A theoretical study is conducted on the stability of exotic antiproton-hydrogen molecular anions (
pH), which in the separated atom limit correlate with
p+H(n=2) (
n being the principal quantum number). The
pH molecule in the electronic ground state is highly unstable due to pair annihilation and autodetachment ($\ensuremath{\rightarrow}\overline{p}p+e$). However, if the
pH molecule is electronically excited, the molecular stability can be drastically improved. Since the excited states of the
H atom have accidental degeneracy, the asymptotic form of the Born-Oppenheimer potential curve of
p+H(n=2) behaves as
1/R2 (
R being the relative distance), which can play a critical role in the bonding and stability of the molecule. It is found that the
pH molecule in the first electronic excited state and in a high rotational state is sufficiently stable and has a lifetime dominated by spontaneous radiative emission ($\ensuremath{\rightarrow}\overline{p}+\mathrm{H}+h\ensuremath{\nu}$). The
pH system is dynamically similar to ${\mathrm{H}}_{2}{\phantom{\rule{0.16em}{0ex}}}^{\ensuremath{-}}$, which had been commonly considered to be unstable due to autodetachment. However, recent measurements of ion-beam sputtering unambiguously verified the existence of long-lived ${\mathrm{H}}_{2}{\phantom{\rule{0.16em}{0ex}}}^{\ensuremath{-}}$ molecules in high rotational states. This suggests that the
pH molecules may actually be created if one employs experimental means such as the chemical sputtering of hydrogen-rich targets with
p beams.
Accurate three-body quantal calculations of the system composed of a proton, an antiproton, and an electron are performed in perimetric coordinates with the Lagrange-mesh method, an approximately variational calculation with the simplicity of a calculation on a grid. Quasibound states with respect to the
p+H(n=2) threshold are obtained for $L=60\ensuremath{-}73$ for various vibrational excitations. Their energies have accuracies up to about ${10}^{\ensuremath{-}14}$ atomic units, while less precise energies are determined for
L=56−−59 broader resonances. Their structure is analyzed with the help of mean distances between the particles. These mean distances indicate that the proton-electron subsystem is in excited states, mostly
n=2, as predicted by Sakimoto [Phys. Rev. A 98, 042503 (2018)] with the Born-Oppenheimer approximation. A comparison performed with this approximation provides the accuracies of its energies and of its proton-antiproton mean distances.
The exotic helium atom, consisting of a helium nucleus
He2+, an electron ${\mathit{e}}^{\mathrm{\ensuremath{-}}}$, and a massive, negatively charged particle ${\mathit{X}}^{\mathrm{\ensuremath{-}}}$, such as an antiproton (p\ifmmode\bar\else\textasciimacron\fi{}) or a kaon (${\mathit{K}}^{\mathrm{\ensuremath{-}}}$), is studied theoretically. This exotic atom is more like a polar molecule with two nuclei
He2+ and ${\mathit{X}}^{\mathrm{\ensuremath{-}}}$, if ${\mathit{e}}^{\mathrm{\ensuremath{-}}}$ is in a low-lying orbital and ${\mathit{X}}^{\mathrm{\ensuremath{-}}}$ is in a highly excited orbital. Such states are generally formed in the capture of ${\mathit{X}}^{\mathrm{\ensuremath{-}}}$ by helium. The Born-Oppenheimer (BO) separation of the ${\mathit{e}}^{\mathrm{\ensuremath{-}}}$ motion and the
He2+-${\mathit{X}}^{\mathrm{\ensuremath{-}}}$ motion is a good approximation for these states, and affords a transparent, unified perspective of exotic helium with different ${\mathit{X}}^{\mathrm{\ensuremath{-}}}$ and different isotopes of
He2+. A propensity rule that favors small transition energies (except for the smallest one) is found for radiative emission by low vibrational and high rotational levels. This rule resembles the selection rule for infrared emission by the usual diatomic polar molecules, and contradicts the conventional expectation that radiative transitions in exotic atoms favor larger transition energies. The radiative lifetimes \ensuremath{\tau} of highly excited states formed immediately after the capture of ${\mathit{X}}^{\mathrm{\ensuremath{-}}}$ are of the order of \ensuremath{\mu}sec for
4He2+-p\ifmmode\bar\else\textasciimacron\fi{}-${\mathit{e}}^{\mathrm{\ensuremath{-}}}$ and
3He2+-p\ifmmode\bar\else\textasciimacron\fi{}-${\mathit{e}}^{\mathrm{\ensuremath{-}}}$, and those for
