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Bulletin of the American Physical Society

Spin dynamics with Solid State NMR and GPU calculations: Loschmidt Echoes, Intrinsic Decoherence and Quantum Dynamical Phase Transitions

Horacio M. Pastawski

Published Mar 4, 2015• 0 citations
OpenAlex

Abstract

I will focus on the Loschmidt Echo [LE], a concept developed and pursed at Cordoba. It is the recovered fraction of a localized excitation after a spreading period followed by an imperfect time reversal procedure [1]. In Solid State NMR, the LE has allowed us to quantify the decoherence and irreversibility induced by an uncontrolled environment. Notably complex many-body dynamics makes the system particularly sensitive to environmental disturbances presenting a decoherence rate that becomes perturbation independent beyond some small threshold. These experiments and the theoretical analysis based on the Feynman's path integral, summarized at a tutorial level, fueled the field of dynamical quantum chaos. The quest for a perturbation independent decoherence as an emergent phenomenon in thermodynamic limit, lead us to discuss other dynamical observables that depend non-analytically on the environment strength, i.e. that undergo a quantum dynamical phase transition QDPT [2]. GPU based high performance computing boosts the evaluation of the LE [3], allowing us to assess thermalization and how the Metal-Insulator transition (also a QDPT) emerges in interacting many-body systems. [1] Loschmidt Echo A. Gousev, R.A. Jalabert, HMP and D.A. Wisniacki. Scholarpedia 7, 11687 (2012) http://www.scholarpedia.org/article/Loschmidt_echo [2] Environmentally induced quantum dynamical phase transition in the spin swap operation, G.A.Alvarez, E.P.Danieli, P.R. Levstein, and HMP, J. Chem.Phys. 124, 1 (2006) [3] Interaction-disorder competition in a spin system evaluated through the Loschmidt echo P.R. Zangara, A.D. Dente, A. Iucci, P.R. Levstein, and HMP, Phys. Rev. B 88, 195106 (2013)

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Loschmidt echo in many-spin systems: a quest for intrinsic decoherence and emergent irreversibility

Pablo R. Zangara, Horacio M Pastawski

Abstract If a magnetic polarization excess is locally injected in a crystal of interacting spins in thermal equilibrium, this ‘excitation’ would spread as consequence of spin–spin interactions. Such an apparently irreversible process is known as spin diffusion and it can lead the system back to ‘equilibrium’. Even so, a unitary quantum dynamics would ensure a precise memory of the non-equilibrium initial condition. Then, if at a certain time, say t / 2 , an experimental protocol reverses the many-body dynamics by changing the sign of the effective Hamiltonian, it would drive the system back to the initial non-equilibrium state at time t . As a matter of fact, the reversal is always perturbed by small experimental imperfections and/or uncontrolled internal or environmental degrees of freedom. This limits the amount of signal M ( t ) recovered locally at time t . The degradation of M ( t ) accounts for these perturbations, which can also be seen as the sources of decoherence. This general idea defines the Loschmidt echo (LE), which embodies the various time-reversal procedures implemented in nuclear magnetic resonance. Here, we present an invitation to the study of the LE following the pathway induced by the experiments. With such a purpose, we provide a historical and conceptual overview that briefly revisits selected phenomena that underlie the LE dynamics including chaos, decoherence, localization and equilibration. This guiding thread ultimately leads us to the discussion of decoherence and irreversibility as an emergent phenomenon. In addition, we introduce the LE formalism by means of spin–spin correlation functions in a manner suitable for presentation in a broad scope physics journal. Last, but not least, we present new results that could trigger new experiments and theoretical ideas. In particular, we propose to transform an initially localized excitation into a more complex initial state, enabling a dynamically prepared LE. This induces a global definition of the LE in terms of the raw overlap between many-body wave functions. Our results show that as the complexity of the prepared state increases, it becomes more fragile towards small perturbations.

