We formulate a method to derive the time-dependent Schr\"odinger equation which describes the interaction of an electron with a $c$-number radiation field. To obtain this semiclassical approximation from the complete quantum-mechanical formulation we use the corresponding Schr\"odinger equation in its projection form, which is an extension of the Hill-Wheeler generator coordinate method. For the basis states of the radiation field we introduce a complete, but not overcomplete, subset of coherent states, which were found by von Neumann and whose proof of completeness was given by Bargmann et al. and Perdomov. We find that the conventional overcomplete continuous coherent states are not suitable for the projection form of the Schr\"odinger equation. The method also allows one to calculate quantum-mechanical correction terms systematically.
We formulate a method to derive the time-dependent Schr"odinger equation which describes the interaction of an electron with a c-number radiation field. To obtain this semiclassical approximation from the complete quantum-mechanical formulation we use the corresponding Schr"odinger equation in its projection form, which is an extension of the Hill-Wheeler generator coordinate method. For the basis states of the radiation field we introduce a complete, but not overcomplete, subset of coherent states, which were found by von Neumann and whose proof of completeness was given by Bargmann et al. and Perdomov. We find that the conventional overcomplete continuous coherent states are not suitable for the projection form of the Schr"odinger equation. The method also allows one to calculate quantum-mechanical correction terms systematically.
The previously proposed method to obtain classical limits of quantized fields using von Neumann - lattice coherent states as basis states for the projection form of the Schr\"odinger equation is modified in order to take into account the reaction of the radiation field to the charge in a compact manner. The modification is based on the work of Glauber on the time evolution of coherent states. To illustrate the method, a charged harmonic oscillator with and without initial external electromagnetic field is investigated.
The interaction of an atomic system with an unquantized electromagnetic field is studied by means of the Heisenberg-operator equations of motion. The electromagnetic fields created by the atom are taken into account by assuming that the charge and probability current densities are the actual charge and current source terms in Maxwell's equation. When Ehrenfest's theorem is written to order (1/c)2, the equations of motion are found to have a constant of motion that can be interpreted as stating that the sum of the atomic energy, energy of interaction, and energy stored in the electromagnetic field is constant. This constant of integration can be expressed as an expectation of a new semiclassical Hamiltonian that now includes the effects of the atomic self-fields to order 1/c2. This Hamiltonian is related to the classical Darwin Lagrangian. Since the new approximate Hamiltonian is the sum of an atomic and a field Hamiltonian, it provides a formulation of semiclassical radiation theory that is formally close to the usual formulation of quantum electrodynamics. A Schr\"odinger equation can be derived by applying the variational principle to the expectation of the new Hamiltonian. The result is a nonlinear integro-differential equation, in \ensuremath{\Psi}, which is somewhat similar to Hartree's self-consistent equation for a multielectron atom.When the Heisenberg equations are written to include the next-higher-order terms, 1/c3, it is found that the total energy of the atom and the electromagnetic field in the vicinity of the atom decreases at a rate that is given by the Larmor power formula (2e2/3c3)(d〈v〉/dt)2, where 〈v〉 is the quantum-mechanical expectation of the electron's velocity operator. This approximate formulation of semiclassical radiation theory is applied to semiclassical calculations of atomic radiative shifts. It is then shown that, if some retardation effects are included to all orders of 1/c in the vector potential, the semiclassical analysis provides a formula for radiative energy-level shifts that are time dependent and that contain coefficients similar to the starting point of the Bethe calculation of the Lamb shift. The incorporation of mass renormalization in semiclassical theory is then discussed.
