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Journal of Physical Chemistry & Biophysics

Revival of the phase-amplitude description of a quantum-mechanical wave functon

George H. Rawitscher

Published Jan 1, 2016• 0 citations
Publisher
DOI
10.4172/2161-0398.c1.016

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Partial revivals of wave packets are investigated by means of the action-angle Wigner function, which is formulated in terms of action quantum numbers and angle variables. In the eigenbasis of the Hamiltonian, the phase shifts of the expansion coefficients of the wave packet are approximated by a quadratic function of action quantum numbers. Under this approximation, the evolution of the action-angle Wigner function of the wave packet, similarly to the classical Liouville density, can be viewed as a result of each phase-space point moving along a classical orbit. The partial and full revivals of wave packets are direct consequences of two facts: (i) The action-angle Wigner function is distributed only on discrete tori of the phase space and (ii) phase-space points of nearby tori move against each other with a constant speed.

Physical Review A•May 1, 1998•13 citations
We study the effect of noise on the axial mode of an electron in a Penning trap under parametric-resonance conditions. Our approach, based on the application of averaging techniques to the description of the dynamics, provides an understanding of the random phase flips detected in recent experiments. The observed correlation between the phase jumps and the amplitude collapses is explained. Moreover, we discuss the actual relevance of noise color to the identified phase-switching mechanism. Our approach is then generalized to analyze the persistence of the stochastic phase flips in the dynamics of a cloud of NNN electrons. In particular, we characterize the detected scaling of the phase-jump rate with the number of electrons.
We investigate the quantum-phase dynamics of a dissipative molecular system interacting with a single-mode amplitude-squeezed field (with a sub-Poissonian photon-number distribution) using the Monte Carlo wave-function method. As quantum dissipation, we consider molecular coherent (phase) and population relaxations, which are caused by nuclear vibration, and cavity relaxation (the dissipation of an internal single mode to outer mode). In this study, we elucidate the effects of these dissipations on the unique quantum dynamical behaviors of this coupled system, e.g., collapse-revival behavior of Rabi oscillations, using the quasiprobability (Q function) distribution of a single-mode field and the off-diagonal molecular density matrix. It is found that although the amplitude-squeezed field exhibits a distinct revival with larger amplitudes of molecular population in the presence of the molecular phase and population relaxations as compared to the coherent field, a very slight cavity relaxation suppresses the revival of molecular population and the increase in the magnitude of off-diagonal molecular density matrices during the quiescent region in the amplitude-squeezed field case more significantly than in the coherent field case. These features are shown to be closely related to the difference in the dynamics of Q function distributions between amplitude-squeezed and coherent fields.
Partial revivals of wave packets are investigated by means of the action-angle Wigner function, which is formulated in terms of action quantum numbers and angle variables. In the eigenbasis of the Hamiltonian, the phase shifts of the expansion coefficients of the wave packet are approximated by a quadratic function of action quantum numbers. Under this approximation, the evolution of the action-angle Wigner function of the wave packet, similarly to the classical Liouville density, can be viewed as a result of each phase-space point moving along a classical orbit. The partial and full revivals of wave packets are direct consequences of two facts: (i) The action-angle Wigner function is distributed only on discrete tori of the phase space and (ii) phase-space points of nearby tori move against each other with a constant speed.