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AIAA Thermophysics Conference

The application of quantum statistical thermodynamics

Jurij Avsec, Milan Marčič

Published Jun 19, 2000• 0 citations
Publisher
DOI
10.2514/6.2000-2509

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In this paper, we give a pedagogical introduction to the ideas of quantum thermodynamics and work fluctuations, using only basic concepts from quantum and statistical mechanics. After reviewing the concept of work as usually taught in thermodynamics and statistical mechanics, we discuss the framework of non-equilibrium processes in quantum systems together with some modern developments, such as the Jarzynski equality and its connection to the second law of thermodynamics. We then apply these results to the problem of magnetic resonance, where all calculations can be done exactly. It is shown in detail how to build the statistics of the work, both for a single particle and for a collection of non-interacting particles. We hope that this paper will serve as a tool to bring the new student up to date on the recent developments in non-equilibrium thermodynamics of quantum systems.
We develop a Lindblad framework for quantum stochastic thermodynamics to study the nonequilibrium thermodynamics of open quantum systems. Our approach adopts the local quantum detailed balance condition, ensuring thermodynamic consistency and leading to a joint fluctuation theorem of quantum work and heat. Instead of solving the full evolution of the density matrix, we employ an effective parametrization to derive the full counting statistics of work and heat and determine the optimal protocols. As an application, we refine the quantum Brownian motion master equation to ensure the quantum detailed balance condition, derive the optimal protocols at different temperatures, and study the work statistics. Our framework provides fundamental insights and practical strategies for optimizing thermodynamic processes in open quantum systems.