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Loschmidt echo in many-spin systems: A quest for intrinsic decoherence and emergent irreversibility

Pablo R. Zangara, Horacio M. Pastawski

If a magnetic polarization excess is locally injected in a crystal of interacting spins in thermal equilibrium, this 'excitation' would spread as consequence of spin-spin interactions. Such an apparently irreversible process is known as spin diffusion and it can lead the system back to 'equilibrium'. Even so, a unitary quantum dynamics would ensure a precise memory of the non-equilibrium initial condition. Then, if at a certain time, say , an experimental protocol reverses the many-body dynamics by changing the sign of the effective Hamiltonian, it would drive the system back to the initial non-equilibrium state at time t. As a matter of fact, the reversal is always perturbed by small experimental imperfections and/or uncontrolled internal or environmental degrees of freedom. This limits the amount of signal M(t) recovered locally at time t. The degradation of M(t) accounts for these perturbations, which can also be seen as the sources of decoherence. This general idea defines the Loschmidt echo (LE), which embodies the various time-reversal procedures implemented in nuclear magnetic resonance. Here, we present an invitation to the study of the LE following the pathway induced by the experiments. With such a purpose, we provide a historical and conceptual overview that briefly revisits selected phenomena that underlie the LE dynamics including chaos, decoherence, localization and equilibration. This guiding thread ultimately leads us to the discussion of decoherence and irreversibility as an emergent phenomenon. In addition, we introduce the LE formalism by means of spin-spin correlation functions in a manner suitable for presentation in a broad scope physics journal. Last, but not least, we present new results that could trigger new experiments and theoretical ideas. In particular, we propose to transform an initially localized excitation into a more complex initial state, enabling a dynamically prepared LE. This induces a global definition of the LE in terms of the raw overlap between many-body wave functions. Our results show that as the complexity of the prepared state increases, it becomes more fragile towards small perturbations.

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In the long quest to identify and compensate the sources of decoherence in many-body systems far from the ground state, the varied family of Loschmidt echoes (LEs) became an invaluable tool in several experimental techniques. A LE involves a time-reversal procedure to assess the effect of perturbations in a quantum excitation dynamics. However, when addressing macroscopic systems one is repeatedly confronted with limitations that seem insurmountable. This led to the formulation of the central hypothesis of irreversibility stating that the timescale of decoherence, ${T}_{3}$, is proportional to the timescale of the many-body interactions we reversed, ${T}_{2}$. We test this by implementing two experimental schemes based on Floquet Hamiltonians where the effective strength of the dipolar spin-spin coupling, i.e., $1/{T}_{2}$, is reduced by a variable scale factor $k$. This extends the perturbation timescale, ${T}_{\mathrm{\ensuremath{\Sigma}}}$, in relation to ${T}_{2}$. Strikingly, we observe the superposition of the normalized Loschmidt echoes for the bigger values of $k$. This manifests the dominance of the intrinsic dynamics over the perturbation factors, even when the Loschmidt echo is devised to reverse that intrinsic dynamics. Thus, in the limit where the reversible interactions dominate over perturbations, the LE decays within a timescale, ${T}_{3}\ensuremath{\approx}{T}_{2}/R$ with $R=(0.15\ifmmode\pm\else\textpm\fi{}0.01)$, confirming the emergence of a perturbation independent regime. These results support the central hypothesis of irreversibility.

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A local excitation in a quantum many-spin system evolves deterministically. A time-reversal procedure, involving the inversion of the signs of every energy and interaction, should produce the excitation revival. This idea, experimentally coined in nuclear magnetic resonance, embodies the concept of the Loschmidt echo (LE). While such an implementation involves a single spin autocorrelation M(1,1), i.e. a local LE, theoretical efforts have focused on the study of the recovery probability of a complete many-body state, referred to here as global or many-body LE MMB Here, we analyse the relation between these magnitudes, with regard to their characteristic time scales and their dependence on the number of spins N We show that the global LE can be understood, to some extent, as the simultaneous occurrence of N independent local LEs, i.e. MMB∼(M(1,1))(N/4) This extensive hypothesis is exact for very short times and confirmed numerically beyond such a regime. Furthermore, we discuss a general picture of the decay of M1,1 as a consequence of the interplay between the time scale that characterizes the reversible interactions (T(2)) and that of the perturbation (τ(Σ)). Our analysis suggests that the short-time decay, characterized by the time scale τ(Σ), is greatly enhanced by the complex processes that occur beyond T(2) This would ultimately lead to the experimentally observed T(3), which was found to be roughly independent of τ(Σ) but closely tied to T(2).

