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Thermometry of arbitrary quantum systems via non-equilibrium work distributions

T. H. Johnson, F. Cosco, Mark T. Mitchison, Dieter Jaksch, Stephen R. L. Clark

Published Aug 12, 2015• 0 citations
OpenAlex

Abstract

Estimating the temperature of a cold quantum system is difficult. Usually, one measures a well-understood thermal state and uses that prior knowledge to infer its temperature. In contrast, we introduce a method of thermometry that assumes no knowledge of the state of a system and is potentially non-destructive. Our method uses a universal temperature-dependence of the non-equilibrium dynamics of an initially thermal system coupled to a qubit probe that follows from the Tasaki-Crooks theorem for non-equilibrium work distributions. We provide examples, for a cold atom system, for which our thermometry protocol may retain accuracy and precision at subnanokelvin temperatures.

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Estimating the temperature of a cold quantum system is difficult. Usually, one measures a well-understood thermal state and uses that prior knowledge to infer its temperature. In contrast, we introduce a method of thermometry that assumes no knowledge of the state of a system and is potentially non-destructive. Our method uses a universal temperature-dependence of the non-equilibrium dynamics of an initially thermal system coupled to a qubit probe that follows from the Tasaki-Crooks theorem for non-equilibrium work distributions. We provide examples, for a cold atom system, for which our thermometry protocol may retain accuracy and precision at subnanokelvin temperatures.
Estimating the temperature of a cold quantum system is difficult. Usually one measures a well-understood thermal state and uses that prior knowledge to infer its temperature. In contrast, we introduce a method of thermometry that assumes minimal knowledge of the state of a system and is potentially nondestructive. Our method uses a universal temperature dependence of the quench dynamics of an initially thermal system coupled to a qubit probe that follows from the Tasaki-Crooks theorem for nonequilibrium work distributions. We provide examples for a cold-atom system, in which our thermometry protocol may retain accuracy and precision at subnano-Kelvin temperatures.
Quantum thermometry aims to measure temperature in nanoscale quantum systems, paralleling classical thermometry. However, temperature is not a quantum observable, and most theoretical studies have therefore concentrated on analyzing fundamental precision limits set by the quantum Fisher information through the quantum Cramer-Rao bound. In contrast, whether a direct temperature readout can be achieved in quantum thermometry remains largely unexplored, particularly under the nonequilibrium conditions prevalent in real-world applications. To address this, we develop a direct temperature readout scheme based on a thermodynamic inference strategy. The scheme integrates two conceptual developments: (i) By applying the maximum entropy principle with the thermometer's mean energy as a constraint, we assign a reference temperature to the nonequilibrium thermometer. We demonstrate that this reference temperature outperforms a commonly used effective temperature defined through equilibrium analogy. (ii) We obtain positive semi-definite error functions that lower-bound the deviation of the reference temperature from the true temperature-in analogy to the quantum Cramer-Rao bound for the mean squared error-and vanish upon thermalization with the sample. Combining the reference temperature with these error functions, we introduce a notion of corrected dynamical temperature which furnishes a postprocessed temperature readout under nonequilibrium conditions. This corrected dynamical temperature can be evaluated adaptively without prior knowledge of the actual temperature. We validate the corrected dynamical temperature in a qubit-based thermometer under a range of nonequilibrium initial states, confirming its capability to estimate the true temperature. Importantly, we find that increasing quantum coherence can enhance the precision of this readout.
Thermometry is essential for studying many-body physics with ultracold atoms. Accurately measuring low temperatures in these systems, however, remains a significant challenge due to the absence of a universal thermometer. Most widely applicable methods, such as fitting of in situ density profiles, are limited by the requirement of global thermal equilibrium and inapplicability to homogeneous systems. In this Letter, we introduce a novel in situ thermometry for quantum gases, leveraging single-atom-resolved measurements via quantum gas microscopy, and demonstrate it on an ideal Fermi gas. By analyzing number fluctuations in probe volumes containing as little as one atom on average, we extract both global and local temperatures over a broad dynamic range. Our method does not rely on the fluctuation-dissipation theorem and is based instead on the exact relationship between number fluctuations and density-density correlations. In the low-temperature regime, it allows us to observe significant deviations from fluctuation-dissipation predictions, uncovering subextensive fluctuations. Our method is applicable to systems with arbitrary trapping potentials, requiring neither precise trap calibration nor global thermal equilibrium. This thermometer for quantum gases overcomes key limitations of existing techniques, paving the way for more accurate and versatile temperature measurements in ultracold quantum systems.
Measuring the temperature of a quantum system is an essential task in almost all aspects of quantum technologies. Theoretically, an optimal strategy for thermometry requires measuring energy which demands full accessibility over the entire system as well as complex entangled measurement basis. In this paper, we take a different approach and show that single qubit sequential measurements in the computational basis not only allows precise thermometry of a many-body system but may also achieve precision beyond the theoretical bound, avoiding demanding energy measurements at equilibrium. To obtain such precision, the time between the two subsequent measurements should be smaller than the thermalization time so that the probe never thermalizes. Therefore, the non-equilibrium dynamics of the system continuously imprint information about temperature in the state of the probe. This allows the sequential measurement scheme to reach precision beyond the accuracy achievable by complex energy measurements on equilibrium probes.
We study the Bayesian approach to thermometry with no prior knowledge about the expected temperature scale, through the example of energy measurements on fully or partially thermalized qubit probes. We show that the most common Bayesian estimators, namely the mean and the median, lead to high-temperature divergences when used for uninformed thermometry. To circumvent this and achieve better overall accuracy, we propose two new estimators based on an optimization of relative deviations. Their global temperature-averaged behavior matches a modified van Trees bound, which complements the Cramer-Rao bound for smaller probe numbers and unrestricted temperature ranges. Furthermore, we show that, using partially thermalized probes, one can increase the range of temperatures to which the thermometer is sensitive at the cost of the local accuracy.
We discuss the application of techniques of quantum estimation theory and quantum metrology to thermometry. The ultimate limit to the precision at which the temperature of a system at thermal equilibrium can be determined is related to the heat capacity when global measurements are performed on the system. We prove that if technical or practical limitations restrict our capabilities to local probing, the highest achievable accuracy to temperature estimation reduces to a sort of mesoscopic version of the heat capacity. Adopting a more practical perspective, we also discuss the relevance of qubit systems as optimal quantum thermometers, in order to retrieve the temperature, or to discriminate between two temperatures, characterizing a thermal reservoir. We show that quantum coherence and entanglement in a probe system can facilitate faster, or more accurate measurements of temperature. While not surprising given this has been demonstrated in phase estimation, temperature is not a conventional quantum observable, therefore these results extend the theory of parameter estimation to measurement of non-Hamiltonian quantities. Finally we point out the advantages brought by a less standard estimation technique based on sequential measurements, when applied to quantum thermometry.