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Physical Review E

Canonical formulation of quantum dissipation and noise in a generalized spin bath

Arnab Ghosh, Sudarson Sekhar Sinha, Deb Shankar Ray

Published Jul 19, 2012• 11 citations
Publisher

Abstract

The quantum dynamics of a particle coupled to the dissipative degrees of freedom of a generalized spin bath in the presence of an external force field is presented. Based on Holstein-Primakoff transformation, which sets up a mapping between boson and spin operators, we show that the spin-1/2 bath and the harmonic bath can be realized as two special limits of the generalized bath. In the large spin limit, the Hamiltonian reduces to well-known Zwanzig Hamiltonian. Making use of spin coherent states and canonical thermal distributions of the associated c numbers, we derive and explore the quantum Langevin equation and the properties of the spin and harmonic baths in the context of quantum dissipation of the system.

DOI
10.1103/physreve.86.011122

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The quantum dynamics of a particle coupled to the dissipative degrees of freedom of a generalized spin bath in the presence of an external force field is presented. Based on Holstein-Primakoff transformation, which sets up a mapping between boson and spin operators, we show that the spin-1/2 bath and the harmonic bath can be realized as two special limits of the generalized bath. In the large spin limit, the Hamiltonian reduces to well-known Zwanzig Hamiltonian. Making use of spin coherent states and canonical thermal distributions of the associated c numbers, we derive and explore the quantum Langevin equation and the properties of the spin and harmonic baths in the context of quantum dissipation of the system.
We propose a scheme for quantum brownian motion of a particle in a fermionic bath. Based on the spin coherent-state representation of the noise operators and a canonical thermal distribution of the associated c numbers, we derive a quantum analog of generalized Langevin equation for quantum-mechanical mean position of the particle subjected to an external force field. The approach allows us to map the quantum problem on a classical setting. The quantum dispersion around the mean can be estimated order by order by a set of quantum correction equations up to a desired degree of accuracy for a given nonlinear potential. We derive a quantum diffusion equation for free particle and show that quantization, in general, enhances the mean-square displacement. Increase in temperature leads to suppression of mean-square displacement. The method is based on canonical quantization procedure and may be used for understanding diffusive transport and thermally activated processes in a fermionic bath.
We investigate the effect of dissipation in a Bose Josephson junction (BJJ) coupled to bath of bosons at two sites as an application of the generalized spin-boson model. Apart from the dynamical transition due to repulsive interactions, the BJJ undergoes a quantum phase transition by increasing the coupling strength with the bath modes. We analyze this system by mapping to an equivalent spin model coupled to the bosonic modes. The excitation energies and fluctuation of number imbalance are obtained within Holstein-Primakoff approximation, which exhibits vanishing of energy gap and enhanced quantum fluctuations at the critical coupling. We study the dynamics of BJJ using time-dependent variational method and analyze stability of different types of steady states. As a special case, we study in details the phase space dynamics of BJJ coupled to a single-mode, which reveals diffusive and incoherent behaviour with increasing coupling to the bath mode. The dynamical steady states corresponding to the Pi-oscillation and self-trapped state become unstable in the region where their oscillation frequencies are in resonance with the bath modes. We investigate the time evolution of number imbalance and relative phase in presence of Ohmic bath with Gaussian noise to incorporate thermal fluctuations. Apart from the damping of Josephson oscillations and transition to symmetry broken state for strong coupling, we observe the decay of Pi-oscillation and self-trapped state to the ground state as a result of dissipation. Variation of phase fluctuation with temperature of the bath shows similar behaviour as observed in the experiments.
The classical work by Zwanzig [J. Stat. Phys. 9 (1973) 215-220] derived Langevin dynamics from a Hamiltonian system of a heavy particle coupled to a heat bath. This work extends Zwanzig's model to a quantum system and formulates a more general coupling between a particle system and a heat bath. The main result proves, for a particular heat bath model, that ab initio Langevin molecular dynamics, with a certain rank one friction matrix determined by the coupling, approximates for any temperature canonical quantum observables, based on the system coordinates, more accurately than any Hamiltonian system in these coordinates, for large mass ratio between the system and the heat bath nuclei.
We present a general and practical theoretical framework to investigate how energy is dissipated in open quantum system dynamics. This is performed by quantifying the contributions of individual bath components to the overall dissipation of the system. The framework is based on the Nakajima-Zwanzig projection operator technique, which allows us to express the rate of energy dissipation into a specific bath degree of freedom by using traces of operator products. The approach captures system-bath interactions to all orders, but is based on second-order perturbation theory on the off-diagonal subsystem's couplings and a Markovian description of the bath. The usefulness of our theory is demonstrated by applying it to various models of open quantum systems involving harmonic oscillators or spin baths and connecting the outcomes to existing results such as our previously reported formula derived for locally coupled harmonic baths [Kim and Franco, J. Chem. Phys. 154, 084109 (2021)]. We also prove that the dissipation calculated by our theory rigorously satisfies thermodynamic principles such as energy conservation and detailed balance. Overall, the strategy can be used to develop the theory and simulation of dissipation pathways to interpret and engineer the dynamics of open quantum systems.
One longstanding difficult problem in quantum dissipative dynamics is to solve the spin-boson model in a non-Markovian regime where a tractable systematic master equation does not exist. The spin-boson model is particularly important due to its crucial applications in quantum noise control and manipulation as well as its central role in developing quantum theories of open systems. Here we solve this important model by developing a non-Markovian quantum Langevin approach. By projecting the quantum Langevin equation onto the coherent states of the bath, we can derive a set of non-Markovian quantum Bloch equations containing no explicit noise variables. This special feature offers a tremendous advantage over the existing stochastic Schr\"odinger equations in numerical simulations. The physical significance and generality of our approach are briefly discussed.
Quantum Brownian motion is a frontier area of research in quantum optics (Louisell 1973; Sargent, Scully, and Lamb 1974; Meystre and Sargent 1991), condensed matter (Grabert, Schramm, and Ingold 1988; Weiss 1999), and chemical physics (Hänggi, Talkner, and Borkovec 1990; Zwanzig 1973) over the last several decades. The fundamental paradigm is the irregular movement of a particle in a thermal bath kept at finite temperature. The bath constitutes many, in principle, infinite degrees of freedom interacting with the particle. In general, the bath is considered to be a set of harmonic oscillators of varied frequency ranges and is therefore bosonic in character. The particle follows the reduced stochastic dynamics obtained after appropriate elimination of these reservoir degrees of freedom under suitable approximation schemes. The dynamical evolution is characterized by quantum dissipation and bosonic noise related to each other by fluctuation-dissipation (FD) relation, ensuring a detailed balance in the system. This chapter concerns a system-reservoir model where the reservoir is constituted by a set of two-level atoms or spin-1/2 systems.