The control afforded by Feshbach resonance phenomena has enabled the exploration of strongly interacting degenerate regimes in dilute ultracold atomic alkali-gases. In these dilute systems, interactions are characterized by a single parameter, the s-wave scattering length. In this dissertation, we review the physics of quantum degenerate atomic gases from a theoretical perspective and present the applications of non-perturbative numerical methods ranging from exact diagonalization to quantum Monte Carlo techniques. Emphasis is given to the effect of interactions. A major goal of this work is to compare theoretical predictions with available experimental results. We begin by introducing the effective interactions in the many-body alkali-gas system. As simplifications of the real interaction between two alkali atoms, the resonance properties of various short range models, the zero-range model and the two-channel model are investigated. The fundamental result is that under appropriate conditions, the true interaction potential V(r) of two atoms may be replaced by a regularized delta-function. In collaboration with experimentalists in our department, we developed a unique method to construct localized single-particle wave functions using imaginary time projection and thereby determine lattice Hamiltonian parameters. Our method enables an efficient coarse-grained mapping from a continuum system to a lattice model. We apply the method to a specific disordered potential generated by an optical lattice experiment and calculate for each instance of disorder the equivalent lattice model parameters. Detailed statistical analysis is performed on the resulting probability distributions of the Hubbard parameters. In the final part, we study the pairing and ferromagnetic instabilities in systems of spin-1/2 fermions. To interpret a recent experimental study of the possibility of itinerant ferromagnetism in cold atom systems, we investigate the energy spectrum of a system of four spin-1/2 fermions with short range attractive interactions both exactly and within the scattering length approximation. The formation of molecular bound states and the ferromagnetic transition of the excited scattering state are examined systematically as a function of the two-body scattering length. We show that an adiabatic ferromagnetic transition occurs, but at a critical transition point k_{F}a much higher than predictions from the scattering length approximations. The exact critical interaction strength calculated in the four-particle system is consistent with that reported by experiment. Finally, by constructing a many-body wavefunction satisfying the Bethe-Peierls boundary conditions, we attempted the first variational Monte Carlo calculations of the zero-range model of unitary Fermion gases, eliminating the need for short-range approximations employed by existing QMC calculations.
The control afforded by Feshbach resonance phenomena has enabled the exploration of strongly interacting degenerate regimes in dilute ultracold atomic alkali-gases. In these dilute systems, interactions are characterized by a single parameter, the s-wave scattering length. In this dissertation, we review the physics of quantum degenerate atomic gases from a theoretical perspective and present the applications of non-perturbative numerical methods ranging from exact diagonalization to quantum Monte Carlo techniques. Emphasis is given to the effect of interactions. A major goal of this work is to compare theoretical predictions with available experimental results. We begin by introducing the effective interactions in the many-body alkali-gas system. As simplifications of the real interaction between two alkali atoms, the resonance properties of various short range models, the zero-range model and the two-channel model are investigated. The fundamental result is that under appropriate conditions, the true interaction potential V(r) of two atoms may be replaced by a regularized delta-function. In collaboration with experimentalists in our department, we developed a unique method to construct localized single-particle wave functions using imaginary time projection and thereby determine lattice Hamiltonian parameters. Our method enables an efficient coarse-grained mapping from a continuum system to a lattice model. We apply the method to a specific disordered potential generated by an optical lattice experiment and calculate for each instance of disorder the equivalent lattice model parameters. Detailed statistical analysis is performed on the resulting probability distributions of the Hubbard parameters. In the final part, we study the pairing and ferromagnetic instabilities in systems of spin-1/2 fermions. To interpret a recent experimental study of the possibility of itinerant ferromagnetism in cold atom systems, we investigate the energy spectrum of a system of four spin-1/2 fermions with short range attractive interactions both exactly and within the scattering length approximation. The formation of molecular bound states and the ferromagnetic transition of the excited scattering state are examined systematically as a function of the two-body scattering length. We show that an adiabatic ferromagnetic transition occurs, but at a critical transition point k_{F}a much higher than predictions from the scattering length approximations. The exact critical interaction strength calculated in the four-particle system is consistent with that reported by experiment. Finally, by constructing a many-body wavefunction satisfying the Bethe-Peierls boundary conditions, we attempted the first variational Monte Carlo calculations of the zero-range model of unitary Fermion gases, eliminating the need for short-range approximations employed by existing QMC calculations.
