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Scientific Reports

Micro-concave waveguide antenna for high photon extraction from nitrogen vacancy centers in nanodiamond

Ranjith Rajasekharan Unnithan, Günter Kewes, Amir Djalalian-Assl, Kumaravelu Ganesan, Snjezana Tomljenovic‐Hanic, Jeffrey Colin McCallum, Ann Roberts, Oliver J. Benson, Steven Prawer

Published Jul 14, 2015• 12 citations
Publisher

Abstract

The negatively charged nitrogen-vacancy colour center (NV(-) center) in nanodiamond is an excellent single photon source due to its stable photon generation in ambient conditions, optically addressable nuclear spin state, high quantum yield and its availability in nanometer sized crystals. In order to make practical devices using nanodiamond, highly efficient and directional emission of single photons in well-defined modes, either collimated into free space or waveguides are essential. This is a Herculean task as the photoluminescence of the NV centers is associated with two orthogonal dipoles arranged in a plane perpendicular to the NV defect symmetry axis. Here, we report on a micro-concave waveguide antenna design, which can effectively direct single photons from any emitter into either free space or into waveguides in a narrow cone angle with more than 80% collection efficiency irrespective of the dipole orientation. The device also enhances the spontaneous emission rate which further increases the number of photons available for collection. The waveguide antenna has potential applications in quantum cryptography, quantum computation, spectroscopy and metrology.

