Bose–Einstein condensates in dilute atomic gases, which were first realized experimentally in 1995 for rubidium, sodium, and lithium, provide unique opportunities for exploring quantum phenomena on a macroscopic scale. These systems differ from ordinary gases, liquids, and solids in a number of respects, as we shall now illustrate by giving typical values of some physical quantities. The particle density at the centre of a Bose-Einstein condensed atomic cloud is typically 10 13 –10 15 cm −3 . By contrast, the density of molecules in air at room temperature and atmospheric pressure is about 10 19 cm −3 . In liquids and solids the density of atoms is of order 1022 cm −3 , while the density of nucleons in atomic nuclei is about 10 38 cm −3 . To observe quantum phenomena in such low-density systems, the temperature must be of order 10 −5 K or less. This may be contrasted with the temperatures at which quantum phenomena occur in solids and liquids. In solids, quantum effects become strong for electrons in metals below the Fermi temperature, which is typically 10 4 –10 5 K, and for phonons below the De bye temperature, which is typically of order 10 2 K. For the helium liquids, the temperatures required for observing quantum phenomena are of order 1 K. Due to the much higher particle density in atomic nuclei, the corresponding degeneracy temperature is about 10 11 K. The path that led in 1995 to the first realization of Bose–Einstein condensation in dilute gases exploited the powerful methods developed over the past quarter of a century for cooling alkali metal atoms by using lasers.
Bose–Einstein condensates in dilute atomic gases, which were first realized experimentally in 1995 for rubidium, sodium, and lithium, provide unique opportunities for exploring quantum phenomena on a macroscopic scale. These systems differ from ordinary gases, liquids, and solids in a number of respects, as we shall now illustrate by giving typical values of some physical quantities. The particle density at the centre of a Bose-Einstein condensed atomic cloud is typically 10 13 –10 15 cm −3 . By contrast, the density of molecules in air at room temperature and atmospheric pressure is about 10 19 cm −3 . In liquids and solids the density of atoms is of order 1022 cm −3 , while the density of nucleons in atomic nuclei is about 10 38 cm −3 . To observe quantum phenomena in such low-density systems, the temperature must be of order 10 −5 K or less. This may be contrasted with the temperatures at which quantum phenomena occur in solids and liquids. In solids, quantum effects become strong for electrons in metals below the Fermi temperature, which is typically 10 4 –10 5 K, and for phonons below the De bye temperature, which is typically of order 10 2 K. For the helium liquids, the temperatures required for observing quantum phenomena are of order 1 K. Due to the much higher particle density in atomic nuclei, the corresponding degeneracy temperature is about 10 11 K. The path that led in 1995 to the first realization of Bose–Einstein condensation in dilute gases exploited the powerful methods developed over the past quarter of a century for cooling alkali metal atoms by using lasers.
The experimental realization in 1995 of Bose–Einstein condensation in dilute atomic gases marked the beginning of a very rapid development in the study of quantum gases. The initial experiments were performed on vapours of rubidium, sodium, and lithium. So far, the atoms 1 H, 7 Li, 23 Na, 39 K, 41 K, 52 Cr, 85 Rb, 87 Rb, 133 Cs, 170 Yb, 174 Yb and 4 He * (the helium atom in an excited state) have been demonstrated to undergo Bose–Einstein condensation. In related developments, atomic Fermi gases have been cooled to well below the degeneracy temperature, and a superfluid state with correlated pairs of fermions has been observed. Also molecules consisting of pairs of fermionic atoms such as 6 Li or 40 K have been observed to undergo Bose–Einstein condensation. Atoms have been put into optical lattices, thereby allowing the study of many-body systems that are realizations of models used in condensed matter physics. Although the gases are very dilute, the atoms can be made to interact strongly, thus providing new challenges for the description of strongly correlated many-body systems. In a period of less than ten years the study of dilute quantum gases has changed from an esoteric topic to an integral part of contemporary physics, with strong ties to molecular, atomic, subatomic and condensed matter physics. The dilute quantum gases differ from ordinary gases, liquids and solids in a number of ways, as we shall now illustrate by giving values of physical quantities.
For sufficiently low temperatures, a Bose gas experiences a transition into a Bose-Einstein condensate, characterized by a macroscopic occupation of the ground state of the system. The development of efficient cooling and trapping techniques for neutral atoms led in 1995, to the first observation of BEC in dilute alkali gases in 87Rb [1]. This remarkable achievement has been followed by BEC experiments in various other elements. The BEC has become during the last years, one of the most active and fruitful research areas of modern atomic physics, constituting an interdisciplinary field, which links atomic physics with various other research areas, like quantum optics, condensed-matter physics, and very especially nonlinear physics.
