A simple method to obtain the Hamiltonian from each unidimensional dynamical system. Each unidimensional system is so quantizable. It is probable that each multidimensional system is quantizable, because of the generalization of the idea.
The quantum dynamics of a simplest dissipative system, a particle moving in a constant external field , is exactly studied by taking into account its interaction with a bath of Ohmic spectral density. We apply the main idea and methods developed in our recent work [1] to quantum dissipative system with constant external field. Quantizing the dissipative system we obtain the simple and exact solutions for the coordinate operator of the system in Heisenberg picture and the wave function of the composite system of system and bath in Schroedinger picture. An effective Hamiltonian for the dissipative system is explicitly derived from these solutions with Heisenberg picture method and thereby the meaning of the wavefunction governed by it is clarified by analyzing the effect of the Brownian motion. Especially, the general effective Hamiltonian for the case with arbitrary potential is directly derived with this method for the case when the Brownian motion can be ignored. Using this effective Hamiltonian, we show an interesting fact that the dissipation suppresses the wave packet spreading.
The fast dynamics of molecular polaritonics is scrutinized theoretically through the implementation of two-dimensional spectroscopy protocols. We derive conceptually simple and computationally efficient formulas to calculate two-dimensional spectra for molecules, each of them modeled as a system of two electronic states including vibrational relaxation, immersed in an optical cavity, thus coupled to quantized radiation. Cavity photon losses and molecular relaxation are incorporated into the Hamiltonian dynamics to form an open quantum system that is solved through a master equation. In the collective case, the relaxation dynamics into dark states is revealed to be the crucial factor to explain the asymmetries in both the diagonal and cross peaks of two-dimensional spectra for long waiting times between excitation and detection, a feature shown by recent experiments. Our theoretical method provides a deeper insight in those processes that yield relevant signals in multidimensional molecular spectroscopy.