We observed the interference of coherently excited biexcitons in a CuCl crystal by double pulse four-wave mixing. Interference is observed even when the two excitation pulses are orthogonally polarized clearly demonstrating the scalar-wave nature of biexcitons.
We propose an experimental scheme to evaluate the intrinsic anharmonicity of the biexciton ensemble by extending the conventional four-wave mixing technique to coherent biexciton waves, which can be prepared by two-photon absorption of ultrashort optical pulses. The anharmonicity originates from the two-body interaction of the bosonic quasi-particles at low densities and leads to Kerr-type nonlinearity for the coherent biexcitonic waves generated in the crystal. We discuss the feasibility of determining the two-body biexciton interaction energy in CuCl by measuring the anharmonicity of the biexcitonic ensemble.
Biexcitonic polarization excited in a ZnSe quantum well is coherently controlled with a pair of phase-locked laser pulses. The coherent control of this four-particle correlation is directly verified by observing a spectrally resolved four-wave-mixing signal in direction of the first order of diffraction of the pulse pair. By using polarization selection rules for the generation of biexcitons and changing the interpulse delay of the pulse pair the oscillations of the four-wave-mixing signal are studied at the energetic position of the excitonic as well as the biexcitonic resonance. The excitonic and biexcitonic signals exhibit a phase shift in dependence on the interpulse delay which clearly indicates the separate coherent control of the excitonic and biexcitonic polarization.