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Role of energy uncertainties in ergodicity breaking induced by competing interactions and disorder. A dynamical assessment through the Loschmidt echo

Pablo R. Zangara, Patricia R. Levstein, Horacio M. Pastawski

A local excitation in a quantum many-particle system evolves deterministically. A time-reversal procedure, involving the invertion of the signs of every energy and interaction, should produce an excitation revival: the Loschmidt echo (LE). If somewhat imperfect, only a fraction of the excitation will refocus. We use such a procedure to show how non-inverted weak disorder and interactions, when assisted by the natural reversible dynamics, fully degrade the LE. These perturbations enhance diffusion and evenly distribute the excitation throughout the system. Such a dynamical paradigm, called ergodicity, breaks down when either the disorder or the interactions are too strong. These extreme regimes give rise to the well known Anderson localization and Mott insulating phases, where quantum diffusion becomes restricted. Accordingly, regardless of the kinetic energy terms, the excitation remains mainly localized and out-of-equilibrium, and the system behaves non-ergodically. The LE constitutes a fair dynamical witness for the whole phase diagram since it evidences a surprising topography in which ergodic and non-ergodic phases interpenetrate each other. Furthermore, we provide an estimation for the critical lines separating the ergodic and non-ergodic phases around the Mott and Anderson transitions. The energy uncertainties introduced by disorder and interaction shift these thresholds towards stronger perturbations. Remarkably, the estimations of the critical lines are in good agreement with the phase diagram derived from the LE dynamics.Received: 20 Novembre 2014, Accepted: 29 June 2015; Edited by: C. A. Condat, G. J. Sibona; Reviewed by: A. De Luca, Laboratoire de Physique Theorique, ENS & Institut Philippe Meyer, Paris, France; DOI: http://dx.doi.org/10.4279/PIP.070012Cite as: P R Zangara, P R Levstein, H M Pastawski, Papers in Physics 7, 070012 (2015)This paper, by P R Zangara, P R Levstein, H M Pastawski, is licensed under the Creative Commons Attribution License 3.0.

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Pablo R. Zangara, Axel D. Dente, Patricia R. Levstein +1 more

We employ the Loschmidt echo, i.e., the signal recovered after the reversal of an evolution, to identify and quantify the processes contributing to decoherence. This procedure, which has been extensively used in single-particle physics, is employed here in a spin ladder. The isolated chains have $1/2$ spins with $XY$ interaction and their excitations would sustain a one-body-like propagation. One of them constitutes the controlled system $\mathcal{S}$ whose reversible dynamics is degraded by the weak coupling with the uncontrolled second chain, i.e., the environment $\mathcal{E}$. The perturbative $\mathcal{SE}$ coupling is swept through arbitrary combinations of $XY$ and Ising-like interactions, that contain the standard Heisenberg and dipolar ones. Different time regimes are identified for the Loschmidt echo dynamics in this perturbative configuration. In particular, the exponential decay scales as a Fermi golden rule, where the contributions of the different $\mathcal{SE}$ terms are individually evaluated and analyzed. Comparisons with previous analytical and numerical evaluations of decoherence based on the attenuation of specific interferences show that the Loschmidt echo is an advantageous decoherence quantifier at any time, regardless of the $\mathcal{S}$ internal dynamics.