The time-dependent Schrodinger for an atom in a radiation field has a very special form, at least within the dipole approximation: The time-dependence of the Hamiltonian is contained entirely in a c-number which appears as a factor in the interaction, V(t), of the atom with the radiation field. In the velocity gauge this factor is the vector potential, A(t), of the field — we have V(t)= − (e/µc)A (t) • p, where e, µ, and p are the charge, reduced mass, and canonical momentum (in the center of mass frame) of the electron — while in the length gauge this factor is the electric field vector F(t) — we have V(t) = –eF(t) • x, where x is the position coordinate. To our knowledge, this factorization property has not been fully exploited in previous approaches to solving the timedependent Schrodinger equation1. As we show here, in an application to multiphoton ionization of atomic hydrogen, it is an extremely useful property; and although at first sight it would seem to be a unique feature of the atom-radiation system, this is not so, for, as Solov’ev2 has pointed out, the time-dependent Schrödinger equation for colliding atoms or ions can be transformed into a form in which a scaled time-dependence also appears only in c-number factors of the (transformed) interactions.
We study the general problem of matter-laser interaction within the framework of nonrelativistic quantum electrodynamics, with particular emphasis on strong laser field effects. Consequently, we formulate a well-defined approximation leading in a straightforward manner toward the conventional semiclassical mode of description. Namely, we arrive naturally to two coupled equations of motion: (i) the Schr\"odinger equation which governs the quantum dynamics of an atomic system driven by classically described radiation field (composed of an incoming laser pulse plus radiation emitted from the atom), and (ii) the classical Maxwell wave equation which describes the emission of radiation from the mentioned atomic source. Employing the formalism of adiabatic Floquet theory, we derive a simple criterion of validity of the just described semiclassical approach. It shows that the semiclassical treatment is justified in most situations. On the other hand, it turns out that the semiclassical approximation breaks down completely in certain special but realistic cases, regardless of the fact that the incoming laser pulse contains a huge number of photons. Under such special circumstances, we anticipate new effects arising due to the quantized nature of the radiation field, to be observable, for example, in harmonic generation spectra. Our considerations are illustrated more explicitly using a simple model of a two-level atom strongly driven by a laser. The quantum dynamics of this model problem is resolved within the framework of quantum electrodynamics while adopting well-defined and physically justifiable approximations. As an outcome, analytic formulas are found serving as a quantitative criterion of (non)applicability of the semiclassical approach and demonstrating the breakdown of semiclassical theory under well-defined conditions. An illustrative numerical calculation is provided.
The interaction of nonrelativistic matter with the quantized electromagnetic field is investigated in the classical limit of large photon numbers. Quantization of both matter, say an atom, and the field results in a time-independent Schr\"odinger equation (TISE). However, for very strong fields (quantum mechanically, large photon numbers) this is impractical to solve. The standard approach then is simply to replace the quantized field by a classical field to give a time-dependent Schr\"odinger equation (TDSE) for the atom alone. Here we show how this TDSE can be derived from the TISE for atom plus field, illustrating at each stage the approximations that are necessary to treat the field classically. An important difficulty at the semiclassical stage is a breakdown of the approximation at classical turning points. We show how the use of coherent field states can circumvent this problem. In the limit that the field can be treated classically, time emerges from the Maxwell equations and a TDSE for the atom alone results.
Methods are developed for discussing the photon statistics of arbitrary fields in fully quantum-mechanical terms. In order to keep the classical limit of quantum electrodynamics plainly in view, extensive use is made of the coherent states of the field. These states, which reduce the field correlation functions to factorized forms, are shown to offer a convenient basis for the description of fields of all types. Although they are not orthogonal to one another, the coherent states form a complete set. It is shown that any quantum state of the field may be expanded in terms of them in a unique way. Expansions are also developed for arbitrary operators in terms of products of the coherent state vectors. These expansions are discussed as a general method of representing the density operator for the field. A particular form is exhibited for the density operator which makes it possible to carry out many quantum-mechanical calculations by methods resembling those of classical theory. This representation permits clear insights into the essential distinction between the quantum and classical descriptions of the field. It leads, in addition, to a simple formulation of a superposition law for photon fields. Detailed discussions are given of the incoherent fields which are generated by superposing the outputs of many stationary sources. These fields are all shown to have intimately related properties, some of which have been known for the particular case of blackbody radiation.