Probabilistic methods in some problems of scattering theory
U. Mark Kac
Introduction.We give three applications of probability to scattering theory.The first question we consider is that of the "scattering length."We obtain a probabilistic expression for scattering length and use this expression to prove that in the case of an impenetrable obstacle ("hard" potential) the scattering length T is the same as the electrostatic capacity.Next, we briefly touch upon a problem which is inherently probabilistic-namely, scattering in a medium with random boundary.We find that if a large number of small hard spheres ("dust particles") are distributed at random in the medium, the effect is to shift all the eigenvalues by a constant.Our final topic is the so-called "inverse problem" of scattering theory: given the scattering operator, to compute the potential.For certain spherically symmetric potentials, this problem was solved in a famous paper of GelTand and Levitan.Here we show that their result can be included in the circle of potential-theoretic problems which can be solved by means of Brownian motion and Wiener integrals.We quickly sketch some of the physical background.We are concerned with the Schrodinger equation of non-relativistic quantum mechanics.In its stationary or time-independent form, this equation isThe "wave function" I/J depends on both the position vector fiEfi 3 and the wave number k.The real parameter k 2 is proportional to the energy.The function q(R) is called the "potential."It represents the interaction of the quantum-mechanical "particle" with some force field.The "scattering problem" is, roughly speaking, to determine the effect of this interaction asymptotically for large R.More precisely, we seek a solution of (1) which at |fl| = » is of the asymptotic form e iV2kz + fk(e)e iV ^k> ^l\\R\\ where e is the unit vector in the direction of R. The first term, e iV2kz , is an incident wave in the direction of the zaxis; the second term /fc(e)e iV ^I^H/||R||, is the "scattered wave."
Rocky Mountain Journal of Mathematics•Sep 1, 1974•112 citations