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Physical Review A

Stark-Induced Quantum Beats in H L Y α Emission

H. J. Andrä

Published Dec 1, 1970• 42 citations
Publisher

Abstract

Intensity beats in the emission of $\mathrm{L}{\mathrm{y}}_{\ensuremath{\alpha}}$ from beam-foil excited hydrogen in various static electromagnetic field configurations have been studied. The observed beat frequencies agree with the calculated values, which are independent of the field directions. The beat amplitudes, however, show significant dependence on the field directions relative to the beam. The theory for emission of light from the decay of coherently excited states is applied in the sudden perturbation limit. Agreement with experiment can only be obtained under the assumption that the foil excitation generates initial coherent wave functions ${\ensuremath{\Psi}}_{\mathrm{I},\mathrm{I}\mathrm{I}}=\ensuremath{\alpha}|p,\frac{1}{2},\ifmmode\pm\else\textpm\fi{}\frac{1}{2}〉+\ensuremath{\beta}|s,\frac{1}{2},\ensuremath{\mp}\frac{1}{2}〉$, where $|l,j,{m}_{j}〉$ notation and the beam as quantization axis are used. The ratio $\frac{\ensuremath{\alpha}}{\ensuremath{\beta}}$ is then determined, which gives the ratio of the excitation cross section of the $p$ to that of the $s$ states as $\frac{{\ensuremath{\sigma}}_{p}}{{\ensuremath{\sigma}}_{s}}>~4\ifmmode\pm\else\textpm\fi{}1$ at a beam energy of 200 (keV) per atom.

DOI
10.1103/physreva.2.2200

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Physical Review A•Dec 1, 1997•4 citations
Intensity beats in the emission of Ly\ensuremathα\mathrm{L}{\mathrm{y}}_{\ensuremath{\alpha}}Ly\ensuremathα​ from beam-foil excited hydrogen in various static electromagnetic field configurations have been studied. The observed beat frequencies agree with the calculated values, which are independent of the field directions. The beat amplitudes, however, show significant dependence on the field directions relative to the beam. The theory for emission of light from the decay of coherently excited states is applied in the sudden perturbation limit. Agreement with experiment can only be obtained under the assumption that the foil excitation generates initial coherent wave functions \ensuremathΨI,II=\ensuremathα∣p,12,\ifmmode±\else\textpm\fi12〉+\ensuremathβ∣s,12,\ensuremath∓12〉{\ensuremath{\Psi}}_{\mathrm{I},\mathrm{I}\mathrm{I}}=\ensuremath{\alpha}|p,\frac{1}{2},\ifmmode\pm\else\textpm\fi{}\frac{1}{2}〉+\ensuremath{\beta}|s,\frac{1}{2},\ensuremath{\mp}\frac{1}{2}〉\ensuremathΨI,II​=\ensuremathα∣p,21​,\ifmmode±\else\textpm\fi21​〉+\ensuremathβ∣s,21​,\ensuremath∓21​〉, where ∣l,j,mj〉|l,j,{m}_{j}〉∣l,j,mj​〉 notation and the beam as quantization axis are used. The ratio \ensuremathα\ensuremathβ\frac{\ensuremath{\alpha}}{\ensuremath{\beta}}\ensuremathβ\ensuremathα​ is then determined, which gives the ratio of the excitation cross section of the ppp to that of the sss states as \ensuremathσp\ensuremathσs> 4\ifmmode±\else\textpm\fi1\frac{{\ensuremath{\sigma}}_{p}}{{\ensuremath{\sigma}}_{s}}>~4\ifmmode\pm\else\textpm\fi{}1\ensuremathσs​\ensuremathσp​​> 4\ifmmode±\else\textpm\fi1 at a beam energy of 200 (keV) per atom.
The strong field-induced quantum beats observed in beam-foil studies of Ly- alpha radiation are obtained in a conventional metastable-hydrogen quenching experiment. The phase relation between the Stark shifted 2s 1/2 -2p 1/2 Lamb-shift oscillations and the much more rapid 2s 1 -2p 3/2 fine-structure oscillations depends on the detailed way in which the quenching field is switched on. Apart from a phaseshift, the results agree with a non-perturbative theoretical calculation which assumes that the field is applied suddenly. Various frequency components of the time-dependent radiation intensity are identified with specific hyperfine transitions or groups of transitions. No adjustable parameters are used for the initial state amplitudes.
Zero-field quantum beats were observed in $\mathrm{L}\mathrm{y}\ensuremath{-}\ensuremath{\beta}$ emission (1026 \AA{}) from hydrogen atoms formed by beam-foil excitation, and the energy dependence of the magnetic-substate cross sections for n=3n=3n=3, l=1l=1l=1 states was determined for beam energies in the range from 230 to 500 keV/atom.
An expression is given for the Stark-induced beat signal in the Lyman-$\ensuremath{\alpha}$ radiation from hydrogen atoms in a beam-foil experiment. This expression includes possible contributions to the beat signal from coherent excitation of SSS and PPP states in the beam-foil process. For the case where the electric field is applied parallel to the beam, the coherentexcitation contributions can be separated experimentally from those resulting purely from coherence produced by the electric field, by simply reversing the direction of the electric field.
Hydrogen atoms are excited into high Rydberg states following fast proton impact on a thin carbon foil. The effects of various electromagnetic fields on these atoms are observed by measuring the integral ionization yield in an additional constant electric field. These experiments reveal oscillations in that yield, regularly spaced as a function of electric field. A model is outlined that quantitatively describes the observed field dependence. This new phenomenon indicates selective excitation of the Stark substates.
We have developed an experimental method for determining the initial density matrix of the foil-excited atoms. The excited hydrogen (n=2)(n=2)(n=2) atoms pass through a region of a variable electric field ($\ensuremath{-}200\mathrm{k}\mathrm{V}/\mathrm{m}$ to +200kV/m+200\mathrm{k}\mathrm{V}/\mathrm{m}+200kV/m), and the intensity of the Lyman-\ensuremath{\alpha} line (121.6 nm) emitted in a free space downstream is observed. By using a vacuum ultraviolet polarizer, the dependence of the intensities of the polarized components on the electric field, including the field-dependent quantum beats, was measured and it was numerically fitted to a calculation. Thus all the initial density matrix elements were determined in a single measurement. It was found that, in the energy range 100--180 keV, just after the excitation, the electron cloud has higher density in the front side of the ion and the electron probability current is backwards.