Quantum systems consisting of many particles are both interesting from the physics and the mathematics perspective. One aspect that makes them fascinating from the physics point of view is that they can exhibit quantum effects on macroscopic scales such as Bose-Einstein condensation. This phenomenon, first predicted 100 years ago by Bose [19] and Einstein [44], occurs when a dilute gas of bosons is cooled down to very low temperatures. Below a certain critical temperature a condensate forms, meaning that a macroscopic fraction of the particles is in the same one-particle state, and thus, quantum phenomena become relevant on length scales much larger than the individual atom. The occurrence of Bose-Einstein condensation is also related to superfluidity as suggested in [88]. Bose-Einstein condensation has been achieved experimentally independently by the groups of Cornell and Wieman [3] and Ketterle [40] earning them a Nobel prize in 2001. While Bose and Einstein analyzed theoretically the non-interacting gas, an effective theory describing weakly interacting Bose gases was proposed by Bogoliubov in 1947 with the goal of explaining the occurrence of superfluidity in liquid helium [18]. Using assumptions such as that condensation indeed occurs, his theory yields predictions for the low-energy states of the system. Seen from the mathematics perspective, describing the Bose gas is an interesting challenge due to the strong correlations between particles introduced by the interaction making this case much harder to study than the non-interacting one. In particular, a proof that Bose-Einstein condensation occurs in the thermodynamic limit for continuous systems is still out of reach. However, there has been a lot of work regarding the rigorous analysis of bosonic systems in various relevant regimes. This thesis contains three new contributions establishing rigorous results on bosonic systems in different, physically relevant settings. It is based on the articles [37, 27, 31]. The first result concerns the time-evolution of initially trapped Bose gases in the ultra-dilute Gross-Pitaevskii regime. Under some assumptions on the initial data satisfied in particular by a class of states that are expected to approximate the ground state in a trap, we derive a quasi-free approximation that is close to the true solution in L2-norm. In particular, we show that this approximate wave function is described in terms of a Bose-Einstein condensate in a one-particle state following the time-dependent Gross-Pitaevskii equation together with pair excitations with respect to this condensate. As a corollary, we establish a central limit theorem for bounded one-particle observables. The second result is a simple proof of Bose-Einstein condensation for interacting, ultra-dilute gases. More specifically, we consider scalings interpolating between the Gross-Pitaevskii regime and the thermodynamic limit. While condensation had been shown to hold in these regimes before, the advantage of the method used here is its simplicity. Lastly, the third result establishes an upper bound on the ground state energy of a dilute Bose gas in the thermodynamic limit. It captures rigorously the third order correction to the energy per unit volume for sufficiently low densities as predicted in the physics literature first by Wu and subsequently others. Full-text embargoed until: 2026-01-01
Introduction Bose–Einstein condensation (BEC) is one of the most intriguing phenomena in physics. The basic idea goes back to the 1920s, when Einstein made predictions for the behavior of atoms at sufficiently low temperatures and high densities. However, it took seven decades for experimental physicists to realize this phase under the low-density conditions envisioned by Einstein. In the intermediate period there were many experiments in which aspects of BEC played important roles. Therefore, phenomena such as superfluidity and superconductivity were connected to BEC long before its 1995 realization in ultra-cold, low-density atomic vapors. Since BEC can be discussed with very many different backgrounds and applications in mind, the subject can sometimes be overwhelming for interested students. There is a very good reason why a chapter on BEC does not belong in this book. In all the other chapters here, the processes described involve one or at most two atoms, and the interactions that play a role are between the particles that constitute the atom, namely between the nucleus (or nuclei) and their electrons. The interactions are described quantum mechanically by their Hamiltonian that can always be written exactly in non-relativistic terms, and in some cases can even be solved exactly. This makes atoms and molecules a branch of physics where comparisons between theory and experiments become very meaningful since theoretical predictions are often confirmed to very high accuracy. In BEC, it is the interactions among many atoms that are the key for understanding the phenomenon. Although in principle one could write a Hamiltonian for a Bose condensed gas, its large number of particles makes this not very practical. The starting point for the description of a BEC is in the area of many-body physics that belongs to the expertise of condensed-matter physicists. The interactions between ~10 23 electrons in a solid state with a lattice formed by ~10 23 ions resemble the kind of interactions in a BEC much more closely than the simple fewbody interactions in an atom or molecule. Thus all the theoretical models that have been described up to now are not applicable for the contents of this chapter.
Since the dramatic discovery of Bose–Einstein condensation (BEC) in trapped atomic gases in 1995 (Anderson et al. , 1995), there has been an explosion of theoretical and experimental research on the properties of Bose-condensed dilute gases. The first phase of this research was discussed in the influential review article by Dalfovo et al. (1999) and in the proceedings of the 1998 Varenna Summer School on BEC (Inguscio et al. , 1999). More recently, this research has been well documented in two monographs, by Pethick and Smith (2008, second edition) and by Pitaevskii and Stringari (2003). Most of this research, both experimental and theoretical, has concentrated on the case of low temperatures (well below the BEC transition temperature, T BEC ), where one is effectively dealing with a pure Bose condensate. The total fraction of noncondensate atoms in such experiments can be as small as 10% of the total number of atoms and, equally importantly, this low-density cloud of thermally excited atoms is spread over a much larger spatial region compared with the high-density condensate, which is localized at the centre of the trapping potential. Thus most studies of Bose-condensed gases at low temperatures have concentrated entirely on the condensate degree of freedom and its response to various perturbations. This region is well described by the famous Gross–Pitaevskii (GP) equation of motion for the condensate order parameter Φ( r , t ). As shown by research since 1995, this pure condensate domain is very rich in physics. The main goal of the present book, in contrast, is to describe the dynamics of dilute trapped atomic gases at finite temperatures such that the noncondensate atoms also play an important role.
Since an atomic Bose-Einstein condensate, predicted by Einstein in 1925, was first produced in the laboratory in 1995, the study of ultracold Bose and Fermi gases has become one of the most active areas in contemporary physics. This book explains phenomena in ultracold gases from basic principles, without assuming a detailed knowledge of atomic, condensed matter, and nuclear physics. This new edition has been revised and updated, and includes new chapters on optical lattices, low dimensions, and strongly-interacting Fermi systems. This book provides a unified introduction to the physics of ultracold atomic Bose and Fermi gases for advanced undergraduate and graduate students, as well as experimentalists and theorists. Chapters cover the statistical physics of trapped gases, atomic properties, cooling and trapping atoms, interatomic interactions, structure of trapped condensates, collective modes, rotating condensates, superfluidity, interference phenomena, and trapped Fermi gases. Problems are included at the end of each chapter.