THE ESSENTIAL INDEFINITENESS OF QUANTUM MECHANICS; HEISENBERG'S PHILOSOPHY AND BOHR'S DE BROGLIE WAVE THEORY OF THE PASSAGE FROM MICRO- TO MACRO-MECHANICS; THE SPREADING FACTOR; BOHR'S SUMMARY OF THE PRESENT STATE OF THE QUANTUM THEORY
The essential indefiniteness of quantum mechanics {Heisenberg) The origin of quantum mechanics was an attempt to break away from the usual kinematical and mechanical concepts and in their place to substitute relations between concrete numbers given by experiment. The position of an electron The position of an electron relative to a given system of axes must be measurable by experiment if the term is to have a meaning in quantum mechanics. We illuminate the electron and observe it through a microscope; the accuracy with which the position can be observed is given by the wave-length of the light used. If we use a y ray microscope, we should get the most exact result physically possible. But these y rays produce a Compton effect on the electron, so that at the instant when the position is determined the momentum of the electron is suddenly changed. This change of momentum is all the greater the shorter the wave-length of the light used, i.e. the more accurate the determination of position is. Thus at the moment when the position of the electron is known, its momentum can only be known to an order equal to this discontinuous change. Hence the more exactly a coordinate q is determined, the less exactly can its momentum p be found; and conversely.
The essential indefiniteness of quantum mechanics {Heisenberg) The origin of quantum mechanics was an attempt to break away from the usual kinematical and mechanical concepts and in their place to substitute relations between concrete numbers given by experiment. The position of an electron The position of an electron relative to a given system of axes must be measurable by experiment if the term is to have a meaning in quantum mechanics. We illuminate the electron and observe it through a microscope; the accuracy with which the position can be observed is given by the wave-length of the light used. If we use a y ray microscope, we should get the most exact result physically possible. But these y rays produce a Compton effect on the electron, so that at the instant when the position is determined the momentum of the electron is suddenly changed. This change of momentum is all the greater the shorter the wave-length of the light used, i.e. the more accurate the determination of position is. Thus at the moment when the position of the electron is known, its momentum can only be known to an order equal to this discontinuous change. Hence the more exactly a coordinate q is determined, the less exactly can its momentum p be found; and conversely.
This chapter starts with the historical development of quantum mechanics and explanations of key concepts behind fundamental discoveries such as Planck's hypothesis, the photoelectric effect, Bohr's atomic model, Compton scattering, the de Broglie hypothesis, the Pauli exclusion principle, the Schrödinger equation, Heisenberg quantum mechanics and the uncertainty principle, the Born interpretation of wave function, the Davisson and Germer experiment, and Dirac relativistic quantum mechanics, which made important contributions to the foundation of modern quantum mechanics. Concepts like the particle properties of radiation, the wave properties of matter, quantized energy and momentum, and the idea that one can no longer know exactly where a single particle like an electron is at any instant of time are brought out clearly through this chapter. A list of important quantum mechanical parameters along with solved examples and unsolved exercises on the key concepts are included towards the end.
At the beginning of the twentieth century, it became clear that microscopic particles do not obey Newton's laws of classical mechanics. The idea of light quanta was at odds with the established wisdom that light is a wave phenomenon, of course, but no other explanation of the photoelectric effect seemed possible. The next step in the development of quantum mechanics was taken by Niels Bohr, who introduced postulates about the discreteness of the energy of the bound electrons in an atom similar to the discreteness of the energy of light quanta. Modern quantum mechanics was founded by Werner Heisenberg, Max Born, Erwin Schroedinger, Paul Adrian Maurice Dirac, Wolfgang Pauli, Enrico Fermi, and others. In quantum mechanics, it is in general fundamentally impossible to determine the exact outcome of an experiment; one can only determine the probability of any given outcome.
