Evidence for Bose-Einstein condensation of a gas of spin-polarized 7Li atoms is reported. Atoms confined to a permanent-magnet trap are laser cooled to 200 \ensuremath{\mu}K and are then evaporatively cooled to lower temperatures. Phase-space densities consistent with quantum degeneracy are measured for temperatures in the range of 100 to 400 nK. At these high phase-space densities, diffraction of a probe laser beam is observed. Modeling shows that this diffraction is a sensitive indicator of the presence of a spatially localized condensate. Although measurements of the number of condensate atoms have not been performed, the measured phase-space densities are consistent with a majority of the atoms being in the condensate, for total trap numbers as high as $2\ifmmode\times\else\texttimes\fi{}{10}^{5}$ atoms. For 7Li, the spin-triplet s-wave scattering length is known to be negative, corresponding to an attractive interatomic interaction. Previously, Bose-Einstein condensation was predicted not to occur in such a system.
abstract: While the use of super-cooled gasses as a tool for the study of macroscopic quantum effects has only become experimentally viable in recent years, theories involing such gasses have existed almost as long as quantum theory itself. Albert Einstein first proposed the concept of what is known today as a Bose-Einstein condensate; the driving principle behind his theory was a deliberate exploitation of the symmetric property of multiparticle bosonic wavefunctions. Specifically, since the Bose-Einstein statistics of bosons dic- tate that any arbitrary number of particles can occupy the same state, it is possible in an extremely low energy environment for particles on the order of Avagadro's number to all condense into the ground state. This state of matter is now called a Bose-Einstein condensate (hereafter referred to as a BEC). This state of matter is interesting because having such a large number of particles in the same state allows for the observation of macroscopic quantum effects.
This chapter presents an overview of the specific experimental tools developed in the field of ultra-cold gases to achieve and probe superfluidity in vapours of bosonic atoms. First, it describes the main cooling techniques: the magneto-optical trap, which brings an atomic vapour from room temperature down to the sub-mK range, and the evaporative cooling scheme, which bridges the gap to the superfluid regime. It then proceeds to the study of interaction effects. It shows that these play a central role in the understanding of both static and dynamic properties of trapped Bose–Einstein condensates (BECs), despite the dilute character of these gases. As a consequence, gaseous BECs and superfluid helium obey the same laws of hydrodynamics and exhibit similar dynamical properties, although their densities differ by several orders of magnitude. The third section is devoted to the coherence properties of gaseous BECs. It shows that, by contrast with liquid helium, specific features of ultra-cold gases make them suitable for a direct probing of the quantum coherence associated with Bose–Einstein condensation. Finally, the possibility of tailoring trapping potentials and realizing low-dimensional systems is discussed, where one or two directions of motion are frozen.