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67th International Symposium on Molecular Spectroscopy

OBSERVATION OF BLUE-DETUNED PHOTOASSOCIATION TO THE 2 $(0_g^+)$ STATE OF $^{85}$Rb$_2$ VIA REMPI

Michael Bellos, Ryan Carollo, David Rahmlow, Jayita Banerjee, Matthew Bermudez, Edward E. Eyler, P. L. Gould, W. C. Stwalley

Published Jun 1, 2012• 0 citations
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OBSERVATION OF BLUE-DETUNED PHOTOASSOCIATION TO THE 2 (0g+)(0_g^+)(0g+​) STATE OF 85^{85}85Rb2_22​ VIA REMPI
BLUE-DETUNED PHOTOASSOCIATION SPECTRUM IN Rb2_22​
Blue-detuned photoassociation in Rb2_22​
Photoassociation of 85^{85}85Rb Atoms in 0u+0_{u}^{+}0u+​ States Near the 5S+5P Atomic Limits
A new laser spectroscopic technique has been demonstrated for examining the structure of alkali--rare gas diatomic electronic states near the classical limit. In two-color experiments, Rb--Ar or Rb--Kr thermal pairs are excited by freeleftarrowleftarrowleftarrowfree or boundleftarrowleftarrowleftarrowfree transitions while monitoring the amplified spontaneous emission produced on the Rb D1_11​ or D2_22​ lines. Spectra observed lying within 10 cm−1^{-1}−1 of the separated atom limit for the A2Pi1/2^{2}Pi_{1/2}2Pi1/2​ states of Rb--Ar and Rb--Kr will be presented and discussed.
Numerical calculations of photoassociation of cold 85^{85}85Rb2_{2}2​ molecules to the 1_{g}(5P_{1/2})$ State