Considering the relations between interaction terms in microscopic Hamiltonian and terms in macroscopic Landau's free-energy-function (FEF) of a phase transition system, we propose a modified Landau's phenomenological FEF to deal with critical phenomena. According to scaling symmetry, it is indeed true that, the dimension of interaction space is fractal at critical points for a phase transition system. Following these analyses, we obtain all the critical indices reasonably classified in the classes denoted by , which satisfy all the scaling laws and coincide with experiments. A cogent example is given.
Considering the relations between interaction terms in microscopic Hamiltonian and terms in macroscopic Landau's free-energy-function (FEF) of a phase transition system, we propose a modified Landau's phenomenological FEF to deal with critical phenomena. According to scaling symmetry, it is indeed true that, the dimension of interaction space is fractal at critical points for a phase transition system. Following these analyses, we obtain all the critical indices reasonably classified in the classes denoted by , which satisfy all the scaling laws and coincide with experiments. A cogent example is given.
The continuous phase transition, indicated by the macroscopic order parameter and the occurrence of the spontaneous symmetry breaking, is well illustrated based on the Ginzburg-Landau's paradigm. In systems described by one order parameter, the phase diagram is only composed of the normal phase and the ordered phase. However, in systems with two or more order parameters, much richer phase diagrams and critical phenomena may emerge. According to coupling terms of the free energy, we classify the systems with two order parameters into several categories, featuring different patterns of phase diagrams and critical scalings respectively. Our work propose the new avenue to studying and evaluating the complex systems only based on the coupling terms in expressions of free energy.
Landau theory relates phase transitions to the minimization of the Landau functional (e.g., free energy functional), which is expressed as a power series of the order parameter. It has been shown that the critical behavior of certain physical systems can be described using Landau functionals that include nonanalytic terms, corresponding to odd or even noninteger powers of the absolute value of the order parameter. In particular, these nonanalytic terms can determine the order of the phase transition and the values of the critical exponents. Here, we show that such terms can also shape the finite-size scaling behavior of fluctuations of observables (e.g., of energy or magnetization) or the response functions (e.g., heat capacity or magnetic susceptibility) at the continuous phase transition point. We demonstrate this on two examples, the equilibrium molecular zipper and the nonequilibrium version of the Curie-Weiss model.
To set the stage for our subsequent thorough discussion of dynamic critical phenomena, we first review the theoretical description of second-order equilibrium phase transitions. (Readers already well acquainted with this material may readily move on to Chapter 2.) To this end, we compare the critical exponents following from the van-der-Waals equation of state for weakly interacting gases with the results from the Curie–Weiss mean-field approximation for the ferromagnetic Ising model. We then provide a unifying description in terms of Landau–Ginzburg theory, i.e., a long-wavelength expansion of the effective free energy with respect to the order parameter. The Gaussian model is analyzed, and a quantitative criterion is established that defines the circumstances when non-linear fluctuations need to be taken into account properly. Thereby we identify d c = 4 as the upper critical dimension for generic continuous phase transitions in thermal equilibrium. The most characteristic feature of a critical point turns out to be the divergence of the correlation length that renders microscopic details oblivious. As a consequence, not only the correlation functions, but remarkably the thermodynamics as well of a critical system are governed by an emergent unusual symmetry: scale invariance. A simple scaling ansatz is capable of linking different critical exponents; as an application, we introduce the basic elements of finite-size scaling. Finally, a brief sketch of Wilson's momentum shell renormalization group method is presented, intended as a pedagogical preview of the fundamental RG ideas. Exploiting the scale invariance properties at the critical point, the scaling forms of the free energy and the order parameter correlation function are derived.
A phenomenological description of first-order phase transitions is proposed in terms of the solution of a certain linear, first-order, partial differential equation suggested by Fisher. In the asymptotic region of the critical point, the coefficient functions of the equation are uniquely determined by the scaling laws. The imposition of the further requirement that the phase boundary coincide with a characteristic curve of this equation is shown to lead to solutions that can reproduce the singular behavior---for example, the density and entropy discontinuities for the case of the liquid-gas transition---along the entire vapor-pressure curve. The important role played by the characteristic curves is stressed and confirmed for the special case of the ideal, d-dimensional, Bose gas. New relations involving discontinuities in the second derivatives of the thermodynamic functions are derived and shown to be useful in obtaining the coefficient functions near the phase boundary. Details are presented for the case of ferromagnetic and ferroelectric systems and include a comparison with experiment.
Abstract Understanding phase transitions requires not only identifying order parameters but also characterizing how their correlations behave across scales. By quantifying how fluctuations at distinct spatial or temporal points are related, correlation functions reveal the structural organization of complex systems. In this work, we reexamine the theoretical foundations of these correlations in systems undergoing second-order phase transitions, with emphasis on the Ising model extended to non-integer spatial dimensions. We revisit the hypotesis that, at criticality, the equilibrium dynamics become effectively confined to the fractal edge of spin clusters and redo the analysis using fractional calculus. Within this framework, the fractal dimension that governs the correlations in that subspace is directly related to Fisher’s exponent η η , which quantifies the singular behavior of the correlation function near criticality. Importantly, this correlation fractal dimension is distinct from the fractal dimension associated with the order parameter. The fractional approach allows us to directly compute the correlation fractal dimension and to establish an explicit geometrical relation connecting the two fractal dimensions. Moreover, the formulation naturally extends to non-integer spatial dimensions, remaining valid below the upper critical dimension and yielding the correct value of Fisher’s exponent η η for a continuous spatial dimension d . Within this framework, we also provide empirical functions describing how the main critical exponents vary continuously as a function of the space dimension.
Critical phenomena, characterized by abrupt changes in macroscopic properties near phase transition points, exhibit universal scaling behavior independent of microscopic details. This paper explores the hypothesis that entropy serves as a fundamental universal scaling law governing these phenomena. We review the theoretical foundations of critical phenomena, including Landau theory and the renormalization group, highlighting the role of critical exponents and scaling functions. We then propose a framework where the configurational entropy, entanglement entropy, and other entropic measures exhibit universal scaling, linking them directly to the underlying critical exponents. Our methodology involves analyzing how entropy behaves under coarse-graining transformations near critical points, identifying a potential entropic fixed point in the renormalization group flow. We present theoretical arguments suggesting that the information content, as quantified by various entropy definitions, reflects the diverging correlation length and the emergent scale invariance at criticality. The discussion extends to how different entropic forms, such as Rényi and Tsallis entropies, might provide a more generalized framework for understanding critical behavior in complex and non-extensive systems. By demonstrating entropy's role as a universal scaling law, this work offers a unifying perspective on critical phenomena, deepening our understanding of phase transitions and the emergence of macroscopic order from microscopic fluctuations.