4He2+-${\mathit{K}}^{\mathrm{\ensuremath{-}}}$-${\mathit{e}}^{\mathrm{\ensuremath{-}}}$ are about half the values for the antiprotonic helium.The effect of the electronic charge polarization by ${\mathit{X}}^{\mathrm{\ensuremath{-}}}$ on \ensuremath{\tau} is explained quantitatively in a simple picture in terms of the molecular dipole moment. Low vibrational, high rotational states are described as circular or near-circular states in the atomic picture. They are stable against Auger decay, which the nonadiabatic perturbation on the BO states induces. An infinite series of bound \ensuremath{\Sigma} electronic states of exotic helium negative ions (
He2+-${\mathit{X}}^{\mathrm{\ensuremath{-}}}$-${\mathit{e}}^{\mathrm{\ensuremath{-}}}$)-${\mathit{e}}^{\mathrm{\ensuremath{-}}}$ exists for any
He2+-${\mathit{X}}^{\mathrm{\ensuremath{-}}}$ distances R beyond 0.819 a.u. in the BO approximation. An infinite \ensuremath{\Pi} series exists for R>3.811 a.u., and an infinite \ensuremath{\Delta} series for R>9.532 a.u.
The main properties of the interaction of ultralow-energy antiprotons $(E<~{10}^{\ensuremath{-}6}$ a.u.) with atomic hydrogen are established. They include the elastic and inelastic cross sections and protonium (Pn) formation spectrum. The inverse Auger process $(\mathrm{Pn}+\stackrel{\ensuremath{\rightarrow}}{e}\mathrm{H}+\overline{p})$ is taken into account in the framework of a unitary coupled-channel model. The annihilation cross section is found to be several times smaller than the predictions made by the black sphere absorption models. A family of
pH near-threshold metastable states is predicted. The dependence of protonium formation probability on the position of such near-threshold
S-matrix singularities is analyzed. An estimation for the $\mathrm{H}\mathrm{H}\ifmmode\bar\else\textasciimacron\fi{}$ annihilation cross section is obtained.
The stability of antimatter in contact with matter has been investigated. The interaction between hydrogen and antihydrogen is considered as the prototype reaction. We have focused interest on the rates for proton-antiproton and/or electron-positron annihilation during hydrogen-antihydrogen collisions at low energies. In particular, we have concentrated on the calculation of the rates for the rearrangement reaction leading to formation of protonium and positronium, ending inevitably in particle-antiparticle annihilation. The cross section for the rearrangement collision has been calculated in a fully quantum-mechanical treatment. Additionally, we have calculated cross sections for direct annihilation during the collision process, which was found to be comparable to the rearrangement cross section. The elastic cross section and its low-energy limit, given by the scattering length, have been calculated, allowing, by comparison to the inelastic processes, a prediction for the efficiency of cooling antihydrogen via collisions with ultracold hydrogen atoms.
We report a theoretical study of antihydrogen-hydrogen molecular resonance states consisting of a positron, an antiproton, an electron and a proton. The four particles strongly correlate and show different character from the hydrogen molecule. Because of the non-separability of the positron and electron motions from the antiproton and proton motions, the adiabatic approximation breaks down at the short antiproton-proton distance. Based on a non-adiabatic method, we directly solve the four-body problem and obtain the resonance energies and widths. In order to examine the roles of positron–antiproton and electron–proton correlations as well as positron–electron and antiproton–proton correlations, we introduce two different types of coordinate systems. One is suited for describing an antihydrogen–hydrogen configuration, and the other is a positronium–protonium configuration. The antihydrogen–hydrogen configuration contributes to the existence of the molecular resonance states, and the positronium–protonium configuration makes the resonance states unstable. Mixing of the two configurations results in an antihydrogen-hydrogen molecular resonance state, and the resonance state has an energy of −0.077 9(3) a.u. from the antihydrogen–hydrogen dissociation threshold with its lifetime 16 (2) fs.