arXiv:1111.2004•Physical Review A•Jul 18, 2012•27 citations
I will focus on the Loschmidt Echo [LE], a concept developed and pursed at Cordoba. It is the recovered fraction of a localized excitation after a spreading period followed by an imperfect time reversal procedure [1]. In Solid State NMR, the LE has allowed us to quantify the decoherence and irreversibility induced by an uncontrolled environment. Notably complex many-body dynamics makes the system particularly sensitive to environmental disturbances presenting a decoherence rate that becomes perturbation independent beyond some small threshold. These experiments and the theoretical analysis based on the Feynman's path integral, summarized at a tutorial level, fueled the field of dynamical quantum chaos. The quest for a perturbation independent decoherence as an emergent phenomenon in thermodynamic limit, lead us to discuss other dynamical observables that depend non-analytically on the environment strength, i.e. that undergo a quantum dynamical phase transition QDPT [2]. GPU based high performance computing boosts the evaluation of the LE [3], allowing us to assess thermalization and how the Metal-Insulator transition (also a QDPT) emerges in interacting many-body systems. [1] Loschmidt Echo A. Gousev, R.A. Jalabert, HMP and D.A. Wisniacki. Scholarpedia 7, 11687 (2012) http://www.scholarpedia.org/article/Loschmidt_echo [2] Environmentally induced quantum dynamical phase transition in the spin swap operation, G.A.Alvarez, E.P.Danieli, P.R. Levstein, and HMP, J. Chem.Phys. 124, 1 (2006) [3] Interaction-disorder competition in a spin system evaluated through the Loschmidt echo P.R. Zangara, A.D. Dente, A. Iucci, P.R. Levstein, and HMP, Phys. Rev. B 88, 195106 (2013)
Abstract If a magnetic polarization excess is locally injected in a crystal of interacting spins in thermal equilibrium, this ‘excitation’ would spread as consequence of spin–spin interactions. Such an apparently irreversible process is known as spin diffusion and it can lead the system back to ‘equilibrium’. Even so, a unitary quantum dynamics would ensure a precise memory of the non-equilibrium initial condition. Then, if at a certain time, say t / 2 , an experimental protocol reverses the many-body dynamics by changing the sign of the effective Hamiltonian, it would drive the system back to the initial non-equilibrium state at time t . As a matter of fact, the reversal is always perturbed by small experimental imperfections and/or uncontrolled internal or environmental degrees of freedom. This limits the amount of signal M ( t ) recovered locally at time t . The degradation of M ( t ) accounts for these perturbations, which can also be seen as the sources of decoherence. This general idea defines the Loschmidt echo (LE), which embodies the various time-reversal procedures implemented in nuclear magnetic resonance. Here, we present an invitation to the study of the LE following the pathway induced by the experiments. With such a purpose, we provide a historical and conceptual overview that briefly revisits selected phenomena that underlie the LE dynamics including chaos, decoherence, localization and equilibration. This guiding thread ultimately leads us to the discussion of decoherence and irreversibility as an emergent phenomenon. In addition, we introduce the LE formalism by means of spin–spin correlation functions in a manner suitable for presentation in a broad scope physics journal. Last, but not least, we present new results that could trigger new experiments and theoretical ideas. In particular, we propose to transform an initially localized excitation into a more complex initial state, enabling a dynamically prepared LE. This induces a global definition of the LE in terms of the raw overlap between many-body wave functions. Our results show that as the complexity of the prepared state increases, it becomes more fragile towards small perturbations.
If a magnetic polarization excess is locally injected in a crystal of interacting spins in thermal equilibrium, this 'excitation' would spread as consequence of spin-spin interactions. Such an apparently irreversible process is known as spin diffusion and it can lead the system back to 'equilibrium'. Even so, a unitary quantum dynamics would ensure a precise memory of the non-equilibrium initial condition. Then, if at a certain time, say , an experimental protocol reverses the many-body dynamics by changing the sign of the effective Hamiltonian, it would drive the system back to the initial non-equilibrium state at time t. As a matter of fact, the reversal is always perturbed by small experimental imperfections and/or uncontrolled internal or environmental degrees of freedom. This limits the amount of signal M(t) recovered locally at time t. The degradation of M(t) accounts for these perturbations, which can also be seen as the sources of decoherence. This general idea defines the Loschmidt echo (LE), which embodies the various time-reversal procedures implemented in nuclear magnetic resonance. Here, we present an invitation to the study of the LE following the pathway induced by the experiments. With such a purpose, we provide a historical and conceptual overview that briefly revisits selected phenomena that underlie the LE dynamics including chaos, decoherence, localization and equilibration. This guiding thread ultimately leads us to the discussion of decoherence and irreversibility as an emergent phenomenon. In addition, we introduce the LE formalism by means of spin-spin correlation functions in a manner suitable for presentation in a broad scope physics journal. Last, but not least, we present new results that could trigger new experiments and theoretical ideas. In particular, we propose to transform an initially localized excitation into a more complex initial state, enabling a dynamically prepared LE. This induces a global definition of the LE in terms of the raw overlap between many-body wave functions. Our results show that as the complexity of the prepared state increases, it becomes more fragile towards small perturbations.
