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Physics Essays

Quantum mechanics of a hydrogen atom: A new look at problems and a new approach to their explanation

V. K. Gudym, E. V. Andreeva

Published Jun 1, 2013• 1 citation
Publisher
DOI
10.4006/0836-1398-26.2.263

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Quantum Mechanics of the Hydrogen Atom

Hermann Haken, Hans Christoph Wolf

Springer eBooks•Jan 1, 1994•1 citation

Two puzzling problems in explanation of the linear Stark effect of hydrogen atom and space quantization of the dipole moment

Pei-Lin You, Xiang-You Huang

The linear Stark effect for the first excited state of the hydrogen atom shows that, in the unperturbed states, the atom has a permanent electric dipole moment (EDM) of magnitude 3eao (ao is Bohr radius). The EDM is not induce by the external field but is inherent behavior of the atom. But the calculation of quantum mechanics tells us that unperturbed states of hydrogen atom have no EDM! In the effect, two of four states have no energy shift. What are the EDM of the hydrogen atoms in the two states? Quantum mechanics can not answer the problem. The statement that the EDM of the two states is perpendicular to the field only comes from guesses in quantum mechanics. The two problems had puzzled physicists for more than 80 years. By introducing a new parameter this article gives a satisfactory explanation for the effect. Our calculation discovered that, in the unperturbed states, the atoms not only have EDM with 3eao but also can have only three directions of quantization! It is an entirely unexpected discovery. This research is a vital clue that not all is well with quantum mechanics. We prophesy that hydrogen-like atoms, such as K, Rb and Cs atom etc, may have large EDM of the order of magnitude eao in their ground state (see arXiv:0809.4767, arXiv:0810.0770 and arXiv:0810.2026).

arXiv:0810.3316•Oct 18, 2008•0 citations

The Solvable and the Symmetric: A Narrative Review of Exactly Solvable Quantum Systems, from the Oscillator to Supersymmetric Factorization

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The exactly solvable systems---the harmonic oscillator, the hydrogen atom, and the angular momentum algebra---are quantum mechanics' solved ground: the spectra computed in closed form that calibrated the theory, taught its methods, and revealed the symmetries that make solvability itself a theorem. This article presents a narrative review of the primary literature of that ground, from de Broglie's 1924 thesis---the wave hypothesis the solvable problems confirmed---through Heisenberg's 1925 umdeutung, Schrödinger's 1926 eigenvalue problem, whose oscillator and rotator opened the solvable list, Dirac's 1926 theory of quantum mechanics and Pauli's 1926 hydrogen solution by the new algebra, Darwin's 1927 vector waves, Dirac's 1928 electron---the relativistic hydrogen's fine structure---Wigner's 1931 group theory and its application to the atomic spectra, Condon and Shortley's 1935 atomic spectra canon, Fock's 1935 hydrogen symmetry---the O(4) hidden behind the spectrum---to the factorization method's systematization in Infeld and Hull's 1951 review and its supersymmetric completion in Cooper, Khare, and Sukhatme's 1995 physics reports. The synthesis is organized around three themes: the solved spectra, in which the oscillator's and hydrogen's levels fixed the new mechanics' validity; the hidden symmetries, in which Runge-Lenz and spherical symmetry explained the solvabilities; and the factorization program, in which the ladder operators' algebra became a method---the exactly solvable potentials classified. It is concluded that the solvable systems are quantum mechanics' load-bearing examples---and that their symmetries remain the theory's deepest explanation of why some problems close.

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New concept of quantum and its classical physics explanation

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In this paper, the problems existing in the concepts of Planck's energy element and Einstein's light quantum are analyzed, and new concepts of quantum and electronic transition power are proposed. The new concept of quantum eliminates the inherent contradiction of the old quantum concept, and can explain the structure and spectral phenomena of hydrogen atom and photoelectric effect completely on the basis of classical physics without Bohr's "quantization hypothesis". The new concept of quantum breaks the gap between macro and micro, eliminates the contradiction between "classical physics" and "quantum mechanics", and lays an important foundation for the reconstruction of unified macro and micro physics.

•Nov 24, 2020•0 citations
The linear Stark effect for the first excited state of the hydrogen atom shows that, in the unperturbed states, the atom has a permanent electric dipole moment (EDM) of magnitude 3eao (ao is Bohr radius). The EDM is not induce by the external field but is inherent behavior of the atom. But the calculation of quantum mechanics tells us that unperturbed states of hydrogen atom have no EDM! In the effect, two of four states have no energy shift. What are the EDM of the hydrogen atoms in the two states? Quantum mechanics can not answer the problem. The statement that the EDM of the two states is perpendicular to the field only comes from guesses in quantum mechanics. The two problems had puzzled physicists for more than 80 years. By introducing a new parameter this article gives a satisfactory explanation for the effect. Our calculation discovered that, in the unperturbed states, the atoms not only have EDM with 3eao but also can have only three directions of quantization! It is an entirely unexpected discovery. This research is a vital clue that not all is well with quantum mechanics. We prophesy that hydrogen-like atoms, such as K, Rb and Cs atom etc, may have large EDM of the order of magnitude eao in their ground state (see arXiv:0809.4767, arXiv:0810.0770 and arXiv:0810.2026).
The exactly solvable systems---the harmonic oscillator, the hydrogen atom, and the angular momentum algebra---are quantum mechanics' solved ground: the spectra computed in closed form that calibrated the theory, taught its methods, and revealed the symmetries that make solvability itself a theorem. This article presents a narrative review of the primary literature of that ground, from de Broglie's 1924 thesis---the wave hypothesis the solvable problems confirmed---through Heisenberg's 1925 umdeutung, Schrödinger's 1926 eigenvalue problem, whose oscillator and rotator opened the solvable list, Dirac's 1926 theory of quantum mechanics and Pauli's 1926 hydrogen solution by the new algebra, Darwin's 1927 vector waves, Dirac's 1928 electron---the relativistic hydrogen's fine structure---Wigner's 1931 group theory and its application to the atomic spectra, Condon and Shortley's 1935 atomic spectra canon, Fock's 1935 hydrogen symmetry---the O(4) hidden behind the spectrum---to the factorization method's systematization in Infeld and Hull's 1951 review and its supersymmetric completion in Cooper, Khare, and Sukhatme's 1995 physics reports. The synthesis is organized around three themes: the solved spectra, in which the oscillator's and hydrogen's levels fixed the new mechanics' validity; the hidden symmetries, in which Runge-Lenz and spherical symmetry explained the solvabilities; and the factorization program, in which the ladder operators' algebra became a method---the exactly solvable potentials classified. It is concluded that the solvable systems are quantum mechanics' load-bearing examples---and that their symmetries remain the theory's deepest explanation of why some problems close.
In this paper, the problems existing in the concepts of Planck's energy element and Einstein's light quantum are analyzed, and new concepts of quantum and electronic transition power are proposed. The new concept of quantum eliminates the inherent contradiction of the old quantum concept, and can explain the structure and spectral phenomena of hydrogen atom and photoelectric effect completely on the basis of classical physics without Bohr's "quantization hypothesis". The new concept of quantum breaks the gap between macro and micro, eliminates the contradiction between "classical physics" and "quantum mechanics", and lays an important foundation for the reconstruction of unified macro and micro physics.