begin with a short introduction to the Green's function formalism for correlated quantum many particle systems. Then the fRG flow equations for the one-particle irreducible vertex functions are deduced, and several approximation schemes are discussed. In chapter 4 we introduce the fRG scheme used in this thesis. At first the SIAM is mapped to a semi-infinite chain, in which the interacting orbital is given by the first site of this chain. The system is then subdivided into two parts. The first part, which is called 'core', consists of the interacting orbital and the first L bath sites. The remaining bath sites form the second part. At the beginning both parts are decoupled from each other such that the core can be solved exactly. Starting with this exact solution the coupling between the core and the remaining bath sites is switched on slowly in a renormalization group flow. This way it is possible to calculate the one-particle and two-particle correlation functions on the correlated site. We call this flow scheme 'hybridization flow'. The flow equations are formulated in an effective theory on the first bath site outside the core, which turns out to be advantageous compared to other implementations of the hybridization flow. In chapter 5 this hybridization flow method is applied to the SIAM with semi-elliptic bath density of states. We discuss the differences which arise for different core-sizes (L = 0,1,2,3) and for different truncations of the fRG flow equations. In the cases L=0 and L=2 the local Fermi liquid properties of the SIAM and the associated Kondo scale can not be reproduced in both approximation schemes. For the core sizes L=1 and L=3 the ground state of the core is already a spin singlet state in the beginning of the flow and the Fermi liquid properties are reproduced. The Kondo energy scale, which determines the width of the central quasi-particle peak and the size of the local spin-susceptibility, is however not accurately resolved. This is partly due to the finite temperature used in our implementation such that for larger interaction strength the temperature is above the Kondo energy scale. The application of the hybridization flow method to quantum impurity problems in the context of the DMFT is discussed in chapter 6. In this approach lattice models with a local interaction, like the Hubbard model, are mapped to an effective impurity problem for a single lattice site embedded in a dynamical mean field representing the influence of the other electrons. This scheme is exact in infinitely many dimensions and a nonperturbative approximation method for finite-dimensional systems. In particular the Mott metal-insulator transition in the Hubbard model is successfully described by this method. One class of quantities, which is easily accessible from the hybridization flow scheme, is given by the local two-particle correlation functions. These play an essential role in non-local extensions of the DMFT. Therefore we mainly focus on these quantities. At first we apply our flow scheme to the Hubbard model on the Bethe lattice in infinite dimensions and calculate the local one-particle irreducible vertex functions in the insulating and the metallic phase in good agreement with previous calculations, which use the exact diagonalization method as impurity solver. After this we extend our flow scheme to a cluster DMFT method, which includes short-range antiferromagnetic correlations and calculate again the local and non-local vertex functions for the two-dimensional Hubbard model. We compare these to the results of the single-site DMFT.