We study ultracold gases of alkali-metal atoms in the quantum degenerate regime. The interatomic interactions in these type of systems can be tuned using resonances induced by magnetic or electric fields. The tunability of the interactions, together with the possibility of confining the atoms with several kinds of external potentials, allows for a completely novel approach to study basic problems in many-body physics, and moreover, allows to enter regimes which have never been accessible in condensed matter or nuclear physics. For example, this has led to the experimental demonstration of an intimate relation between two types of superfluidity: the crossover from Bose-Einstein condensation of tightly bound molecules to the superfluid behavior related to weakly bound BCS-like pairs. Another experimental landmark was reached when the existence of universal Efimov three-body bound states was proven in experiments with ultracold bosonic cesium atoms. In this thesis, we study several aspects of these strongly interacting and ultracold atomic gases. We develop an analytical model that encapsulates all of the relevant scattering physics in atomic systems where open-channel shape resonances and closedchannel Feshbach resonances give rise to complicated and non-trivial scattering properties. This model provides lots of physical insight and is shown to describe important quantities, such as the molecular energies and scattering phase shifts, with a high level of accuracy. The model is compared to full numerical coupled-channel calculations in two atomic systems: rubidium and lithium. We study the BCS-BEC crossover using a many-body description of the ultracold gas that includes the non-trivial energy dependence of the scattering model. We show that it gives rise to superfluid behavior associated with the formation of BCS-like pairs while the low-energy interactions are repulsive in character. The energy dependence of the interactions is crucial, as it gives rise to attractive interactions at the Fermi energy, necessary for the formation of Cooper pairs. We demonstrate new ways of controlling the interatomic interactions using a combination of magnetic and electric fields. This leads to experimental control of, for instance, the three-body parameter in the context of Efimov physics and of non-universal behavior in the BCS-BEC crossover in fermionic gases. Using a four-body method based on first principles, we solve the molecule-molecule scattering problem to calculate several important properties of bosonic and fermionic Summary 145 molecules that consist of light and heavy atoms. These type of molecules are of current experimental interest, and we predict several exciting relations between three- and four-body observables in these type of systems.
Quantum degenerate Fermi gases can be created in the laboratories using alkali atoms. These gases can be in different regimes of density and interaction strength and provide an ideal test bed for the basic properties of the quantum and statistical mechanics. Also some astrophysical objects such as neutron stars can be idealized as interacting fermion systems. In this thesis work, the ground state properties of dilute Fermi gases with attractive short range two-body interactions are reported. Main results of this work are produced by application of quantum Monte Carlo methods. We introduce variational nodal structure to the trial wave function in order to deal with the fermion sign problem. We consider the possibility of Cooper pairing between fermions of different species. The strength of the interaction is varied to study different pairing regimes which are characterized by the product of the s-wave scattering length a and the Fermi wave vector kF. We also review some of the conventional variational methods such as the Lowest Order Constrained Variational which is suitable for Fermi fluids without pairing correlation. The ground state energy, pairing gap Δ, quasi-particle spectrum, two-body distribution function, and momentum distribution of the superfluid were studied with greater accuracy using ab initio quantum Monte Carlo techniques. In the case of the two component Fermi fluid, we find that in the weak coupling regime, 1/akF < -1, the system is a Bardeen-Cooper-Schrieffer type superfluid and the energy gap Δ is much smaller than the Fermi gas energy EFG. For 1/akF ≥ 0:5 we find that weakly interacting composite bosons or molecules are formed in the superfluid gas with Δ and gas energy per particle approaching half of the molecular energy jEmolj=2. In this region we seem to have Bose-Einstein condensation of molecules. The behavior of the energy, chemical potential and energy gap in the transition region, -0:5 < 1/akF < 0:5, is discussed. The study is extended to the three component Fermi fluid in relation to the spin polarized alkali gases and color superconductivity of the quark matter. Unlike the two component fluids, zero potential range limit cannot be reached without causing collapse of the system. We also study the scaling behavior of the three-body system. We calculate the threshold of the three-body bound state as a function of the potential range and strength. For the many-body systems, we find that ground state can be achieved by broken symmetry pairing. However, the restored symmetry pairing scenario in the strongly interacting regime is not conclusive. We also discuss the pairing gap as well as the structural properties such as two-body distribution functions.