The ideas in Heisenberg's paper on quantum mechanics in 1925 mark the beginning not only of a new phase in modern physics, but also of Heisenberg's own philosophical journey. This thesis examines that journey between 1925 and the late 1950s by situating Heisenberg's philosophy of quantum mechanics in the context of his encounters with his contemporaries as well as the context of various strands of thought in the German-speaking world at the time. Heisenberg's early philosophical critique of the 'classical' viewpoint between 1925 and 1927 bears the decisive influence of Einstein's theory of relativity, more specifically, the positivism he saw as underpinning Einstein's emancipation from Newtonian physics. The positivist influence on Heisenberg's early attitude to quantum mechanics is evident in three ways: (a) his invocation of an observability principle in 1925 to justify the renunciation of the concept of the electron orbit, (b) an instrumentalist conception of understanding, which characterised Heisenberg's response to Schrodinger's demand for classical visualisation in space and time in 1926-7, and (c) the introduction of an operational definition of concepts such as position and velocity in 1927, in an attempt to replace the concepts of classical physics. But after discussions with Bohr and Einstein in 1926-7, Heisenberg soon recognised what we might term his `empiricist' viewpoint was problematic. In 1927 Heisenberg's thought undergoes a shift away from the `empiricist' viewpoint that had underpinned his early philosophy of quantum mechanics. The nature and scope of this transformation, which forms the central theme in this thesis, has, up until now, been poorly understood and often completely neglected. Through his discussions with Bohr, Heisenberg came to the realisation that despite their limitations, classical concepts were conditions for the possibility of the description of all experience. This marked the abandonment of his earlier attempt to replace classical concepts with quantum concepts. The recognition of the primacy of classical language forms the point of departure for much of Heisenberg's later thought, which brought him into contact with the attempts in the German-speaking world in the 1920s to reconstruct Kantian epistemology. By the mid-1930s, Heisenberg advocated a 'pragmatic transformation' of Kantian philosophy, in which classical concepts were held to be a priori in the sense that they remained the conditions for the possibility of experience, but were no longer held to be necessary or universal in a strict Kantian sense. After 1940 Heisenberg saw the paradoxes of quantum mechanics under the aegis of what can be termed a 'transcendental conception of language', according to which language is not a mere tool, but actively shapes, gives form, and objectifies, our 'reality'. The limits of a classical 'description' in quantum mechanics therefore came to signify for Heisenberg, the limits of 'objective reality'. While Bohr exerted perhaps the most important philosophical influence on Heisenberg, their intellectual relationship was characterised by disagreement and misunderstanding. This is most strikingly displayed in their respective views on wave-particle duality and complementarily. While after 1927 Heisenberg accepted Bohr's basic insight that our knowledge of the quantum world is mediated through classical language, he did not share Rohr's interpretation of complementarity. While Heisenberg certainly used terms such as 'complementarity' and wave-particle duality' in his writings, a close reading reveals that these terms had very different meanings for the two physicists. This is particularly evident in the contrast between Heisenberg's notion of wave-particle equivalence and Bohr's idea of complementarity. In bringing to light these divergences between Bohr and Heisenberg, this thesis lends further weight to the view - already advocated by scholars such as John Hendry and Mara Beller - that the so-called Copenhagen interpretation of quantum mechanics should not be thought of as a unified philosophical position, but actually comprises a number of different strands.
We have seen in the previous chapter how useful wave mechanics can be in solving physical problems. But wave mechanics has several limitations. It describes physical states by means of wave functions, which are functions of the positions of the particles of the system, but why should we single out position as the fundamental physical observable? For instance, we might want to describe states in terms of probability amplitudes for particles to have certain values of the momentum or energy rather than the position. A more fundamental limitation: There are attributes of physical systems that cannot be described at all in terms of the positions and momenta of a set of particles. One of these attributes is spin , which will be the subject of Chapter 4. Another is the value of the electric or magnetic field at some point in space, treated in Chapter 11. This chapter will describe the principles of quantum mechanics in a formalism which is essentially the “transformation theory” of Dirac, mentioned briefly in Section 1.4. This formalism generalizes both the wave mechanics of Schrödinger and the matrix mechanics of Heisenberg, and is sufficiently comprehensive to apply to any sort of physical system. States The first postulate of quantum mechanics is that physical states can be represented as vectors in a sort of abstract space known as Hilbert space . Before getting into Hilbert space, I need to say a bit about vectors in general. In kindergarten we learn that vectors are quantities with both magnitude and direction. Later, when we study analytic geometry, we learn instead to describe a vector in d dimensions as a string of d numbers, the components of the vector. This latter approach lends itself well to calculation, but in some respects the kindergarten version is better, because it allows us to describe relations among vectors without specifying a coordinate system. For instance, a statement that one vector is parallel to a second vector, or perpendicular to a third, has nothing to do with how we choose our coordinate system.
