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Practical Quantum Mechanics: Modern Tools and Applications

Efstratios Manousakis

Published Jan 12, 2016• 1 citation
Publisher

Abstract

Quantum mechanics forms the foundation of all modern physics, including atomic, nuclear, and molecular physics, the physics of the elementary particles, condensed matter physics. Modern astrophysics also relies heavily on quantum mechanics. Quantum theory is needed to understand the basis for new materials, new devices, the nature of light coming from stars, the laws which govern the atomic nucleus, and the physics of biological systems. As a result the subject of this book is a required course for most physics graduate students. While there are many books on the subject, this book targets specifically graduate students and it is written with modern advances in various fields in mind. Many examples treated in the various chapters as well as the emphasis of the presentation in the book are designed from the perspective of such problems. For example, the book begins by putting the Schrodinger equation on a spatial discrete lattice and the continuum limit is also discussed, inspired by Hamiltonian lattice gauge theories. The latter and advances in quantum simulations motivated the inclusion of the path integral formulation. This formulation is applied to the imaginary-time evolution operator to project the exact ground state of the harmonic oscillator as is done in quantum simulations. As an example of how to take advantage of symmetry in quantum mechanics, one-dimensional periodic potentials are discussed, inspired by condensed matter physics. Atoms and molecules are discussed within mean-field like treatment (Hartree-Fock) and how to go beyond it. Motivated by the recent intense activity in condensed matter and atomic physics to study the Hubbard model, the electron correlations in the hydrogen molecule are taken into account by solving the two-site Hubbard model analytically. Using the canonical Hamiltonian quantization of quantum electrodynamics, the photons emerge as the quanta of the normal modes, in the same way as the phonons emerge in the treatment of the normal modes of the coupled array of atoms. This is used later to treat the interaction of radiation with atomic matter.

