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Accurate Mean-Field Approximation of Ferromagnet Transition

Fu Cheng Yu

Published Jan 1, 2000• 0 citations
OpenAlex

Abstract

By using the fractal series (the exponents are equal to arbitrary real number) and taking term M 2+0.75 instead of M 2 in the Landau ′s free energy formula, the improved mean field approximation of continuous phase transition beneath critical point was presented. The derived critical exponents can satisfy the two scaling equations and the accurate critical exponents were given as follows: α =0.13, β =0.34, γ =1.19, δ =4.5.

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A new method is proposed to study critical phenomena, which is a unification of Weiss' mean-field theory and Fisher's finite-size scaling theory. A systematic series of clusters is considered and generalized mean-fields are applied to the boundary spins of such clusters. From the size-dependence of the coefficients of mean-field singularities systematically obtained, the static critical exponents α, β and γ, and critical slowing down exponent Δ can be estimated. The critical point T C can be also evaluated from the size-dependence of mean-field critical points obtained in a systematic series of clusters. Some applications to the two- and three-dimensional Ising models are given explicitly to obtain T C =(2.24(0.036)) J / k B and γ=1.7(0.05) in the two-dimensional square lattice in our preliminary calculations.

Journal of the Physical Society of Japan•Jan 15, 1986•45 citations
By using the fractal series (the exponents are equal to arbitrary real number) and taking term M 2+0.75 instead of M 2 in the Landau ′s free energy formula, the improved mean field approximation of continuous phase transition beneath critical point was presented. The derived critical exponents can satisfy the two scaling equations and the accurate critical exponents were given as follows: α =0.13, β =0.34, γ =1.19, δ =4.5.
A series of spin-cluster approximation which is a mean field type approximation is derived systematically on the basis of a spin-cluster expansion formula of the free energy. Mean field critical temperature and mean field critical coefficients are calculated by the spin-cluster approximation for the two-, three- and more than four-dimensional ferromagnetic Ising systems. Analyzing them by the coherent anomaly method, the critical temperature and the critical exponents α, β, γ and δ are estimated. Accuracy of estimated values in this method are comparable to those given by other methods such as the high temperature series analysis. The present theory provides a new and useful tool to study the critical phenomena, especially of three-dimensional systems.
A careful Monte Carlo investigation of the phase transition very close to the critical point (T -> Tc, H -> 0) in relatively large d = 3, s = 1/2 Ising lattices did produce critical exponents beta = 0.3126(4) =~ 5/16, delta^{-1} = 0.1997(4) =~ 1/5 and gamma_{3D} = 1.253(4) =~ 5/4. Our results indicate that, within experimental error, they are given by simple fractions corresponding to the linear interpolations between the respective two-dimensional (Onsager) and four-dimensional (mean field) critical exponents. An analysis of our inverse susceptibility data chi^{-1}(T) vs. /T - Tc/ shows that these data lead to a value of gamma_{3D} compatible with gamma' = gamma and Tc = 4.51152(12), while gamma values obtained recently by high and low temperature series expansions and renormalization group methods are not.
The intrinsic linear and nonlinear magnetic susceptibilities, χ n , for a ferromagnet of arbitrary spin, calculated using the mean-field approximation, are shown to diverge in the asymptotic critical region (ACR) with the exponent γ n = n γ+( n − 1)β and n =1, 2, ... . This behaviour of χ n in the ACR is consistent with the scaling equation of state. With increasing spin, the divergence in χ n ( T ), as the ferromagnetic-paramagnetic phase transition temperature, T C , is approached from below or above, progressively slows down with the result that the width of the ACR increases. For a given spin, the higher the order of nonlinear susceptibility, the narrower the ACR. These results are in qualitative agreement with the critical behaviour of χ n ( T ) observed in an archetypal ferromagnet.
Simple but rigorous derivations are presented for the inequalities2−η≤dγ′/(2β+γ′)≤dγ′/(2−α′),2−η≤d(δ−1)/(δ+1),γ≤(2−η)ν.(Proofs of the first two inequalities have been given by Buckingham and Gunton.1) Here d is the dimensionality and α′, β, γ, γ′ and δ are the exponents characterizing a ferromagnet near its critical point,2 while η and ν describe the decay of the corresponding spin-spin correlation functions2 Γ2(r)=〈S0zSrz〉, according to ∑ |r|<RΓ2(r)∼R2−η(T=Tc,H=0,R→∞),κ1∼(T−Tc)ν,(T→Tc,H=0),where the inverse range of correlation κ1 may be defined by κ1−2=[Σrr2Γ2(r)]/[ΣrΓ2(r)]. The corresponding exponent ηE for the energy-energy correlation function (essentially Γ4(r, a)−[Γ(a)]2, where Γ4(r, a)=〈S0zSazSrzSr+az〉) is proved to satisfy 2−ηE≤dα′,2−ηE≤dαc/(1+ζ+αc),where the specific heat CM at T=Tc diverges with the magnetization as M−αc while the energy derivative | ∂U/∂M |Tc varies as Mζ. (Mean Field or classical values are αc=0, ζ=1.) The proofs are based on the ``intuitively obvious'' properties: (a) positivity, namely, Γ1=〈S0z〉≥0,Γ(r)−Γ12≥0,Γ4(r, a)−[Γ2(a)]2≥0, and (b) monotonic increase of Γ1, Γ2 and Γ4 under increase of magnetic field and decrease of temperature. These properties are known3 to be rigorously valid for Ising models of arbitrary spin, lattice structure and ferromagnetic coupling (Jij≥0). Their validity for real magnets together with the experimental observation δ≤4.7 leads to the significant conclusion η≥0.05.
The critical behavior of the Ising model on a fractal lattice, which has the Hausdorff dimension log_{4}12≈1.792, is investigated using a modified higher-order tensor renormalization group algorithm supplemented with automatic differentiation to compute relevant derivatives efficiently and accurately. The complete set of critical exponents characteristic of a second-order phase transition was obtained. Correlations near the critical temperature were analyzed through two impurity tensors inserted into the system, which allowed us to obtain the correlation lengths and calculate the critical exponent ν. The critical exponent α was found to be negative, consistent with the observation that the specific heat does not diverge at the critical temperature. The extracted exponents satisfy the known relations given by various scaling assumptions within reasonable accuracy. Perhaps most interestingly, the hyperscaling relation, which contains the spatial dimension, is satisfied very well, assuming the Hausdorff dimension takes the place of the spatial dimension. Moreover, using automatic differentiation, we have extracted four critical exponents (α, β, γ, and δ) globally by differentiating the free energy. Surprisingly, the global exponents differ from those obtained locally by the technique of the impurity tensors; however, the scaling relations remain satisfied even in the case of the global exponents.
A new method is proposed to study critical phenomena, which is a unification of Weiss' mean-field theory and Fisher's finite-size scaling theory. A systematic series of clusters is considered and generalized mean-fields are applied to the boundary spins of such clusters. From the size-dependence of the coefficients of mean-field singularities systematically obtained, the static critical exponents α, β and γ, and critical slowing down exponent Δ can be estimated. The critical point T C can be also evaluated from the size-dependence of mean-field critical points obtained in a systematic series of clusters. Some applications to the two- and three-dimensional Ising models are given explicitly to obtain T C =(2.24(0.036)) J / k B and γ=1.7(0.05) in the two-dimensional square lattice in our preliminary calculations.