DOI
10.1038/srep12013

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The negatively charged nitrogen-vacancy colour center (NV(-) center) in nanodiamond is an excellent single photon source due to its stable photon generation in ambient conditions, optically addressable nuclear spin state, high quantum yield and its availability in nanometer sized crystals. In order to make practical devices using nanodiamond, highly efficient and directional emission of single photons in well-defined modes, either collimated into free space or waveguides are essential. This is a Herculean task as the photoluminescence of the NV centers is associated with two orthogonal dipoles arranged in a plane perpendicular to the NV defect symmetry axis. Here, we report on a micro-concave waveguide antenna design, which can effectively direct single photons from any emitter into either free space or into waveguides in a narrow cone angle with more than 80% collection efficiency irrespective of the dipole orientation. The device also enhances the spontaneous emission rate which further increases the number of photons available for collection. The waveguide antenna has potential applications in quantum cryptography, quantum computation, spectroscopy and metrology.
Single-photon sources are essential for quantum technologies, supporting secure communication, quantum computing, and integrated photonic systems. Nitrogen-vacancy (NV) centers in nanodiamonds are robust emitters that operate at room temperature and can be positioned on-chip, but efficient coupling to photonic modes remains challenging. We present the design, fabrication, and experimental characterization of a silicon nitride photonic structure engineered to enhance and extract emission from NV centers. The device features a subwavelength gap between waveguides, a Bragg reflector for emission redirection, and an output waveguide for collection. Simulations guided the optimization of the geometry to increase the spontaneous emission rate through photonic confinement. Nanodiamonds were deposited into the gap using lithographic patterning and drop-casting. Fluorescence lifetime measurements confirm that the structure modifies the emission dynamics of the NV centers. The approach is compatible with scalable fabrication techniques and offers a practical route toward integrated, chip-based single-photon sources.
The nitrogen-vacancy (NV) center in diamond has an optically addressable, highly coherent spin. However, an NV center even in high quality single-crystalline material is a very poor source of single photons: extraction out of the high-index diamond is inefficient, the emission of coherent photons represents just a few per cent of the total emission, and the decay time is large. In principle, all three problems can be addressed with a resonant microcavity, which significantly boosts the emission rate of coherent photons into the cavity mode based on the Purcell effect. In practice though, it has proved difficult to implement this concept: photonic engineering hinges on nano-fabrication yet it is notoriously difficult to process diamond without degrading the NV centers. \nIn this thesis, we present a microcavity scheme which employs minimally processed diamond membranes, thereby preserving the high quality of the starting material. The miniaturized plano-concave Fabry-Perot microcavity platform features full in situ spatial and spectral tunability. We demonstrate a clear change in the lifetime for multiple individual NV centers on tuning both the cavity frequency and anti-node position. The overall Purcell factor for the zero-phonon line (ZPL) of ~30 translates to an increase in the ZPL emission probability from ~3% to ~46%. \nFurthermore, we report the creation of a low-loss, broadband optical antenna giving highly directed output from a coherent single spin in the solid state. The device, the first crystalline solid-state realization of a dielectric antenna, is engineered for individual NV electronic spins in diamond. The photonic structure preserves the high spin coherence of single-crystalline diamond (T2 ~100µs). We demonstrate a directionality of close to 10 and single photon count rates approaching one MHz. The analysis of the angular emission pattern of our device suggests that 95% of the broadband NV fluorescence is channeled into a solid angle corresponding to a numerical aperture of 0.8. \nThe abovementioned approaches feature complementary benefits. The narrowband enhancement of the ZPL emission rate provided by the microcavity benefits applications in quantum information processing relying on coherent photons. With the prospect of integrating lifetime-limited emitters and achieving a high ZPL collection efficiency our results pave the way for much enhanced spin-photon and spin-spin entanglement rates. On the other hand, by channeling the major fraction of the broadband NV fluorescence into a narrow solid angle the dielectric optical antenna facilitates efficient spin readout. Our approach enables a near-unity collection efficiency which, upon mitigation of the known photon losses, renders it a potential key technology for quantum sensing applications. \n
We demonstrate an exceptionally bright photon source based on a single nitrogen-vacancy center (NV center) in a nanodiamond (ND) placed in the nanoscale gap between two monocrystalline silver cubes in a dimer configuration. The system is operated near saturation at a stable photon rate of 850 kcps, while we further achieve strongly polarized emission and high single photon purity, evident by the measured autocorrelation with a g (2) (0) value of 0.08. These photon source features are key parameters for quantum technological applications, such as secure communication based on quantum key distribution. The cube antenna is assembled with an atomic force microscope, which allows us to predetermine the dipole orientation of the NV center and optimize cube positioning accordingly, while also tracking the evolution of emission parameters from isolated ND to the one- and two-cube configuration. The experiment is well described by finite element modeling, assuming an instrinsic quantum efficiency of 0.35. We attribute the large photon rate of the assembled photon source, to increased quantum efficiency of the NV center and high antenna efficiency.
We present a novel design of optical nanostructure for efficient light extraction from nitrogen vacancy (NV) center in diamond. Numerical simulations of the optimal structure exhibit significant collection efficiency along with a stable radiation profile. We achieved a photon collection efficiency of 70% even with a lower numerical aperture of 0.5. Two different approaches (simple cone and encapsulated cone) have been adopted to reach a high geometrical tolerance without affecting much to the efficiency and emission profile. Besides that, our structure adds an extra benefit in terms of emission enhancement near zero phonon line (ZPL) region of NV spectra. Overall, this cone shaped diamond structure provides a robust, highly efficient and directional emission which can be integrated with a quantum optical network for various applications.
The nitrogen vacancy center in diamond in its negative charge state is a promising candidate for quantum optic experiments that require single photon emitters. Important benefits of the NV center are its high brightness and photo-stability, even at room temperature. Engineering the emission properties of NV centers with optical resonators is a widely followed approach to meet the requirements for quantum technological applications, but the effect on non-radiative decay paths is yet to be understood. Here we report on modifying the internal quantum efficiency of a single NV center in a nanodiamond coupled to a 1D photonic crystal cavity. We assess the Purcell enhancement via three independent measurement techniques and perform autocorrelation measurements at elevated excitation powers in confocal microscopy. Employing a three-level model allows us to extract the setup efficiency, individual transition rates and thus the internal quantum efficiency of our system. Combining our results, we find that the enhancement of the radiative decay rate via the Purcell effect results in an internal quantum efficiency of 90 % for cavity-coupled NV centers. Our findings will facilitate the realization of nano-scale single photon sources with near-unity internal quantum efficiencies operating at high repetition rates.
Enhancing the collection efficiency of single emitters via dielectric antennas is a common approach in research dealing with solid-state quantum light sources. Current design concepts often suffer from a large footprint, quenching or a complex fabrication process. Here we report on another design where the Kerker effect is used to collimate emission from a nitrogen vacancy (NV) center. The structure discussed here is an easy to fabricate cylindrical protrusion made from diamond on top of a diamond substrate with NVs incorporated into its center. We optimize the structure with respect to application in quantum information processing and quantum sensing and find an up to 15 times higher photon extraction.