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Graduate texts in mathematics

A Particle in a Square Well

Brian C. Hall

Published Jan 1, 2013• 0 citations
Publisher
DOI
10.1007/978-1-4614-7116-5_5

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Abstract In order to specify the uncertainty relation for a particle confined in a finite square well potential we derived the standard deviation of momentum Δ p and that of position Δ x . It is shown that Δ p has a peak as a function of the well width and both Δ x and Δ p ⋅ Δ x have a dip in contrast to the case of the particle confined in an infinite square well potential. We clarified that Δ p 0 ⋅ Δ x 0 of the particle occupying the ground state exists in the finite range as a function of the well width and the potential-barrier height, but a particle confined in an infinite square well potential has a constant Δ p 0 ⋅ Δ x 0 . In addition, we found that the values of Δ p n ⋅ Δ x n for excited states diverge in a certain range of well widths, where the energy level of the confined particle exceeds the potential barrier.