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Institute of Physics eBooks

Probability operator and statistical averages

Phil Attard

Published Oct 1, 2015• 0 citations
Publisher

Abstract

Entanglement with the reservoir causes the wave function of an open quantum system to collapse into a mixture of entropy states. This gives the von Neumann trace form for the statistical average. The mechanism is related to environmental selection. The wave space of a closed quantum system has uniform weight, which means that microstates have equal weight. The Maxwell–Boltzmann form for the equilibrium probability operator arises from the weight of reservoir microstates. The collapse of an open quantum system gives rise to the classical universe and Hamilton’s equations of motion from the underlying Schrödinger equation.

DOI
10.1088/978-0-7503-1188-5ch1

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Entanglement with the reservoir causes the wave function of an open quantum system to collapse into a mixture of entropy states. This gives the von Neumann trace form for the statistical average. The mechanism is related to environmental selection. The wave space of a closed quantum system has uniform weight, which means that microstates have equal weight. The Maxwell–Boltzmann form for the equilibrium probability operator arises from the weight of reservoir microstates. The collapse of an open quantum system gives rise to the classical universe and Hamilton’s equations of motion from the underlying Schrödinger equation.
The probability operator is derived from first principles for an equilibrium quantum system. It is also shown that the superposition states collapse into a mixture of states giving the conventional von Neumann trace form for the quantum average. The mechanism for the collapse is found to be quite general: it results from the conservation law for a conserved, exchangeable variable (such as energy) and the entanglement of the total system wave function that necessarily follows. The relevance of the present results to the einselection mechanism for decoherence, to the quantum measurement problem, and to the classical nature of the macroscopic world are discussed.
The exchange of conserved variables between a subsystem and a reservoir or environment entangles their wave functions. Their subsequent collapse, together with the uniform weight of wave space, gives rise to quantum statistical mechanics formulated as the trace of the probability and observable operators. A dual representation in position and momentum space allows a permutation loop expansion for particle symmetrization, and a second expansion accounting for the non-commutativity of the position and momentum operators. The leading term gives classical statistical mechanics, and higher-order terms give successive quantum corrections that become increasingly important for low temperatures, high densities and small masses. The probability density in phase space is stable under the stochastic dissipative equations of motion. Trapped Bose-Einstein condensates may be modeled as a system of non-interacting harmonic oscillators. Most bosons in the condensate are in the ground state, in contrast to the -transition in 4He where the fraction in the ground state is negligible.
The seventh chapter is concerned with the formulation of quantum statistical mechanics from first principles. It is shown that interactions with the reservoir or environment cause the subsystem wave function to collapse into a mixture of pure entropy states, which obey the axioms of classical probability theory. A dual representation in position and momentum states allows a permutation loop expansion for particle symmetrisation, and a second expansion accounting for the non-commutativity of the position and momentum operators. The leading term gives classical statistical mechanics, and higher order terms gives successive quantum corrections that become increasingly important for low temperatures, high densities, and small masses. From the permutation loop expansion, explicit results for the quantum ideal gas and the quantum harmonic oscillator are derived. The role of entropy in the classical manifestation of the universe given the underlying quantum mechanical wave equation is discussed.
Bose-Einstein condensation at low temperatures is driven by occupation entropy, since configurations of labeled particles with multiply-occupied states have more weight. An open quantum system collapses into decoherent states weighted by the reservoir entropy. Thus arises quantum statistical mechanics in classical phase space. The symmetrization function generalizes quantum state occupancy to the momentum continuum. Hamilton's classical equations of motion hold only for an open quantum system with negligible condensation. In the condensed regime the molecular equations of motion preserve the entropy, consistent with fountain pressure measurements of superfluid flow. Condensed bosons in the same momentum state experience non-local forces and move as a rigid body that does not dissipate momentum in classical collisions. High-temperature superconductivity is statistical mechanical in nature, requires bound fermion pairs of neighboring electrons, and is driven by the monotonic-oscillatory transition at high charge coupling.
The Schrödinger equation describes a quantum system that does not interact with anything outside itself. The participation measure evolves unitarily; the norm is preserved; coherent superpositions are maintained indefinitely. This is a useful idealization but it is not what real quantum systems do. Every real quantum system is in contact with its environment — thermal photons, lattice vibrations, stray fields, gas‑phase collisions, observation by experimenters. Coherent superpositions decay; populations relax toward thermal equilibrium; entanglement with the environment proliferates. The closed‑system Schrödinger equation cannot describe these phenomena because, by construction, it has no environment. In 1976, Lindblad — and independently Gorini, Kossakowski, and Sudarshan — proved that the most general Markovian dynamics for a quantum density operator that preserves Hermiticity, trace, and complete positivity has a specific functional form: ∂ₜ ρ̂ = −(i/ℏ)[Ĥ, ρ̂] + ∑_α ( L̂_α ρ̂ L̂_α† − ½{ L̂_α† L̂_α , ρ̂ } ) The first term is the von Neumann equation. The sum is the “dissipator” — jump operators L̂_α mediating environmental coupling. This is the master equation of decoherence theory: qubits coupled to reservoirs, atoms in optical cavities, mesoscopic conductors with electron‑phonon coupling, open‑system everything. The standard derivation traces out the environment and applies the Born–Markov approximation. It works empirically but leaves open: why is Markov valid? Why is Born valid? What is the substrate‑level meaning of the jump operators? This walkthrough shows how the Event Density framework forces the Lindblad form at substrate level rather than deriving it from approximations. The density‑operator description is forced by environmental phase‑independence, derived from substrate primitives, rather than postulated as the natural object after partial‑tracing. Between commitment events, the density operator evolves unitarily — U3 in density‑operator form. The jump operators are the substrate‑level representation of Primitive 11 commitment events: discrete, channel‑selective updates triggered when environmental coupling drives the chain’s individuation. The Markov property is forced by P11’s locality (commitment events do not carry long‑range memory). The anti‑commutator normalization is forced by P04 (bandwidth conservation) plus trace preservation. Complete positivity is automatic from the projector structure of commitment events. The structural payoff: decoherence is not approximate physics derived from a Born–Markov simplification of a more fundamental closed‑system theory. It is what U3 plus substrate primitives produces directly when the chain is non‑isolated. The Lindblad form is forced rather than approximate. Complete positivity, trace preservation, and the Markovian property — usually justified by appeals to physical reasonableness — are forced consequences of bandwidth conservation, environmental phase‑independence, and commitment‑event locality respectively.