The physics of quantum degenerate atomic Fermi gases in uniform as well as in harmonically trapped configurations is reviewed from a theoretical perspective. Emphasis is given to the effect of interactions that play a crucial role, bringing the gas into a superfluid phase at low temperature. In these dilute systems, interactions are characterized by a single parameter, the s-wave scattering length, whose value can be tuned using an external magnetic field near a broad Feshbach resonance. The BCS limit of ordinary Fermi superfluidity, the Bose-Einstein condensation (BEC) of dimers, and the unitary limit of large scattering length are important regimes exhibited by interacting Fermi gases. In particular, the BEC and the unitary regimes are characterized by a high value of the superfluid critical temperature, on the order of the Fermi temperature. Different physical properties are discussed, including the density profiles and the energy of the ground-state configurations, the momentum distribution, the fraction of condensed pairs, collective oscillations and pair-breaking effects, the expansion of the gas, the main thermodynamic properties, the behavior in the presence of optical lattices, and the signatures of superfluidity, such as the existence of quantized vortices, the quenching of the moment of inertia, and the consequences of spin polarization. Various theoretical approaches are considered, ranging from the mean-field description of the BCS-BEC crossover to nonperturbative methods based on quantum Monte Carlo techniques. A major goal of the review is to compare theoretical predictions with available experimental results.
The research described in this thesis is part of an international effort with the aim of studying ultracold quantum degenerate gas samples like Bose-Einstein condensates and Fermi degenerate systems, consisting of atoms confined in magnetic or optical traps. The behavior of such samples is governed by the inter-atomic interactions and the resulting properties of the atom-atom scattering. At the relevant temperatures of 1nK to 10µK a key property is the atom-atom scattering length a. In chapter 2 a theoretical method is presented which enables one to describe the interaction and scattering of (ultra)cold atoms to unprecedented precision. It is also unparalleled in comprehensiveness: it allows the prediction of a large and varied set of experimental data for all isotopes of the same element. The method relies on the extraction from experiments of a few (phase) parameters which completely summarize the behavior of the atoms in the (ultra)cold regime. In chapter 3 the method is applied to the "workhorses" of cold-atom physics: the atomic species 85Rb and 87Rb. We extract the foregoing parameters to a very high precision from several recent high precision experiments, allowing us to predict e.g. the 87Rb spinor condensate to be ferromagnetic: a prediction for which the scattering length has to be calculated with a precision better than 1%. We also predict Feshbach resonances at experimentally accessible magnetic field strengths; resonances searched for and found by the experimental group of Rempe. In close collaboration with his group we "fine-tune" the interaction parameters found previously, by making use of only one of the observed resonances. We then obtain agreement with 42 out of the observed 43 resonance field strengths and are able to identify bound states inducing the Feshbach resonances at these locations. Chapter 4 describes the results of this research. With a thorough understanding of the rubidium interactions, we then switch to lithium which has a fermionic (6Li) and a bosonic (7Li) isotope. Both are being used in cold-atom experiments. In chapter 5 we evaluate the interaction parameters for lithium allowing us to predict magnetic field strengths for which a sample of fermionic 6Li atoms can be regarded as strongly interacting. Furthermore, a three-level method for measuring mean-field shifts, based on radio-frequency techniques, is introduced. For weak interactions we find proportionality of resonance shifts to interaction strengths. In the strongly interacting regime, however, these shifts become very small reflecting the quantum unitarity limit and many-body effects. Most interesting is the fact that in this regime the shifts are small both for large positive a and for large negative a, likely reflecting the universality of the