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Cambridge University Press eBooks

Real-time formalism

Jørgen Rammer

Published Jul 19, 2007• 0 citations
Publisher

Abstract

The contour-ordered Green's function considered in the previous chapter was ideal for discussing general closed time path properties such as the perturbative diagrammatic structure for non-equilibrium states. However, the contour-ordered Green's function lacks physical transparency and does not appeal to intuition. We need a different approach, which brings quantities back to real time. To accomplish this we introduce a representation where forward and return parts of the closed time path are ordered by numbers, specifying the position of a contour time by two indices, i = 1, 2. Next is the diagrammatic perturbation theory in the real-time technique then formulated in a fashion where the aspects of non-equilibrium states emerge in the physically most appealing way. In particular, we shall construct the representation where spectral properties and quantum statistics show up on a different footing in the diagrams. Lastly, we consider the connection to the imaginary-time treatment of non-equilibrium states, and establish its equivalence to the real-time approach propounded in this chapter. Real-time matrix representation To let our physical intuition come into play; we need to get from contour times back to real times. This is achieved by labeling the forward and return contours of the closed time path, depicted in Figure 4.5, by numbers, specifying the position of a contour time by an index. The forward contour we therefore label c 1 and the return contour c 2 , i.e. a contour time variable gets tagged by the label 1 or 2 specifying its belonging to forward or return contour, respectively.

DOI
10.1017/cbo9780511618956.006

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The contour-ordered Green's function considered in the previous chapter was ideal for discussing general closed time path properties such as the perturbative diagrammatic structure for non-equilibrium states. However, the contour-ordered Green's function lacks physical transparency and does not appeal to intuition. We need a different approach, which brings quantities back to real time. To accomplish this we introduce a representation where forward and return parts of the closed time path are ordered by numbers, specifying the position of a contour time by two indices, i = 1, 2. Next is the diagrammatic perturbation theory in the real-time technique then formulated in a fashion where the aspects of non-equilibrium states emerge in the physically most appealing way. In particular, we shall construct the representation where spectral properties and quantum statistics show up on a different footing in the diagrams. Lastly, we consider the connection to the imaginary-time treatment of non-equilibrium states, and establish its equivalence to the real-time approach propounded in this chapter. Real-time matrix representation To let our physical intuition come into play; we need to get from contour times back to real times. This is achieved by labeling the forward and return contours of the closed time path, depicted in Figure 4.5, by numbers, specifying the position of a contour time by an index. The forward contour we therefore label c 1 and the return contour c 2 , i.e. a contour time variable gets tagged by the label 1 or 2 specifying its belonging to forward or return contour, respectively.
This chapter considers the product of operators in the Heisenberg representation and express it in terms of the contour time-ordering operator. Since the relative order in which the operators enter the quantum average matters, this order has to be specified in detail. This procedure leads to considering the single- and two-particle Green’s functions, where the product contains, respectively, two and four field operators, which are at the core of the diagrammatic many-particle theory to be developed in what follows.
At present, the only general method available for gaining knowledge from the fundamental principles about the dynamics of a system is the perturbative study. According to Feynman, as described in Chapter 4, instead of formulating quantum theory in terms of operators, the canonical formulation, for calculational purposes quantum dynamics can conveniently be formulated in terms of a few simple stenographic rules, the Feynman rules for propagators and interaction vertices. In Chapters 4 and 5, we showed how to arrive at the Feynman rules of diagrammatic perturbation theory for non-equilibrium states starting from the Hamiltonian defining the theory. The feature of non-equilibrium states, originally carried by the dynamical indices, could be expressed in terms of two simple universal vertex rules for the RAK-components of the matrix Green's functions. We are thus well acquainted with diagrammatics even for the description of non-equilibrium situations. However, for the situations studied using the quantum kinetic equations in Chapters 7 and 8, only the Dyson equation was needed, i.e. the self-energy, the 2-state one-particle irreducible amputated Green's function. No need for higher-order vertex functions was required, and the full flourishing diagrammatics was not put into action. In this chapter we shall proceed the other way around. We shall show that the diagrammatics of a physical theory, including the description of non-equilibrium states, can be obtained by simply stating quantum dynamics, the superposition principle, as the two exclusive options for a particle: to interact or not to interact ! From this simple Shakespearean approach we shall construct the Feynman diagrammatics of non-equilibrium dynamics.
This chapter considers the closed-time-path Green’s functions approach when specified to equilibrium situations and shows that it offers an alternative to the more standard Matsubara plus analytic continuation procedure for obtaining physical quantities directly in real frequency. In this case, the number of independent components of the single-particle Green’s function (as well as of the related self-energy) reduces considerably, thereby making it easier to solve the Kadanoff–Baym equations. The fluctuation–dissipation theorem and the single-particle spectral function (with its related sum rule) are also considered.
This chapter explores to what extent the closed-contour Schwinger–Keldysh approach and the Lindblad Master equation can be connected with each other. Here, the connection with the Schwinger–Keldysh closed-contour approach does not involve the full machinery of the Green’s functions method, but rather refers directly to the time evolution of the many-body density matrix, which contains a forward evolution operator from the reference time t ₀ to the measuring time t and a backward evolution operator from t back to t ₀. The key approximations to derive the Lindblad Master equation are specified in detail. As an example, a two-level system coupled to a phonon bath is explicitly considered.