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Kakuyūgō kenkyū

Ion Trap. Recent Experiments.

Makoto Sakuai, Masahiro Kimura, Shunsuke Ohtani

Published Jan 1, 1991• 0 citations
Publisher

Abstract

Recent experimental works with ion traps are surveyed.Ion traps can confine ions of very low-energy in a small space, and they are useful tools for the precise spectroscopy of ions.Basic ideas on trapping mechanism of several types of the traps and detection methods of trapped ions are summarized.Major topics are ultrahigh-resolution spectroscopy of ions using laser cooling methods and physics on one-component plasmas such as localization, phase transition and crystallization of ion cloud.Applications to elementary particle physics , nuclear physics and atomic physics on multiply charged ions are also presented.

DOI
10.1585/jspf1958.66.224

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Recent experimental works with ion traps are surveyed.Ion traps can confine ions of very low-energy in a small space, and they are useful tools for the precise spectroscopy of ions.Basic ideas on trapping mechanism of several types of the traps and detection methods of trapped ions are summarized.Major topics are ultrahigh-resolution spectroscopy of ions using laser cooling methods and physics on one-component plasmas such as localization, phase transition and crystallization of ion cloud.Applications to elementary particle physics , nuclear physics and atomic physics on multiply charged ions are also presented.
Translationally cold, spatially localised molecular ions prepared by sympathetic cooling with laser-cooled atomic ions in ion traps have recently found a wide range of applications in both chemistry and physics. The very low temperatures of the ions (down to millikelvins), their tight localisation in the trap and the ability to control and manipulate single isolated molecules on the quantum level offer intriguing possibilities for new experiments in the realms of cold chemistry, precision molecular spectroscopy, mass spectrometry and quantum technology. The present article gives an overview of the basic experimental methods, current topics and recent developments in this field.
Ensembles of cold atomic and molecular ions in ion traps prepared at millikelvin temperatures by laser and sympathetic cooling have recently found considerable interest in both physics and chemistry. At very low temperatures the ions form ordered structures in the trap also known as "Coulomb crystals". Ion Coulomb crystals exhibit a range of intriguing properties which render them attractive systems for novel experiments in chemical dynamics, ultrahigh-resolution spectroscopy and quantum-information processing. In this article we review the methods used to prepare atomic and molecular ion Coulomb crystals and discuss some recent studies in mass spectrometry, low-temperature chemistry and precision spectroscopy to illustrate their scientific potential for chemical applications. Finally, we conclude with an outlook on outstanding challenges and prospective further developments in the field.
Examples of recent experiments are presented which show characteristic features associated with the technique of ion trapping: Ultrahigh resolution in hyperfine spectroscopy due to long coherence time, lifetime measurements for very long living states and rare isotope investigation due to the high sensitivity of optical detection of stored ions. The possibility of experiments of fundamental quantum mechanical interest will be pointed out. In addition a few open questions associated with the behaviour of large ion clouds, which might influence the precision of future experiments, will be discussed.
Trapped and laser-cooled ions are increasingly used for a variety of modern high-precision experiments, for frequency standard applications, and for quantum information processing. Therefore laser cooling of trapped ions is reviewed, the current state of the art is reported, and several new cooling techniques are outlined. The principles of ion trapping and the basic concepts of laser cooling for trapped atoms are introduced. The underlying physical mechanisms are presented, and basic experiments are briefly sketched. Particular attention is paid to recent progress by elucidating several milestone experiments. In addition, a number of special cooling techniques pertaining to trapped ions are reviewed; open questions and future research lines are indicated.
One of the current themes in quantum physics is the creation of cold ( 1 K) molecules to study molecule-molecule, molecule-atom, and molecule-radiation interactions under these novel low-temperature conditions. This book highlights the field of cold trapped molecular ions. In particular, the development of a novel, universal cooling method for charged particles, sympathetic cooling using laser-cooled atoms, together with the experimental and computational techniques required are extensively reviewed. The book also reviews first spectacular applications of the cold ion ensembles produced: the study of the properties of cold non-neutral plasmas, the study of ion-neutral chemical reactions and of photodissociation processes, and high-resolution rotational overtone spectroscopy of cold hydrogen molecular ions with unprecedented spectral resolution. The large potential of this field of research and its possible impact to other fields of physics, chemistry, and biology are highlighted. The book summarizes the main lines of research in cold trapped molecular ion physics, thus, making it useful as an introduction for advanced students and experienced researchers.
A range of experimental techniques for application in reaction studies between ionic and neutral atoms/molecules and high resolution spectroscopy experiments with sympathetically cooled molecular ions are presented. A novel ion trap loading scheme using the photo-ionisation of atoms generated by the pulsed laser ablation of a solid calcium target has been characterised. We have identified the range of ablation laser fluences that must be used in order to produce a flux of neutral calcium atoms, which is a prerequisite for isotope selective ion trap loading. Calcium ions are trapped and laser cooled in a linear radio-frequency ion trap. We have developed a spectroscopy scheme that allows the entire fluorescence spectrum of trapped ions to be rapidly collected with high precision while maintaining a low ion temperature and good ion localisation throughout interrogation. The scheme has been demonstrated by measuring the saturation intensity of the calcium ion 4S1/2?4P1/2 transition. We have developed a novel scheme to measure the secular motion of trapped ions and demonstrated the application of the technique to ion-neutral collision reaction experiments. Employing pulsed excitation and Doppler velocimetry, we have measured the centre-of-mass mode frequency of single ions as well as large ion crystals with a frequency precision better than 2x10-3 within an interrogation time on the order of seconds. This method has been used to measure the mass of ions and observe charge exchange collisions between trapped calcium isotopes. In particular, we have measured the 44Ca++40Ca!40Ca++44Ca reaction cross section and demonstrated the single-event resolution of the technique. Finally, we have developed a novel all-optical broadband scheme for exciting, amplifying and measuring the secular motion of ions in the trap. Oscillation induced by optical excitation has been coherently amplified to control and measure the ion's secular motion. Requiring only a single interrogation laser, the ion's oscillation amplitude can be precisely controlled. The application of this technique to non-destructive spectroscopy of trapped molecular ions is discussed.