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Journal of Shandong University of Technology

The error analysis on solving Schrodinger equation of harmonic oscillator with symposium

Jianguo Wang

Published Jan 1, 2004• 0 citations
OpenAlex

Abstract

The varying regularity of relative errors of wave function is uncover ed while the Schrodinger equation of harmonic oscillator is solved with symposiu m. It has been found through calculation that relative errors of wave function i n different X points are all the same a t the same time. The relative errors of real number part and imaginary number pa rt of wave function change periodically between positive and negative numbers wi th the passage of time. The period is 628 steps or π seconds. The relation betw een the relative error of real number part and the one of imaginary number part of wave function is similar to the characteristic of Uncertainty Principle. Whe n one relative error approaches infinitely small, the another one approaches inf initely great. The product of the two relative errors is a fixed small number. T he absolute value of the small number increases with the passage of time slowly.

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The varying regularity of relative errors of wave function is uncover ed while the Schrodinger equation of harmonic oscillator is solved with symposiu m. It has been found through calculation that relative errors of wave function i n different X points are all the same a t the same time. The relative errors of real number part and imaginary number pa rt of wave function change periodically between positive and negative numbers wi th the passage of time. The period is 628 steps or π seconds. The relation betw een the relative error of real number part and the one of imaginary number part of wave function is similar to the characteristic of Uncertainty Principle. Whe n one relative error approaches infinitely small, the another one approaches inf initely great. The product of the two relative errors is a fixed small number. T he absolute value of the small number increases with the passage of time slowly.
A method has been introduced to derive the solution of the time-independent Schrodinger equation for the simple harmonic oscillator. A trial solution has been chosen as the product of the divergent part of the approximate asymptotic solution of the Schrodinger equation and an unknown function. Choosing the divergent exponential factor has an advantage. Because if the equation has to have a meaningful bound state solution, the other part of the product is compelled to converge faster than the diverging exponential, so that their product, which is the bound state solution, must converge at large distances. This requirement makes the other part an oscillatory function with (n+1) extrema when it has n nodes. Since its derivative vanishes at each of these extrema, its derivative necessarily possesses at least (n+1) nodes. Such a nodal structure is characteristic of the next higher bound state, motivating an investigation into whether the derivative of the remaining part is directly related to the wave function of the next higher energy eigen state. This investigation demonstrates that the wave functions of the harmonic oscillator can be generated by successively reconstructing the equations of the higher eigen states through repeated differentiation.
The Schrödinger equation is a significant achievement on the development of quantum mechanics. By solving the Schrödinger equation, the fundamental behaviors and properties of a microscopic particle can be found in one- to three-dimensions. The article focuses on the derivations of quantum harmonic oscillators in one dimension by solving second order-differential equation. The wave functions, probability densities under different energy levels are presented. The results can be used to estimate different forms of continuous potential experienced by an oscillator. By calculating the uncertainty relation of the oscillator under one specific excited state, the general relation can be confirmed. Based on the output, by splitting the variables, the two-dimensional harmonic oscillator can also be derived. The degenerate energy levels are presented as . Numerical simulations are made to visualize those results and suggests the relation of energy levels and number of maxima of the probability densities.
A method has been introduced to derive the solution of the time-independent Schrodinger equation for the simple harmonic oscillator. A trial solution has been chosen as the product of the divergent part of the approximate asymptomatic solution of the Schrodinger equation and an unknown function. By inserting this trial solution into the same equation, an equation of that unknown function is obtained. This equation has a recursive property which has been exploited to obtain the solutions of the equation. It is all about reconstruction of the equation with different solutions of that unknown function by repetitive differentiation and that ultimately leads to the wave functions of the Schrodinger equation for harmonic oscillator.
The time dependent harmonic oscillator is solved explicitly for quantum mechanics by the operator method with an auxiliary condition as the classical solution. Two classical invariant quantities which determine whether or not the system is bound are derived by the classical equation of motion. We obtain the invariant operator from one classical invariant quantity. Its eigenfunction is related to the solution of Schrodinger equation of the system and its eigenvalue is related to another classical quantity. The wave function is evaluated exactly by the eigenfunction of the invariant operator but it is not the eigenfunction of the Hamiltonian of the system. The uncertainty which calculates with the wave function is not a minimum one. We will confirm that the function which holds minimum uncertainty is a eigenfunction of the Hamiltonian.
This article establishes the proof of the Schrödinger equation for numerous quantum systems, utilizing Heisenberg's uncertainty principle. The Fourier transform connects functions in the time and frequency domains, resulting in the mathematical inequality that is the foundation of the uncertainty principle. In the part of Methods and Theory, the article derives the uncertainty principle through Fourier transforms by defining the mean and variance of angular frequency and time, and subsequently expanding the integral. This establishes the fundamental connection between time and frequency domains, illustrating the constraints imposed by quantum mechanics. In the part of Results and Application, the article applies the uncertainty principle to derive the Schrödinger equation under different conditions: free particle, particle in a box, harmonic oscillator, and hydrogen atom. For each case, the article assumes wave function solutions, uses the uncertainty in position and momentum to estimate kinetic and potential energies, and shows that the total energy matches the ground state energy derived from the Schrödinger equation. The results highlight the critical role of Heisenberg's uncertainty principle in understanding key aspects of quantum mechanics, providing a unified framework for these diverse systems.
The starting point in a quantum mechanical problem is the construction of a Schrödinger equation. We try to solve it exactly to obtain wave function. A Schrödinger equation is exactly solvable only for a certain number of simple potentials. In most of the cases the Schrödinger equation cannot be solved exactly. The solution of the Schrödinger equation for the real systems is usually complicated and often exact solutions are very difficult to find or solutions not exist. Examples include as anharmonic oscillator, hydrogen atom in an electric field, a plane rotator in the presence of an applied electric field and so on. Therefore, we need to rely on approximation methods. The simple and most interesting and powerful approximate method is the perturbation theory developed by Schrödinger in 1926 [1]. Earlier Lord Rayleigh [2] analysed harmonic vibrations of a string perturbed by small inhomogeneities. The work of Rayleigh was pointed out by Schrödinger. Consequently, the method is also called Rayleigh-Schrödinger perturbation theory. This method is powerful for determining the changes in the discrete energy values and the associated eigenfunctions of a system due to a weak perturbation, provided the eigenpairs of the undisturbed system are available. The approximations obtained from the perturbation theory are used to calculate energy level diagrams and to understand the splitting and assignments of atomic and molecular spectra [35]. The perturbation theory has been proven to be useful in several fields of theoretical physics and also in chemistry. It provides considerable insight into various phenomena. The main disadvantage of this method is that in certain problems the perturbation series converges slowly or diverges.