This chapter discusses the prime cause of the magnetic moment within an individual atom. In the classical model, the angular momentum of the electrons can be used to determine the magnetic moments of the electrons by invoking the concept of electrical charge in motion. There are two contributions to the electronic magnetic moment: an orbital magnetic moment due to orbital angular momentum and a spin magnetic moment due to electron spin. The component of orbital angular momentum along the axis of a magnetic field is restricted to discrete values by quantum mechanics. Electrons have spin angular momentum, which can be represented by the spin quantum number. As the magnetic field is increased and the field splitting becomes greater than the multiple splitting, the anomalous Zeeman effect changes over to a normal Zeeman effect. The chapter looks at experimental evidence confirming the quantization of magnetic moments, specifically the Zeeman effect and the Stern-Gerlach experiment.
The Pauli spin matrices have many useful properties. The spin of a particle is a degree of freedom additional to the spatial degrees of freedom. It is independent of the spatial degrees of freedom in the sense that one can simultaneously specify the spin state and the spatial state of a particle. Non-relativistically one must use more indirect methods of observing the spin. Classically, a spinning distribution of charge will have a magnetic moment; quantum mechanical spinning particles also have magnetic moments associated with their spins, and one tries to observe these magnetic moments in experiments. Spins in magnetic fields have very interesting dynamical properties. The right side is just the torque exerted by a magnetic field on a magnetic moment. This equation says in operator language that the rate of change of the spin angular momentum is the applied torque.