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Oxford University Press eBooks

Coherent interaction of light with atoms

J. C. Garrison, R. Y. Chiao

Published Jun 5, 2008• 0 citations
Publisher

Abstract

The perturbation expansion (Chapter 4) fails if the incident field — assumed to be resonant with an atomic transition — has a coherence time that is long compared to the spontaneous emission time. The dominance of resonance effects is used to replace the perturbation expansion by the resonant-wave approximation, which approximately describes the joint evolution of the field-atom system for long times. This approach is employed to describe quantum propagation of spontaneously emitted photons. When combined with the Markov approximation, it yields the Weisskopf-Wigner model for single-photon emission and two-photon cascade emission. The chapter ends with a discussion of the semi-classical limit, Rabi oscillations, the Bloch equation, and adiabatic elimination.

DOI
10.1093/acprof:oso/9780198508861.003.0012

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The perturbation expansion (Chapter 4) fails if the incident field — assumed to be resonant with an atomic transition — has a coherence time that is long compared to the spontaneous emission time. The dominance of resonance effects is used to replace the perturbation expansion by the resonant-wave approximation, which approximately describes the joint evolution of the field-atom system for long times. This approach is employed to describe quantum propagation of spontaneously emitted photons. When combined with the Markov approximation, it yields the Weisskopf-Wigner model for single-photon emission and two-photon cascade emission. The chapter ends with a discussion of the semi-classical limit, Rabi oscillations, the Bloch equation, and adiabatic elimination.
This chapter begins with a review of the semi-classical model of the interaction of charged particles with light, and then proceeds to the full quantum theory by replacing the classical fields with the corresponding field operators. A presentation of the quantum Maxwell equations and their behavior under parity and time reversal transformations is followed by a discussion of stationary density operators. The notion of positive- and negative-frequency parts of field operators is extended to interacting fields and used to define multi-time correlation functions that describe experimental results. The perturbation expansion is formulated by means of the interaction picture and combined with the dipole approximation to calculate the Einstein A- and B-coefficients. The chapter ends with a discussion of spontaneous emission in a cavity and Raman scattering.
Chapter 6 transforms the optical wave into a quantized form. The electric field is pictured as an infinite ladder of discrete states: this structure allows optical interactions to be described photon by photon. The origin of spontaneous emission emerges as a transition process that is stimulated by electric field fluctuations of the vacuum; Weisskopf–Wigner theory explains why it is irreversible. Squeezed states are introduced and qualitatively unique properties are identified. Statistical analysis of light fields serves as a basis for more quantitative comparisons of fields and their noise properties. Methods of calculating the first and second degrees of coherence are presented. The ranges of values corresponding to “classical” versus “quantum” light sources are discussed. The reduced density matrix is developed to justify analysis that focuses on a subset of the components or dynamics of a complex system, ignoring aspects that are not of primary interest. The problem of calculating the fluorescence spectrum of resonantly excited two-level atoms is considered using both a method of moments and dressed atom theory.
Chapter 6 begins by transforming the optical wave itself into a quantized form, and the full implications of the wave‐particle duality of Chapter 2 become clear. The electric field may be pictured as an infinite ladder of discrete states and this structure allows optical interactions to be described photon by photon. The origin of spontaneous emission emerges from this treatment as a transition process that is stimulated by electric field fluctuations of the vacuum, and Weisskopf–Wigner theory explains why it is irreversible. The subject of coherent states is introduced and intriguing possibilities outlined regarding the noise properties of components of these states that form different quadratures in terms of the optical phase. Next, statistical analysis of light fields is considered to serve as a basis for more quantitative comparisons of fields and their noise properties. Methods of calculating the first and second degrees of coherence are presented, and the ranges of values corresponding to “classical” versus “quantum” light sources are discussed. The reduced density matrix is developed to justify analysis that focuses on only certain aspects of optical dynamics while ignoring others, as an important tool for simplifying complex problems. Finally, in view of its historical importance, the problem of calculating the fluorescence spectrum of resonantly excited two‐level atoms is considered using both a method of moments and dressed atom theory.
In the preceding chapters concerning the interaction of a radiation field with matter, we assumed the field to be classical. In many situations this assumption is valid. There are, however, many instances where a classical field fails to explain experimentally observed results and a quantized description of the field is required. This is, for example, true of spontaneous emission in an atomic system which was described phenomenologically in Chapter 5. For a rigorous treatment of the atomic level decay in free space, we need to consider the interaction of the atom with the vacuum modes of the universe. Even in the simplest system involving the interaction of a single-mode radiation field with a single two-level atom, the predictions for the dynamics of the atom are quite different in the semiclassical theory and the fully quantum theory. In the absence of the decay process, the semiclassical theory predicts Rabi oscillations for the atomic inversion whereas the quantum theory predicts certain collapse and revival phenomena due to the quantum aspects of the field. These interesting quantum field theoretical predictions have been experimentally verified. In this chapter we discuss the interaction of the quantized radiation field with the two-level atomic system described by a Hamiltonian in the dipole and the rotating-wave approximations. For a single-mode field it reduces to a particularly simple form. This is a very interesting Hamiltonian in quantum optics for several reasons. First, it can be solved exactly for arbitrary coupling constants and exhibits some true quantum dynamical effects such as collapse followed by periodic revivals of the atomic inversion.
In nanostructures where confinement of a light wave is manifested, the conditions of strong light–matter interaction become feasible. In this case, the approach based on the environment-sensitive probability of quantum transitions is no longer applicable. Instead, joint states of light and matter should be considered and their time evolution explored. The content of the previous Chapters 13 and 14 can then be treated as a perturbative description of light–matter interactions with a limited range of applicability. In this chapter a few representative examples are given where joint light–matter states bring an unprecedented flavor of nanophotonic engineering to frozen excited states for quantum memory devices and single photon sources for quantum computing. Cavity quantum electrodynamics in the strong coupling regime The regime of strong coupling of a quantum system with an electromagnetic field can be performed in a cavity with very high Q-factor, where light can survive for a reasonable time until it either leaves the cavity or dies through being absorbed by cavity imperfections. In a simplified picture, a photon once emitted stays within the cavity so long that it is absorbed again by the emitter (an imaginary two-level system, an atom or a quantum dot). Thus spontaneous emission appears to become reversible. In a more accurate presentation, an “atom+field” state develops which evolves via oscillations between the state | E , 0〉 (“excited atom, depleted cavity”) to the state | G , 1〉 (“de-excited atom, a photon in the cavity”).
This chapter gives an overview of the field as it stands at the time of writing in mid 1995. It shows how the picture radically changes when there is more than one atom in the cavity. The simplest light-atom interaction one can think of is the coupling between a single atom and a single mode of the electromagnetic field. This system provides considerable insight into the fundamental physics of the light-atom coupling but the reader is warned that the more general many mode-many atom interactions are much richer in their dynamics. An atom in free space couples not only to one, but to a continuum of modes. The mathematics of the Weisskopf-Wigner theory of spontaneous emission tends to obscure the relatively simple physics of the emission process. An alternative, shorter way of calculating the single atom spontaneous emission rate is to use Fermi’s Golden rule, which is a prescription for calculating general transition rates to first order in perturbation theory.