interaction energy. In chapters 6 and 7 the interactions between lithium atoms are reinvestigated, making use of newly available experimental data and with the updated interaction parameters special attention is paid to locating field strengths at which magnetically tunable Feshbach resonances occur in the scattering of lithium atoms. In chapter 6 scattering events in a gas of (fermionic) 6Li atoms are studied. In chapter 7 we show that a consistent description of the 6Li+6Li system can be given. We discuss theoretical uncertainties for the position of the wide 6Li Feshbach resonance and present an analytic scattering model for this resonance, based on the inclusion of a field-dependent virtual open-channel state. We predict new Feshbach resonances for the 6Li-7Li system, and their importance for different types of crossover superfluidity models is discussed. Molecules created by magnetically sweeping over these resonances will have a fermionic character. One magnetic field strength is predicted at which two different fermionic molecules can be created simultaneously.
Advances in experiments on dilute ultracold atomic gases have given us access to highly tunable quantum systems. In particular, there have been substantial improvements in achieving different kinds of interaction between atoms. As a result, utracold atomic gases oer an ideal platform to simulate many-body phenomena in condensed matter physics, and engineer other novel phenomena that are a result of the exotic interactions produced between atoms. In this dissertation, I present a series of studies that explore the physics of dilute ultracold atomic gases in different settings. In each setting, I explore a different form of the inter-particle interaction. Motivated by experiments which induce artificial spin-orbit coupling for cold fermions, I explore this system in my first project. In this project, I propose a method to perform universal quantum computation using the excitations of interacting spin-orbit coupled fermions, in which effective p-wave interactions lead to the formation of a topological superfluid. Motivated by experiments which explore the physics of exotic interactions between atoms trapped inside optical cavities, I explore this system in a second project. I calculate the phase diagram of lattice bosons trapped in an optical cavity, where the cavity modes mediates effective global range checkerboard interactions between the atoms. I compare this phase diagram with one that was recently measured experimentally. In two other projects, I explore quantum simulation of condensed matter phenomena due to spin-dependent interactions between particles. I propose a method to produce tunable spin-dependent interactions between atoms, using an optical Feshbach resonance. In one project, I use these spin-dependent interactions in an ultracold Bose-Fermi system, and propose a method to produce the Kondo model. I propose an experiment to directly observe the Kondo effect in this system. In another project, I propose using lattice bosons with a large hyperfine spin, which have Feshbach-induced spin-dependent interactions, to produce a quantum dimer model. I propose an experiment to detect the ground state in this system. In a final project, I develop tools to simulate the dynamics of fermionic superfluids in which fermions interact via a short-range interaction.
We investigate the energy spectrum of systems of two, three, and four spin-21 fermions with short range attractive interactions both exactly and within the scattering length approximation. The formation of molecular bound states and the ferromagnetic transition of the excited scattering state are examined systematically as a function of the two-body scattering length. Identification of the upper branch (scattering states) is discussed and a general approach valid for systems with many particles is given. We show that an adiabatic ferromagnetic transition occurs, but at a critical transition point kFa much higher than predicted from previous calculations, almost all of which use the scattering length approximation. In the four-particle system the discrepancy is a factor of 2. The exact critical interaction strength calculated in the four-particle system is consistent with that reported by experiment. To make comparisons with the adiabatic transition, we study the quench dynamics of the pairing instability using the eigenstate wave functions.