We examine the revival structure of Rydberg wave packets. These wave packets exhibit initial classical periodic motion followed by a sequence of collapse, fractional/full revivals, and fractional/full superrevivals. The effects of quantum defects on wave packets in alkali-metal atoms and a squeezed-state description of the initial wave packets are also described. We then examine the revival structure of Rydberg wave packets in the presence of an external electric field, i.e., the revival structure of Stark wave packets. These wave packets have energies that depend on two quantum numbers and exhibit new types of interference behavior.
Quantum mechanical wave packet states can approach the classical ideal of a spatially localized particle traveling along a well-defined trajectory. These states offer a system in which the classical limit of quantum atomic theory can be studied. In this work, a wave packet that is radially localized and whose radial motion occurs at the classical orbital period is studied. Despite these strong classical features, the long-term evolution displays the quantum nature of the state. As the wave packet evolves, it becomes dispersed, and the radial motion becomes irregular. However, the wave packet does not remain dispersed, and classical motion returns with the return of the spatial localization. Both the collapse and revival of the wave packet occur because of the quantized nature of the atom. In this experiment, the wave packet was excited to the Rydberg slates by a short, ultraviolet pulse from the ground state of potassium. The probe pulse delay was scanned, and the resulting photo-ionization signal displayed the evolution of the wave packet. The collapse and revival of the radial wave packet were observed.1
The article discusses the properties of time evolution of wave packets in a few systems. Dynamics of wave packet motion for Rydberg atoms with the hierarchy of collapses and revivals is briefly reviewed. The main part of the paper focuses on the new mechanism of quantum reccurrences in wave packet dynamics. This mechanism can occur (in principle) in any physical system with strong enough spin-orbit interaction. We discuss here the SPIN_ORBIT PENDULUM effect that consists in different motions of subpackets possessing different spin fields and results in oscillations of a fraction of average angular momentum between spin and ordinary subspaces. The evolution of localized wave packet into toroidal objects and backwards (for other class of initial conditions) is also subject to discussion.
After a Rydberg wave packet forms, it is known to undergo a series of collapses and revivals within a time period called the revival time
trev, at the end of which it resembles its original shape. We study the behavior of Rydberg wave packets on time scales much greater than
trev. We find that after a few revival cycles the wave packet ceases to reform at multiples of the revival time. Instead, a new series of collapses and revivals commences, culminating after a time period
tsr≫trev with the formation of a wave packet that more closely resembles the initial packet than does the full revival at time
trev. Furthermore, at times that are rational fractions of
tsr, we show that the motion of the wave packet is periodic with periodicities that can be expressed as fractions of the revival time
trev. These periodicities indicate a new type of fractional revival, occurring for times much greater than
trev. We also examine the effects of quantum defects and laser detunings on the revival structure of Rydberg wave packets for alkali-metal atoms.
The behavior of Hydrogen Rydberg wave packets on time scales much greater than trev was studied.After a few revival cycles the wave packet ceases to reform at multiples of the revival time.Instead,a new series of collapses and revivals commences.Its periodicity is tsr(tsrtrev).The wave packet that forms at time tsr more closely resembles the initial packet than does the full revival packet at time trev.An explanation of these effects is given by constructing autocorrelation function and using the relationship between the wave function and those subsidiary wave functions.
In this paper, a coherent superposition of angular-momentum states created by absorption of polarized light by molecules is analyzed. Attention is paid to the time evolution of wave packets representing the spatial orientation of the internuclear axis of a diatomic molecule. Two examples are considered in detail. Molecules absorbing light in a permanent magnetic field experiencing the Zeeman effect and molecules absorbing light in a permanent electric field experiencing the quadratic Stark effect. In a magnetic field, we have a wave packet that evolves in time exactly as a classical dipole oscillator in a permanent magnetic field (classical-physics picture of the Zeeman effect). In the second case, we have a wave packet that goes through periodical changes of shape of the packet with revivals of the initial shape. This is pure quantum behavior. The classical motion of angular momentum in an electric field in the case of a quadratic Stark effect is known to be a periodic. Solutions obtained for wave packet evolution are briefly compared with Rydberg-state coherent wave packets and harmonic-oscillator wave packets. Zeeman and Stark effects in small molecules continuously attract the attention of researchers, theoreticians, as well as experimentalists. These investigations allow us to obtain a deeper understanding of the interaction of molecules with stationary external fields and also can be used as a practical tool to measure different molecular characteristics, such as permanent electric or magnetic dipole moments, intramolecular perturbations, etc. It is worthwhile analyzing these effects as an evolution of wave packets. All this motivates a comparison of the quantum and classical picture of Zeeman and Stark effects in molecules.PACS No.: 33.55.Be