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Study of ionization processes of highly excited Rydberg atoms by collision with molecules

真司 植松

Published Jan 1, 1984• 0 citations
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In collisions with NH3{\mathrm{H}}_{3}H3​ molecules it is observed that Xe(nf)\mathrm{Xe}(\mathrm{nf})Xe(nf) Rydberg atoms are selectively excited to discrete, more highly excited states. These states are identified by the technique of field ionization and are found to be displaced in energy from the initial Rydberg states by amounts equal to the rotational spacings of the NH3{\mathrm{H}}_{3}H3​ molecule. These measurements demonstrate, for the first time, the conversion of rotational energy to electronic energy in collisions.