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Helvetica Physica Acta (Switzerland)

The unstable system and irreversible motion in quantum theory

Lawrence Paul Horwitz, C. Piron

Published Jan 17, 1994• 17 citations
Publisher

Abstract

It has been shown by Flesia and Piron that the scattering theory of Lax and Phillips, developed primarily for the treatment of hyperbolic systems (e.g., classical scattering of electromagnetic waves on a finite target), can be applied to the quantum theory. In order to construct the correspondence, the continuously infinite family of (isomorphic) Hilbert spaces associated with each value of the time (are taken to be a direct integral representation (with a choice of measure) of a larger Hilbert space which includes the variable t in its measure space. We show that this theory, for which the evolution contracted to the subspace orthogonal to the incoming and outgoing subspaces is a contractive semigroup, provides a natural description of the irreversible motion of an unstable quantum system

DOI
10.5169/seals-116585

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It has been shown by Flesia and Piron that the scattering theory of Lax and Phillips, developed primarily for the treatment of hyperbolic systems (e.g., classical scattering of electromagnetic waves on a finite target), can be applied to the quantum theory. In order to construct the correspondence, the continuously infinite family of (isomorphic) Hilbert spaces associated with each value of the time (are taken to be a direct integral representation (with a choice of measure) of a larger Hilbert space which includes the variable t in its measure space. We show that this theory, for which the evolution contracted to the subspace orthogonal to the incoming and outgoing subspaces is a contractive semigroup, provides a natural description of the irreversible motion of an unstable quantum system
The scattering theory of Lax and Phillips, designed primarily for hyperbolic systems, such as electromagnetic or acoustic waves, is described. This theory provides a realization of the theorem of Foias and Nagy; there is a subspace of the Hilbert space in which the unitary evolution of the system, restricted to this subspace, is realized as a semigroup. The embedding of the quantum theory into this structure, carried out by Flesia and Piron, is reviewed. We show how the density matrix for an effectively pure state can evolve to an effectively mixed state (decoherence) in this framework. Necessary conditions are given for the realization of the relation between the spectrum of the generator of the semigroup and the singularities of the SSS-matrix (in energy representation). It is shown that these conditions may be met in the Liouville space formulation of quantum evolution, and in the Hilbert space of relativistic quantum theory.
Abstract: We discuss some of the experimental motivation for the need for semigroup decay laws, and the quantum Lax-Phillips theory of scattering and unstable systems. In this framework, the decay of an unstable system is described by a semigroup. The spectrum of the generator of the semigroup corresponds to the singularities of the Lax-Phillips S-matrix. In the case of discrete (complex) spectrum of the generator of the semigroup, associated with resonances, the decay law is exactly exponential. The states corresponding to these resonances (eigenfunctions of the generator of the semigroup) lie in the Lax-Phillips Hilbert space, and therefore all physical properties of the resonant states can be computed. We show that the parametrized relativistic quantum theory is a natural setting for the realization of the Lax-Phillips theory. 1.
Basic notions and theWigner–Weisskopf theory Although the notions of bound states, scattering and quantum transitions are well defined in the quantum theory, the description of an unstable system, involved in the process of decay, has remained an outstanding issue for many years. The problem is fundamental, since it concerns the nature of irreversible processes, one of the most important issues in statistical mechanics and the theme that is central to this book. The theory of decay is intimately connected with scattering theory and necessarily contains mathematical ideas and methods. We shall try to explain these points carefully as we get to them. We treat elsewhere in the book the ideas of Boltzmann, Van Hove and Prigogine on irreversible phenomena. The tools that are developed there are basically approximate, although very useful. One can argue that the basic rigorous characteristic of an irreversible process is that, as represented in terms of the evolution of a state in the Hilbert space of the quantum theory, it must be a semigroup. This type of evolution, resulting in an operation Z ( t ) on a state ψ , should satisfy the property Z ( t 2 ) Z ( t 1 ) = Z ( t 1 + t 2 ). (17.1) The argument is as follows. If the system evolves in time t 1 and is stopped, then evolves further at time t 2 , since the process has no memory, the total evolution should be as if the system evolved from the initial state to a state at t 1 + t 2 independently of the fact that it was done in two stages (Piron, 1976). Since the process is irreversible, the operator Z ( t ) may have no inverse. Such an evolution is called a semigroup . As we shall see, it is not possible to obtain such an evolution law in the framework of the standard quantum theory (Horwitz et al. , 1971), but recently much work has been done, and methods have been developed, based on ideas of Sz.-Nagy and Foias (1976), such as the theory of Lax and Phillips (1967) and its extension to the quantum theory (Strauss et al. , 2000) in which semigroup evolution can be achieved.
We discuss the quantum Lax–Phillips theory of scattering and unstable systems. In this framework, the decay of an unstable system is described by a semigroup. The spectrum of the generator of the semigroup corresponds to the singularities of the Lax–Phillips S-matrix. In the case of discrete (complex) spectrum of the generator of the semigroup associated with resonances, the decay law is exactly exponential. We explain how this profound difference between the quantum Lax–Phillips theory and the description of unstable systems in the framework of the standard quantum theory emerges. The states corresponding to these resonances (eigenfunctions of the generator of the semigroup) lie in the Lax–Phillips Hilbert space, and therefore all physical properties of the resonant states can be computed. In the special case of a time-independent potential problem lifted trivially to the quantum Lax–Phillips theory, we show that the Lax–Phillips S-matrix is unitarily related to the S-matrix of standard scattering theory by a unitary transformation parametrized by the spectral variable σ of the Lax–Phillips theory. Analytic continuation in σ has some of the properties of a method developed some time ago for application to dilation analytic potentials. We work out an illustrative example of the theory using a Lee–Friedrichs model, which is generalized to a rank one potential in the Lax–Phillips Hilbert space.
Traditional Quantum Scattering theory is built upon a Hilbert space formalism. The nature of the Hilbert space has led to a number of ideas about the nature of scattering systems, chief among them being the understanding that the decay of unstable quan- tum systems cannot be purely exponential and that there can only be an approximate relationship between the width Γ of a scattering resonance and the lifetime τ of the resonant state whose formation gives rise to it. That such physical conclusions are de- rived from purely mathematical properties of the underlying topological vector space inform the notion that, in choosing a particular space, one is choosing the mathemat- ical representation of the physical universe for the system. With this notion in mind, purely physical characteristics of quantum systems are used to answer the question: “What is the proper mathematical space for quantum mechanical calculations?” In the particular case of quantum scattering, it is shown that this approach casts the choice of the Hilbert space into doubt and motivates instead the use of rigged Hilbert spaces employing Hardy spaces; in these Hardy rigged Hilbert spaces, exponential decay is permissible and the time evolution of decaying states is governed by semigroups. The original theories concerning deviation from exponential decay in the Hilbert space are revisited to reveal how their conclusions flow from a mathematical property whose physical interpretation is problematic. Finally, an application of a Hardy rigged Hilbert space formalism is presented: Time Asymmetric Quantum Mechanics, as developed by A. Bohm, M. Gadella, and S. Wickramasekara.