We present measurements of inelastic collisions between ultracold Cs Rydberg atoms using time-of-flight velocity distributions. The collision mechanism is identified by comparison to Rydberg atom pair potentials calculated using matrix diagonalization.
Rydberg-Rydberg collisions in a cold, dense Rydberg gas can lead to the conversion of internal energy into center-of-mass energy of the colliding atoms, resulting in Rydberg-atom velocities much larger than the initial velocities in the gas. We prepare cold Rydberg-atom gases by laser excitation of laser-cooled atom clouds and use time-of-flight measurements to demonstrate the production of fast Rydberg atoms. The velocity distributions of Rydberg atoms emerging from the Rydberg-atom gases are obtained. State-selective field ionization spectra indicate a correlation between the production of fast Rydberg atoms and the presence of Penning ionization signatures. The dependence of the yield of fast Rydberg atoms on Rydberg atom density is measured.
We present calculations of potential curves for very high-n(89D) Cs Rydberg-atom pairs, including a background electric field. From these potentials, we show that energy transfer occurs at rates of $\ensuremath{\sim}30--70\phantom{\rule{0.3em}{0ex}}\mathrm{MHz}$, background electric fields play an important role and dipole-dipole- and quadrupole-quadrupole-induced avoided curve crossings should lead to conversion of electronic to kinetic energy, n-changing collisions, and observable ultracold long-range Rydberg molecules.