DOI
10.1093/acprof:oso/9780198749349.001.0001

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Abstract The book contains lectures notes for a graduate two-semester course in quantum mechanics. It differs from other quantum mechanics textbooks as various parts of the book are inspired by rather recent advances in various areas of physics. For example, the book begins by putting the Schrödinger equation on a spatial discrete lattice, inspired by Hamiltonian lattice gauge theories (HLGT). The book also discusses the path integral formulation of quantum mechanics and emphasize the adiabatic time evolution in the case of a time-dependent Hamiltonian. As an example of how to use symmetry in quantum mechanics, the book treats one-dimensional periodic potentials. The book also discusses atoms and molecules using mean-field-like treatment, such as the Hartree–Fock approximation, including a discussion on how to go beyond it. Electron–electron correlations in the hydrogen molecule are taken into account with a first quantized formulation of the two-site Hubbard model, which is solved analytically. The book also uses the canonical Hamiltonian quantization of quantum electrodynamics after finding the normal modes, in an analogy with the treatment of the normal modes of an array of atoms, the photons emerge as the quanta of such normal modes, in the same way as the phonons emerge in the treatment of the normal modes of the coupled array of atoms. This Hamiltonian quantization of the electromagnetic field is used later to treat its interaction with atomic matter, without having to follow the usual semiclassical treatment.
Over the course of the past two to three decades, new tools of presentation and mathematical treatment have emerged and the subject matter of quantum mechanics has gone through significant changes. A Textbook on Modern Quantum Mechanics presents the selected elementary, intermediate, and advance topics with rejuvenated approach to the subject matter. Newly merged topics from contemporary physics and chemistry are included in the text as well as solved examples. The book covers: (i) fundamental discoveries that are the foundation of modern quantum mechanics; (ii) solution of Schrödinger’s wave equation for 1D problems and their importance; (iii) matrix and vector formulation of quantum mechanics; (iv) transformations, symmetries, and conservation laws; (v) angular and spin momenta; (vi) solution of Schrödinger equation for central potentials; (vii) time-independent perturbation theory, variational method and WKB approximation; (viii) quantum theory of scattering; (xi) many-particle systems and their quantum mechanical treatments; (x) time-dependent perturbations and the interaction of fields with matter; (xi) relativistic quantum mechanics; and (xii) quantization of fields and the second quantization. Key Features: It provides everything a student needs to know for succeeding at all levels of the undergraduate and graduate studies. It covers most of the topics that are taught under (a) elementary, (b) intermediate, and (c) advance courses of quantum mechanics at universities and colleges. It has detailed and elegant mathematical treatment with contemporary style of interpretation and presentation in simple English. Solved examples and unsolved exercises that are part of each chapter to consolidate the readers' understanding of fundamental concepts. The subject matter of the book is well tested on the students taught by the author over a period of 30 years. This is a valuable textbook for students pursuing Bachelor of Science, Master of Science, and Doctor of Philosophy (PhD) degrees in the subjects of Physics, Chemistry, and materials science in India, South Asian countries, the United States, and Europe.
Written for a two-semester graduate course in Quantum Mechanics, this comprehensive text helps develop the tools and formalism of Quantum Mechanics and its applications to physical systems. It suits students who have taken some introductory Quantum Mechanics and Modern Physics courses at undergraduate level, but it is self-contained and does not assume any specific background knowledge beyond appropriate fluency in mathematics. The text takes a modern logical approach rather than a historical one and it covers standard material, such as the hydrogen atom and the harmonic oscillator, the WKB approximations and Bohr-Sommerfeld quantization. Important modern topics and examples are also described, including Berry phase, quantum information, complexity and chaos, decoherence and thermalization, nonstandard statistics, as well as more advanced material such as path integrals, scattering theory, multiparticles and Fock space. Readers will gain a broad overview of Quantum Mechanics, as solid preparation for further study or research.
Written for a two-semester graduate course in Quantum Mechanics, this comprehensive text helps develop the tools and formalism of Quantum Mechanics and its applications to physical systems. It suits students who have taken some introductory Quantum Mechanics and Modern Physics courses at undergraduate level, but it is self-contained and does not assume any specific background knowledge beyond appropriate fluency in mathematics. The text takes a modern logical approach rather than a historical one and it covers standard material, such as the hydrogen atom and the harmonic oscillator, the WKB approximations and Bohr-Sommerfeld quantization. Important modern topics and examples are also described, including Berry phase, quantum information, complexity and chaos, decoherence and thermalization, nonstandard statistics, as well as more advanced material such as path integrals, scattering theory, multiparticles and Fock space. Readers will gain a broad overview of Quantum Mechanics, as solid preparation for further study or research.
Written for a two-semester graduate course in Quantum Mechanics, this comprehensive text helps develop the tools and formalism of Quantum Mechanics and its applications to physical systems. It suits students who have taken some introductory Quantum Mechanics and Modern Physics courses at undergraduate level, but it is self-contained and does not assume any specific background knowledge beyond appropriate fluency in mathematics. The text takes a modern logical approach rather than a historical one and it covers standard material, such as the hydrogen atom and the harmonic oscillator, the WKB approximations and Bohr-Sommerfeld quantization. Important modern topics and examples are also described, including Berry phase, quantum information, complexity and chaos, decoherence and thermalization, nonstandard statistics, as well as more advanced material such as path integrals, scattering theory, multiparticles and Fock space. Readers will gain a broad overview of Quantum Mechanics, as solid preparation for further study or research.
Written for a two-semester graduate course in Quantum Mechanics, this comprehensive text helps develop the tools and formalism of Quantum Mechanics and its applications to physical systems. It suits students who have taken some introductory Quantum Mechanics and Modern Physics courses at undergraduate level, but it is self-contained and does not assume any specific background knowledge beyond appropriate fluency in mathematics. The text takes a modern logical approach rather than a historical one and it covers standard material, such as the hydrogen atom and the harmonic oscillator, the WKB approximations and Bohr-Sommerfeld quantization. Important modern topics and examples are also described, including Berry phase, quantum information, complexity and chaos, decoherence and thermalization, nonstandard statistics, as well as more advanced material such as path integrals, scattering theory, multiparticles and Fock space. Readers will gain a broad overview of Quantum Mechanics, as solid preparation for further study or research.