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中国物理B：英文版

STARK STRUCTURE OF THE RYDBERG STATES OF ALKALINE-EARTH ATOMS

郅妙婵, 戴长建, 李士本

Published Jun 12, 2005• 0 citations
Publisher
DOI
10.1088/1009-1963/10/10/009

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Rydberg series of msns and msnd configurations of Be (m=2) and Mg (m=3) were investigated between principal quantum numbers 10 ≤ n ≤ 70. The Rydberg states were populated using stepwise excitation or direct two-photon transitions with frequency doubled light (235 nm ≤ λ < 330 nm) from pulsed dye lasers. The excited Rydberg atoms were detected with a space charge limited thermionic diode. An analysis of the Rydberg series both in Be and Mg by means of multi-channel quantum-defect theory (MQDT) results in the determination of mp2 1D2 admixtures in msnd 1D2 states.
This paper presents the coherent elliptic states (CES) of alkaline constructed from the spherical Rydberg wavefunctions generated by the B-spline method associated with Hartree–Fock approximation. To construct the elliptic orbit for alkaline is not straightforward. The core effect plays an important role for the formation of elliptic states especially in higher and lower eccentricity. When the eccentricity is not large (i.e. e=0.6), the physical quantities of CES of alkaline atoms can be theoretically calculated by the replacement with hydrogen atom.