In the long quest to identify and compensate the sources of decoherence in many-body systems far from the ground state, the varied family of Loschmidt echoes (LEs) became an invaluable tool in several experimental techniques. A LE involves a time-reversal procedure to assess the effect of perturbations in a quantum excitation dynamics. However, when addressing macroscopic systems one is repeatedly confronted with limitations that seem insurmountable. This led to the formulation of the central hypothesis of irreversibility stating that the timescale of decoherence, T3{T}_{3}T3​, is proportional to the timescale of the many-body interactions we reversed, T2{T}_{2}T2​. We test this by implementing two experimental schemes based on Floquet Hamiltonians where the effective strength of the dipolar spin-spin coupling, i.e., 1/T21/{T}_{2}1/T2​, is reduced by a variable scale factor kkk. This extends the perturbation timescale, ${T}_{\mathrm{\ensuremath{\Sigma}}}$, in relation to T2{T}_{2}T2​. Strikingly, we observe the superposition of the normalized Loschmidt echoes for the bigger values of kkk. This manifests the dominance of the intrinsic dynamics over the perturbation factors, even when the Loschmidt echo is devised to reverse that intrinsic dynamics. Thus, in the limit where the reversible interactions dominate over perturbations, the LE decays within a timescale, ${T}_{3}\ensuremath{\approx}{T}_{2}/R$ with $R=(0.15\ifmmode\pm\else\textpm\fi{}0.01)$, confirming the emergence of a perturbation independent regime. These results support the central hypothesis of irreversibility.
A local excitation in a quantum many-spin system evolves deterministically. A time-reversal procedure, involving the inversion of the signs of every energy and interaction, should produce the excitation revival. This idea, experimentally coined in nuclear magnetic resonance, embodies the concept of the Loschmidt echo (LE). While such an implementation involves a single spin autocorrelation M(1,1), i.e. a local LE, theoretical efforts have focused on the study of the recovery probability of a complete many-body state, referred to here as global or many-body LE MMB Here, we analyse the relation between these magnitudes, with regard to their characteristic time scales and their dependence on the number of spins N We show that the global LE can be understood, to some extent, as the simultaneous occurrence of N independent local LEs, i.e. MMB∼(M(1,1))(N/4) This extensive hypothesis is exact for very short times and confirmed numerically beyond such a regime. Furthermore, we discuss a general picture of the decay of M1,1 as a consequence of the interplay between the time scale that characterizes the reversible interactions (T(2)) and that of the perturbation (τ(Σ)). Our analysis suggests that the short-time decay, characterized by the time scale τ(Σ), is greatly enhanced by the complex processes that occur beyond T(2) This would ultimately lead to the experimentally observed T(3), which was found to be roughly independent of τ(Σ) but closely tied to T(2).
A local excitation in a quantum many-particle system evolves deterministically. A time-reversal procedure, involving the invertion of the signs of every energy and interaction, should produce an excitation revival: the Loschmidt echo (LE). If somewhat imperfect, only a fraction of the excitation will refocus. We use such a procedure to show how non-inverted weak disorder and interactions, when assisted by the natural reversible dynamics, fully degrade the LE. These perturbations enhance diffusion and evenly distribute the excitation throughout the system. Such a dynamical paradigm, called ergodicity, breaks down when either the disorder or the interactions are too strong. These extreme regimes give rise to the well known Anderson localization and Mott insulating phases, where quantum diffusion becomes restricted. Accordingly, regardless of the kinetic energy terms, the excitation remains mainly localized and out-of-equilibrium, and the system behaves non-ergodically. The LE constitutes a fair dynamical witness for the whole phase diagram since it evidences a surprising topography in which ergodic and non-ergodic phases interpenetrate each other. Furthermore, we provide an estimation for the critical lines separating the ergodic and non-ergodic phases around the Mott and Anderson transitions. The energy uncertainties introduced by disorder and interaction shift these thresholds towards stronger perturbations. Remarkably, the estimations of the critical lines are in good agreement with the phase diagram derived from the LE dynamics.Received: 20 Novembre 2014, Accepted: 29 June 2015; Edited by: C. A. Condat, G. J. Sibona; Reviewed by: A. De Luca, Laboratoire de Physique Theorique, ENS & Institut Philippe Meyer, Paris, France; DOI: http://dx.doi.org/10.4279/PIP.070012Cite as: P R Zangara, P R Levstein, H M Pastawski, Papers in Physics 7, 070012 (2015)This paper, by P R Zangara, P R Levstein, H M Pastawski, is licensed under the Creative Commons Attribution License 3.0.
We employ the Loschmidt echo, i.e., the signal recovered after the reversal of an evolution, to identify and quantify the processes contributing to decoherence. This procedure, which has been extensively used in single-particle physics, is employed here in a spin ladder. The isolated chains have 1/21/21/2 spins with XYXYXY interaction and their excitations would sustain a one-body-like propagation. One of them constitutes the controlled system S\mathcal{S}S whose reversible dynamics is degraded by the weak coupling with the uncontrolled second chain, i.e., the environment E\mathcal{E}E. The perturbative SE\mathcal{SE}SE coupling is swept through arbitrary combinations of XYXYXY and Ising-like interactions, that contain the standard Heisenberg and dipolar ones. Different time regimes are identified for the Loschmidt echo dynamics in this perturbative configuration. In particular, the exponential decay scales as a Fermi golden rule, where the contributions of the different SE\mathcal{SE}SE terms are individually evaluated and analyzed. Comparisons with previous analytical and numerical evaluations of decoherence based on the attenuation of specific interferences show that the Loschmidt echo is an advantageous decoherence quantifier at any time, regardless of the S\mathcal{S}S internal dynamics.