We study the entanglement of two adsorbed polar molecules in static electric fields. The concurrence is estimated to quantify the entanglement. The adsorbed molecules reveal significant rotational characteristics, such as anticrossing features, due to the influences of electric field and quantum confinement. Numerical results demonstrate that these rotational properties dominate the amount and profile of concurrence. At zero temperature, an enhanced concurrence is obtained near the anticrossing in the ground state. Moreover, we analyze the effect of temperature on the concurrence. The temperature-dependent concurrence displays a suppressed behavior, especially at the anticrossing.
We study the entanglement of two adsorbed polar molecules in static electric fields. The concurrence is estimated to quantify the entanglement. The adsorbed molecules reveal significant rotational characteristics, such as anticrossing features, due to the influences of electric field and quantum confinement. Numerical results demonstrate that these rotational properties dominate the amount and profile of concurrence. At zero temperature, an enhanced concurrence is obtained near the anticrossing in the ground state. Moreover, we analyze the effect of temperature on the concurrence. The temperature-dependent concurrence displays a suppressed behavior, especially at the anticrossing.
Dynamic entanglement between two end molecules in a polar-molecule array is investigated in static electric fields. Specific initial states are set to probe the evolution of the molecular system under the influence of intrinsic decoherence. We analyze the degree of entanglement between the end molecules by use of concurrence. When the Bell states are initially shared between the end molecules, the end-to-end concurrence shows either a fragile or a robust behavior. The robust concurrence is less affected by decoherence, reflecting a situation that the initial Bell state can be shared between the end molecules for long periods of time. The stability of the entanglement shared between two arbitrary molecules in the array is further studied. Furthermore, we show how to induce a high end-to-end concurrence via transfer of a separable state. The state is transferred from one end molecule to the other. During the back-and-forth transfer processes, the concurrence cyclically reveals high peaks, corresponding to different Bell-like states. In addition, population inversion is observed to only occur at the end molecules in the array. We further examine the contribution of effective states to the concurrence and discuss the effects of decoherence, dipole-field interaction, and dipole-dipole interaction on its properties.
In proposals for quantum computers using arrays of trapped ultracold polar molecules as qubits, a strong external field with appreciable gradient is imposed in order to prevent quenching of the dipole moments by rotation and to distinguish among the qubit sites. That field induces the molecular dipoles to undergo pendular oscillations, which markedly affect the qubit states and the dipole-dipole interaction. We evaluate entanglement of the pendular qubit states for two linear dipoles, characterized by pairwise concurrence, as a function of the molecular dipole moment and rotational constant, strengths of the external field and the dipole-dipole coupling, and ambient temperature. We also evaluate a key frequency shift, △ω, produced by the dipole-dipole interaction. Under conditions envisioned for the proposed quantum computers, both the concurrence and △ω become very small for the ground eigenstate. In principle, such weak entanglement can be sufficient for operation of logic gates, provided the resolution is high enough to detect the △ω shift unambiguously. In practice, however, for many candidate polar molecules it appears a challenging task to attain adequate resolution. Simple approximate formulas fitted to our numerical results are provided from which the concurrence and △ω shift can be obtained in terms of unitless reduced variables.
We examine the potential-energy curves and polarization of the dipole moments of two static polar molecules under the influence of an external dc electric field and their anisotropic dipole-dipole interaction. We model the molecules as quantum rigid rotors to take their rotational degrees of freedom into account and consider a selection of linear, symmetric, and asymmetric top molecules. We provide a comprehensive examination of the energy curves and polarization of the dipoles for varying intermolecular separation and direction of the electric field and find that the properties of the molecules depend strongly on the field's direction at short separations, showing the importance of accounting for molecular rotation. The latter provides insight into the possible effects of accounting for rotational degrees of freedom in molecular dipolar gases. Published by the American Physical Society 2024
In proposals for quantum computers using arrays of trapped ultracold polar molecules as qubits, a strong external field with appreciable gradient is imposed in order to prevent quenching of the dipole moments by rotation and to distinguish among the qubit sites. That field induces the molecular dipoles to undergo pendular oscillations, which markedly affect the qubit states and the dipole-dipole interaction. We evaluate entanglement of the pendular qubit states for two linear dipoles, characterized by pairwise concurrence, as a function of the molecular dipole moment and rotational constant, strengths of the external field and the dipole-dipole coupling, and ambient temperature. We also evaluate a key frequency shift, △ω, produced by the dipole-dipole interaction. Under conditions envisioned for the proposed quantum computers, both the concurrence and △ω become very small for the ground eigenstate. In principle, such weak entanglement can be sufficient for operation of logic gates, provided the resolution is high enough to detect the △ω shift unambiguously. In practice, however, for many candidate polar molecules it appears a challenging task to attain adequate resolution. Simple approximate formulas fitted to our numerical results are provided from which the concurrence and △ω shift can be obtained in terms of unitless reduced variables.
We determine trapping conditions for ultracold polar molecules, where pairs of internal states experience identical trapping potentials. Such conditions could ensure that detrimental effects of inevitable inhomogeneities across an ultracold sample are significantly reduced. In particular, we investigate the internal rovibronic and hyperfine quantum states of ultracold fermionic ground-state 40K87Rb polar molecules, when static magnetic, static electric and trapping laser fields are simultaneously applied. Understanding the effect of changing the relative orientation or polarisation of these three fields is of crucial importance for the creation of decoherence-free subspaces built from two or more rovibronic states. Moreover, we evaluate the induced dipole moment of the molecule in the presence of these fields, which will allow control of interactions between molecules in different sites of an optical lattice, and study the influence of the interaction anisotropy on the ability to entangle polar molecules.
Abstract We consider two ultracold polar symmetric top molecules coupled by dipole-dipole interaction in an external electric field with appreciable intensity gradient, serving as the physical carrier of quantum information. Each molecule is induced to undergo pendular oscillations under the strong static electric field. Based on the pendular states of polar symmetric top molecules as candidate qubits, we investigate the bipartite quantum correlations of the two polar molecular system for the thermal equilibrium states, characterized by negativity and quantum discord, and then analyze the corresponding coherence, measured by relative entropy and l1 norm. Furthermore, we also examine the dynamics of the entanglement and coherence of the system in the presence of intrinsic decoherence, and explore the relations of their temporal evolution with various physical system parameters for two different initial Bell states. It is found that quantum correlations and coherence of the two polar molecules in pendular states can be manipulated by adjusting appropriate reduced variables including external electric field, dipole-dipole interaction, ambient temperature and decoherence factor. Our findings could be used for molecular quantum computing based on rotational states.