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Quantum Electronics and Laser Science Conference

Order and chaos in laser cooled trapped ions

Ralph G. DeVoe, John A. Hoffnagle, Luis G. Reyna, Richard G. Brewer

Published Apr 24, 1989• 0 citations
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Abstract

Several groups have recently used laser cooling to produce ordered arrays of ions (ion crystals) in rf quadrupole traps. We discuss two physical mechanisms which underlie and explain the behavior of ion crystals. First, we show that deterministic chaos can be responsible for phase transitions between the ordered (crystal) state and the disordered (cloud) state.1 The crystal—cloud transition is explained as an order—chaos transition. Chaos arises from the nonlinear interaction of Coulomb repulsion with the oscillating trap potential.

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Several groups have recently used laser cooling to produce ordered arrays of ions, ion crystals, in rf quadrupole ion traps (Paul traps). Laser cooling has been understood using previous theories which ignore ion micromotion and replace the oscillating rf trap potential with a static pseudopotential. We show that in recent experiments, ion micromotion can exceed one wavelength of the cooling radiation and that the resulting Doppler shifts can transform laser cooling into laser heating. Changes in trap voltage, ion position, and laser intensity can all reverse the sign of laser cooling. This, together with ideas of deterministic chaos, can lead to a reinterpretation of experiments on ion crystals. The recognition that effects previously attributed to an experimental artifact, rf heating, may actually be due to a failure of laser cooling opens the door, on the one hand, to precise theories of phase transitions and, on the other, to improved cooling techniques that can permit the creation of larger ion crystals.

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arXiv:1303.6389•AIP conference proceedings•Jan 1, 2013•6 citations
Several groups have recently used laser cooling to produce ordered arrays of ions (ion crystals) in rf quadrupole traps. We discuss two physical mechanisms which underlie and explain the behavior of ion crystals. First, we show that deterministic chaos can be responsible for phase transitions between the ordered (crystal) state and the disordered (cloud) state.1 The crystal—cloud transition is explained as an order—chaos transition. Chaos arises from the nonlinear interaction of Coulomb repulsion with the oscillating trap potential.
Several groups have recently used laser cooling to produce ordered arrays of ions, ion crystals, in rf quadrupole ion traps (Paul traps). Laser cooling has been understood using previous theories which ignore ion micromotion and replace the oscillating rf trap potential with a static pseudopotential. We show that in recent experiments, ion micromotion can exceed one wavelength of the cooling radiation and that the resulting Doppler shifts can transform laser cooling into laser heating. Changes in trap voltage, ion position, and laser intensity can all reverse the sign of laser cooling. This, together with ideas of deterministic chaos, can lead to a reinterpretation of experiments on ion crystals. The recognition that effects previously attributed to an experimental artifact, rf heating, may actually be due to a failure of laser cooling opens the door, on the one hand, to precise theories of phase transitions and, on the other, to improved cooling techniques that can permit the creation of larger ion crystals.
It is currently thought that the laser cooling of an ordered ion array, an ion crystal, is qualitatively the same as that of a single ion. We show that this assumption is strongly violated in recent experiments in Paul traps, due to ion micromotion. Our analysis demonstrates an unexpected laser damping instability that induces an ion-crystal order-chaos transition and also explains why ion crystals in Paul traps have been limited to less than 100 ions. We directly observe the effects of ion micromotion on the laser cooling of a single trapped Ba+{\mathrm{Ba}}^{+}Ba+ ion by a new technique.
We present recent experimental and theoretical results on the behavior of two-, three-, and four-ion crystals close to the Mathieu instability. In particular, we show that the crystals are stable until the Mathieu instability is reached, i.e., for the parameter space investigated, there is no ``melting'' of the crystals. Laser and rf heating are studied in detail. A simple model of chaotic rf heating as well as a classification of the ion dynamics into four characteristic regimes are presented.
A laser-cooling experiment with Ca+{\mathrm{Ca}}^{+}Ca+ ions trapped in a linear rf octupole ion trap is presented. The phase transition of the laser-cooled Ca+{\mathrm{Ca}}^{+}Ca+ ions from the cloud to the crystal state is observed by an abrupt dip of the laser-induced fluorescence spectrum and indicates that mK temperatures are obtained. We have also performed molecular dynamics simulations under various conditions to confirm this property by deducing axially symmetric structures of Coulomb crystals and by evaluating the translational temperatures of the laser-cooled ions. The simulation results show that for small numbers of ions novel ring-shaped crystals are produced. As the number of ions is increased, cylindrical layers in the ring crystal are sequentially formed. For more than 100 ions, also hexagonal and spiral structures emerge in parts of the large-size ion crystal, which has a length on the order of millimeters for the present geometrical arrangement and voltages. An advantage of the linear rf octupole trap is its large almost-field-free region in the middle of the trap, where the micromotion amplitude is small for trapped ions. These results demonstrate that such a multipole trap has attractive features for quantum computing and ultracold ion-atom collision studies.
While the linear radiofrequency trap finds various applications in high-precision spectroscopy and quantum information, its higher-order cousin, the linear multipole trap, is almost exclusively employed in physical chemistry. Recently, first experiments have shown interesting features by laser-cooling multipole-trapped ion clouds. Multipole traps show a flatter potential in their centre and therefore a modified density distribution compared to quadrupole traps. Micromotion is an important issue and will certainly influence the dynamics of crystallized ion structures. Our experiment tends to investigate possible crystallization processes in the multipole. In a more general way, we are interested in the study of the dynamics and thermodynamics of large ion clouds in traps of different geometry.