The collisional interaction between Ba and Yb is not pure dipole-dipole. The maximum of transfer cross section appears at the induced laser wavelength, which corresponds to the interatomic transition. The effect of spin interaction is observed.
Observations are made of dipole-quadrupole laser-induced inelastic collisions occurring during the collision of two Ba atoms. Results for both stimulated-absorption and spontaneous-emission experiments using the same collisional configuration are reported for the first time. In both experiments the interaction maximizes at the $R=\ensuremath{\infty}$ wavelength and has a full-width-at-half-maximum linewidth of \ensuremath{\sim}8 ${\mathrm{cm}}^{\ensuremath{-}1}$. These results bear on the study of the interatomic potentials for colliding atoms and permit the collisional energy transfer to states hitherto inaccessible to dipole-dipole collisions.
Based on the existing four-level model of laser-induced collisional energy transfer, the collision process in Ba-Sr system in both weak and strong fields is calculated by immediate integration of the equation of motion, and profiles of laser-induced transition probability and collision cross section under both conditions are obtained. Numerical results for the weak field are in fair to good agreement with former analytical results, while the ones for the strong field show that the effect of laser-induced collision is enhanced when the transfer laser intensity increases. Moreover, the peak of the laser-induced collisional energy transfer spectrum shows an evident shift from resonant frequency to the violet side in strong field, and full width at half maximum (i.e. tuning range) of the spectrum becomes obviously narrower compared with that in weak field.
We describe two new experiments which demonstrate laser-induced inelastic collisions. Energy was stored in the Sr 5p1Po state and selectively transferred both to the Ca $4{p}^{2}^{1}S$ and 5d1D states. The collision cross sections maximized at the interatomic wavelengths of 4977 and 4711 \AA{}, respectively, and had a half-power width of about 14 ${\mathrm{cm}}^{\ensuremath{-}1}$.