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JOURNAL OF ADVANCES IN PHYSICS

Onsagerian Quantum Mechanics

Gyula Vincze, András Szász

Published Feb 10, 2016• 0 citations
Publisher

Abstract

We describe the basic quantum-mechanical categories and properties of the thermodynamical basis of Onsagers theorem. 3 basic principles are used: 1. energy dissipation; 2. Hamiltonian formalism; 3. Onsagers linearity. We obtain the 2 characteristic values of the observables, their main-value and the deviation, the first and second momentums of the probability distribution function, which we also derived also from the same principles.

DOI
10.24297/jap.v11i5.349

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We describe the basic quantum-mechanical categories and properties of the thermodynamical basis of Onsagers theorem. 3 basic principles are used: 1. energy dissipation; 2. Hamiltonian formalism; 3. Onsagers linearity. We obtain the 2 characteristic values of the observables, their main-value and the deviation, the first and second momentums of the probability distribution function, which we also derived also from the same principles.
We propose six principles as the fundamental principles of quantum mechanics: principle of space and time, Galilean principle of relativity, Hamilton's principle, wave principle, probability principle, and principle of indestructibility and increatiblity of particles. We deductively develop the formalism of quantum mechanics on the basis of them: we determine the form of the Lagrangian that satisfies requirements of these principles, and obtain the Schroedinger equation from the Lagrangian. We also derive the canonical commutation relations. Then we adopt the following four guide lines. First, we do not premise the relations between dynamical variables in classical mechanics. Second, we define energy, momentum, and angular momentum as the constants of motion that are derived from homogeneity and isotropy in space and time on the basis of principle of space and time. Since energy and momentum are quantitatively defined in classical mechanics, we define them in quantum mechanics so that the corresponding conservation laws are satisfied in a coupling system of a quantum particle and a classical particle. Third, we define Planck's constant and the mass of a particle as proportionality constants between energy and frequency due to one of Einstein-de Broglie formulas and between momentum and velocity, respectively. We shall obtain the canonical commutation relations and the Schroedinger equation for a particle in an external field in the definitive form. We shall also prove that relations between dynamical variables in quantum mechanics have the same forms for those in classical mechanics.
The basic concepts and rules of quantum mechanics are shown to be immediate consequences, on the basis of simple reasoning, of a postulate of continuity in the domain of macroscopic thermodynamics. The continuity principle leads first to the concept of a fractional likeness between two states in general, as opposed to the classical alternative of either like or unlike. Then all possible states of a system can be arranged in sets of mutually unlike or “orthogonal” states, with members A and B of different sets interconnected by fractional likeness factors q(A, B) between zero and unity. These factors q are identical with the relative intensities in a splitting effect of a state into components, ruled by probability relations and by the basic principle of quantum statistics of not counting permutations of individual particles. The problem of relation between the various fractional likenesses, or probabilities of transition under analysis, is a purely mathematical problem and is solved by the introduction of probability amplitudes necessarily subject to a matrix law of multiplication, i.e., to the principle of superposition. Thus, starting from the continuity postulate of thermodynamics, quantum theory in its general outline is obtained by simple reasoning. All further details, such as the duality of waves and particles, the uncertainty relation, and the mechanics of special systems, need only one more bit of empirical information, namely, the symmetric and periodic form of the amplitude ψ of fractional likeness between a state of given coordinate and a state of given momentum.
The Heisenberg uncertainty postulates are a convenient way to describe the qualitative properties of quantum mechanics. The response from Heisenberg’s uncertainty principle is that one can create states that require a certain amount of momentum and position localization. The numerical quantities used by the old Newtonian mechanics, position, momentum, and energy are mere “shadows” of what nature describes: operators. The energy value contradicts the Newtonian notion of any energy level being necessary for a harmonic oscillator. The basic postulates of classical statistical mechanics are now applied to quantum statistical mechanics. In classical mechanics, the variables characterize a microstate that evolves according to the Hamiltonian equations. If the standard deviation relative to what we are interested in is very high, it is probably safe to use the expected value as a classical value. A quantum field theory is a relativistic invariant quantum theory where there is a particular form of quantity operators connected with the classical fields.
Quantum mechanics is based on the concepts of indeterminacy , indistinguishability probability amplitudes , probabilities , reversibility , superposition , and uncertainty . And yet that is only part of the essence of quantum mechanics. Using the words attached to the concepts just described provides only a partial description of what quantum mechanics really is. The other part is provided by a set of physical and mathematical principles annexed to the mentioned concepts. The beauty is that quantum mechanics becomes workable and functional just by observing its mathematical principles. There is no need for any particular interpretation. Not even the orthodox interpretation. Here, fifteen mathematical-physical principles of quantum mechanics are listed and succinctly explained.