We have seen in the previous chapter how useful wave mechanics can be in solving physical problems. But wave mechanics has several limitations. It describes physical states by means of wave functions, which are functions of the positions of the particles of the system, but why should we single out position as the fundamental physical observable? For instance, we might want to describe states in terms of probability amplitudes for particles to have certain values of the momentum or energy rather than the position. A more fundamental limitation is that there are attributes of physical systems that cannot be described at all in terms of the positions and momenta of a set of particles. One of these attributes is spin , which will be a chief subject of Chapter 4. Another is the value of the electric or magnetic field at some point in space, treated in Chapter 11. This chapter will describe the principles of quantum mechanics in a formalism which is essentially the “transformation theory” of Dirac, mentioned briefly in Section 1.4. This formalism generalizes both the wave mechanics of Schrödinger and the matrix mechanics of Heisenberg, and is sufficiently comprehensive to apply to any sort of physical system. States The first postulate of quantum mechanics is that physical states can be represented as vectors in a sort of abstract space known as Hilbert space . Before getting into Hilbert space, I need to say a bit about vectors in general. In kindergarten we learn that vectors are quantities with both magnitude and direction. Later, when we study analytic geometry, we learn instead to describe a vector in d dimensions as a string of d numbers, the components of the vector. The latter approach lends itself well to calculation, but in some respects the kindergarten version is better, because it allows us to describe relations among vectors without specifying a coordinate system. For instance, a statement that one vector is parallel to a second vector, or perpendicular to a third, has nothing to do with how we choose our coordinate system. Here we will formulate what we mean by vector spaces in general, and Hilbert space in particular, in a way that is independent of the coordinates we use to describe directions in these spaces.
Chapter 4 deals with Quantum Mechanical (QM) phenomena. The first section describes the first attempts at quantization of energy, momentum, angular momentum, etc. We start with Plank's solution to the black-body problem, introducing the concept of photons: discrete packets of electromagnetic energy. We show how Plank's description of black-body radiation is perfectly fit by the cosmic microwave radiation, providing the strongest evidence for the Big-Bang at the origin of the Universe. We then describe Bohr's solution to the paradoxical stability of atoms, introducing quantization of angular momentum (or action) and correctly predicting the energy levels of the hydrogen atom. We show how Einstein used Plank's idea to explain the photo-electric effect (an effect exploited in CCD cameras and solar cells) and how he used Bohr's understanding of energy levels in atoms to provide an intuitive explanation of Plank's law. Einstein insight opened the way to the field of spectroscopy and the development of the laser. In the second section, following the lead of Dirac, we show that QM is equivalent to Linear Algebra in the space of complex functions (which describe the state of the system). We show that Schrödinger's equation is a natural consequence of that description, once the relation between energy and frequency established by Plank (for photons) and de Broglie (for particles) is taken into account. In the context of the chiral ammonia molecule we discuss the queerness of QM which describes physical systems as superposition of states (such as left and right chirality state of a molecule, dead and alive cat). We show that this queerness is nonetheless supported by experiments and is behind much of our technology: masers and lasers, atomic clocks, semiconductors (diodes, transistors, etc.). In the following section we introduce the representation of operators in QM (the equivalent of matrices in linear algebra): momentum, position, energy, etc. which correspond to measurements on the system. We show that the non-commutability of some operators (common with matrix operations) leads to Heisenberg uncertainty principle: the position and momentum of a particle cannot be determined with absolute precision. We discuss the solution of Schrödinger's equation for free particles demonstrating their equivalence with EM phenomena: particles undergo refraction and diffraction, exemplifying the particle/wave duality inherent to QM systems. We discuss QM tunneling and its use in the Scanning Tunneling Microscope. In the following section we study Dirac's equation: the successful attempt by Dirac to unify QM with Einstein's relativity, with the resulting prediction of anti-particles and spin. We then solve for the energy levels of electrons in the hydrogen atom (from Schrödinger's equation) and show that the existence of spin profoundly affects the behavior of electrons in an atom: they cannot share the same energy level, a rule known as Pauli's exclusion principle. Pauli's principle is central to the understanding of the chemical properties of atoms and fully explains Mendeleev's periodic table of the elements. In the next section we discuss along with two exactly soluble systems (diatomic rotational and vibrational levels), various approximations used to study systems (e.g. molecules) for which there are no analytical solutions. In particular, we introduce Pauling's variational approach, Hückel molecular orbital theory and time independent perturbation theory. We apply those approaches to determine the energy levels in alkenes, in multi-electron atoms and in systems under constant electric or magnetic field (such as in Magnetic Resonance Imaging). In the last section we discuss time dependent perturbation theory. We use it to establish the rules allowing for transitions between energy levels and revisit Einstein description of absorption/emission phenomena.